{"title":"利用纳米计量探测器测量丙烷气体的扩散和迁移率","authors":"Irina Kempf , Uwe Schneider","doi":"10.1016/j.radphyschem.2024.112274","DOIUrl":null,"url":null,"abstract":"<div><div>For the operation of nanodosimetric detectors with propane gas, it is essential to know the gas properties at room temperature, such as drift velocity, ion mobility, longitudinal and transversal diffusion coefficients. For propane gas there is only limited experimental data available for the ion mobility and transverse diffusion coefficients. In this work, the drift velocities and ion mobilities for propane were obtained over the reduced electric field range <span><math><mrow><mi>E</mi><mo>/</mo><mi>N</mi></mrow></math></span> from 24 to 212 Td (1 Td = <span><math><mrow><mn>1</mn><msup><mrow><mn>0</mn></mrow><mrow><mo>−</mo><mn>17</mn></mrow></msup></mrow></math></span> Vcm<span><math><msup><mrow></mrow><mrow><mn>2</mn></mrow></msup></math></span>) based on arrival time measurements. The reduced ion mobility <span><math><msub><mrow><mi>K</mi></mrow><mrow><mn>0</mn></mrow></msub></math></span> for propane was determined to be <span><math><mrow><mo>(</mo><mn>0</mn><mo>.</mo><mn>71</mn><mspace></mspace><mo>±</mo><mspace></mspace><mn>0</mn><mo>.</mo><mn>09</mn><mo>)</mo></mrow></math></span> cm<span><math><mrow><msup><mrow></mrow><mrow><mn>2</mn></mrow></msup><mo>/</mo></mrow></math></span>Vs. The longitudinal diffusion coefficients were determined from the widths of the experimental arrival time spectra and found to be <span><math><mrow><mi>N</mi><msub><mrow><mi>D</mi></mrow><mrow><mi>L</mi></mrow></msub></mrow></math></span> = (3.7 <span><math><mo>±</mo></math></span> 0.5)<span><math><mrow><mi>⋅</mi><mn>1</mn><msup><mrow><mn>0</mn></mrow><mrow><mn>19</mn></mrow></msup></mrow></math></span> 1/ms in the low field limit below 30 Td.</div><div>The results presented in this work extend the range of available experimental data for propane, as well as introduce first experimental measurements of the longitudinal diffusion coefficient of propane.</div></div>","PeriodicalId":20861,"journal":{"name":"Radiation Physics and Chemistry","volume":"226 ","pages":"Article 112274"},"PeriodicalIF":2.8000,"publicationDate":"2024-10-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Diffusion and mobility measurements for propane gas with a nanodosimetric detector\",\"authors\":\"Irina Kempf , Uwe Schneider\",\"doi\":\"10.1016/j.radphyschem.2024.112274\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>For the operation of nanodosimetric detectors with propane gas, it is essential to know the gas properties at room temperature, such as drift velocity, ion mobility, longitudinal and transversal diffusion coefficients. For propane gas there is only limited experimental data available for the ion mobility and transverse diffusion coefficients. In this work, the drift velocities and ion mobilities for propane were obtained over the reduced electric field range <span><math><mrow><mi>E</mi><mo>/</mo><mi>N</mi></mrow></math></span> from 24 to 212 Td (1 Td = <span><math><mrow><mn>1</mn><msup><mrow><mn>0</mn></mrow><mrow><mo>−</mo><mn>17</mn></mrow></msup></mrow></math></span> Vcm<span><math><msup><mrow></mrow><mrow><mn>2</mn></mrow></msup></math></span>) based on arrival time measurements. The reduced ion mobility <span><math><msub><mrow><mi>K</mi></mrow><mrow><mn>0</mn></mrow></msub></math></span> for propane was determined to be <span><math><mrow><mo>(</mo><mn>0</mn><mo>.</mo><mn>71</mn><mspace></mspace><mo>±</mo><mspace></mspace><mn>0</mn><mo>.</mo><mn>09</mn><mo>)</mo></mrow></math></span> cm<span><math><mrow><msup><mrow></mrow><mrow><mn>2</mn></mrow></msup><mo>/</mo></mrow></math></span>Vs. The longitudinal diffusion coefficients were determined from the widths of the experimental arrival time spectra and found to be <span><math><mrow><mi>N</mi><msub><mrow><mi>D</mi></mrow><mrow><mi>L</mi></mrow></msub></mrow></math></span> = (3.7 <span><math><mo>±</mo></math></span> 0.5)<span><math><mrow><mi>⋅</mi><mn>1</mn><msup><mrow><mn>0</mn></mrow><mrow><mn>19</mn></mrow></msup></mrow></math></span> 1/ms in the low field limit below 30 Td.</div><div>The results presented in this work extend the range of available experimental data for propane, as well as introduce first experimental measurements of the longitudinal diffusion coefficient of propane.</div></div>\",\"PeriodicalId\":20861,\"journal\":{\"name\":\"Radiation Physics and Chemistry\",\"volume\":\"226 \",\"pages\":\"Article 112274\"},\"PeriodicalIF\":2.8000,\"publicationDate\":\"2024-10-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Radiation Physics and Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0969806X24007667\",\"RegionNum\":3,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Radiation Physics and Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0969806X24007667","RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Diffusion and mobility measurements for propane gas with a nanodosimetric detector
For the operation of nanodosimetric detectors with propane gas, it is essential to know the gas properties at room temperature, such as drift velocity, ion mobility, longitudinal and transversal diffusion coefficients. For propane gas there is only limited experimental data available for the ion mobility and transverse diffusion coefficients. In this work, the drift velocities and ion mobilities for propane were obtained over the reduced electric field range from 24 to 212 Td (1 Td = Vcm) based on arrival time measurements. The reduced ion mobility for propane was determined to be cmVs. The longitudinal diffusion coefficients were determined from the widths of the experimental arrival time spectra and found to be = (3.7 0.5) 1/ms in the low field limit below 30 Td.
The results presented in this work extend the range of available experimental data for propane, as well as introduce first experimental measurements of the longitudinal diffusion coefficient of propane.
期刊介绍:
Radiation Physics and Chemistry is a multidisciplinary journal that provides a medium for publication of substantial and original papers, reviews, and short communications which focus on research and developments involving ionizing radiation in radiation physics, radiation chemistry and radiation processing.
The journal aims to publish papers with significance to an international audience, containing substantial novelty and scientific impact. The Editors reserve the rights to reject, with or without external review, papers that do not meet these criteria. This could include papers that are very similar to previous publications, only with changed target substrates, employed materials, analyzed sites and experimental methods, report results without presenting new insights and/or hypothesis testing, or do not focus on the radiation effects.