A. A. Gumovskaya, Yu. Z. Vasilyeva, A. Ya. Pak, G. I. Mamontov
{"title":"用无真空电弧法合成多组分碳化物","authors":"A. A. Gumovskaya, Yu. Z. Vasilyeva, A. Ya. Pak, G. I. Mamontov","doi":"10.1134/S2635167623600694","DOIUrl":null,"url":null,"abstract":"<div><p>This paper presents the results of experimental studies in the field of the electric-arc synthesis of a solid solution of TiZrNbHfTaC<sub>5</sub> multicomponent carbide using an atmospheric plasma reactor. The implementation of the synthesis of carbide in air is possible due to the formation of a buffer layer of carbon monoxide, which prevents the oxidation of synthesis products. It is shown that when TiO<sub>2</sub>, ZrO<sub>2</sub>, Nb<sub>2</sub>O<sub>5</sub>, HfO<sub>2</sub>, and Ta<sub>2</sub>O<sub>5</sub> metal-oxide powders are used as precursors, it is possible to provide such parameters of the synthesis process that ensure the formation of a high-entropy TiZrNbHfTaC<sub>5</sub> carbide phase with a face-centered cubic lattice. According to the data of transmission electron microscopy, the synthesis products contain particles with a wide size distribution from tens of micrometers to submicron and nanoscale ones.</p></div>","PeriodicalId":716,"journal":{"name":"Nanotechnologies in Russia","volume":"18 1 supplement","pages":"S11 - S16"},"PeriodicalIF":0.8000,"publicationDate":"2024-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of Multicomponent Carbides by the Vacuum-Free Electric-Arc Method\",\"authors\":\"A. A. Gumovskaya, Yu. Z. Vasilyeva, A. Ya. Pak, G. I. Mamontov\",\"doi\":\"10.1134/S2635167623600694\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>This paper presents the results of experimental studies in the field of the electric-arc synthesis of a solid solution of TiZrNbHfTaC<sub>5</sub> multicomponent carbide using an atmospheric plasma reactor. The implementation of the synthesis of carbide in air is possible due to the formation of a buffer layer of carbon monoxide, which prevents the oxidation of synthesis products. It is shown that when TiO<sub>2</sub>, ZrO<sub>2</sub>, Nb<sub>2</sub>O<sub>5</sub>, HfO<sub>2</sub>, and Ta<sub>2</sub>O<sub>5</sub> metal-oxide powders are used as precursors, it is possible to provide such parameters of the synthesis process that ensure the formation of a high-entropy TiZrNbHfTaC<sub>5</sub> carbide phase with a face-centered cubic lattice. According to the data of transmission electron microscopy, the synthesis products contain particles with a wide size distribution from tens of micrometers to submicron and nanoscale ones.</p></div>\",\"PeriodicalId\":716,\"journal\":{\"name\":\"Nanotechnologies in Russia\",\"volume\":\"18 1 supplement\",\"pages\":\"S11 - S16\"},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2024-03-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nanotechnologies in Russia\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S2635167623600694\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"Engineering\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nanotechnologies in Russia","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.1134/S2635167623600694","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"Engineering","Score":null,"Total":0}
Synthesis of Multicomponent Carbides by the Vacuum-Free Electric-Arc Method
This paper presents the results of experimental studies in the field of the electric-arc synthesis of a solid solution of TiZrNbHfTaC5 multicomponent carbide using an atmospheric plasma reactor. The implementation of the synthesis of carbide in air is possible due to the formation of a buffer layer of carbon monoxide, which prevents the oxidation of synthesis products. It is shown that when TiO2, ZrO2, Nb2O5, HfO2, and Ta2O5 metal-oxide powders are used as precursors, it is possible to provide such parameters of the synthesis process that ensure the formation of a high-entropy TiZrNbHfTaC5 carbide phase with a face-centered cubic lattice. According to the data of transmission electron microscopy, the synthesis products contain particles with a wide size distribution from tens of micrometers to submicron and nanoscale ones.
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Nanobiotechnology Reports publishes interdisciplinary research articles on fundamental aspects of the structure and properties of nanoscale objects and nanomaterials, polymeric and bioorganic molecules, and supramolecular and biohybrid complexes, as well as articles that discuss technologies for their preparation and processing, and practical implementation of products, devices, and nature-like systems based on them. The journal publishes original articles and reviews that meet the highest scientific quality standards in the following areas of science and technology studies: self-organizing structures and nanoassemblies; nanostructures, including nanotubes; functional and structural nanomaterials; polymeric, bioorganic, and hybrid nanomaterials; devices and products based on nanomaterials and nanotechnology; nanobiology and genetics, and omics technologies; nanobiomedicine and nanopharmaceutics; nanoelectronics and neuromorphic computing systems; neurocognitive systems and technologies; nanophotonics; natural science methods in a study of cultural heritage items; metrology, standardization, and monitoring in nanotechnology.
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