退火对磁控溅射二氧化铈表面层结构的影响

IF 0.4 Q4 METALLURGY & METALLURGICAL ENGINEERING
E. O. Nasakina, M. A. Sudarchikova, A. S. Baikin, A. A. Mel’nikova, A. V. Mikhailova, N. A. Dormidontov, P. A. Prokof’ev, S. V. Konushkin, K. V. Sergienko, M. A. Kaplan, M. A. Sevost’yanov, A. G. Kolmakov
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引用次数: 0

摘要

利用磁控溅射和随后的退火在 VT6 钛合金基底上形成纳米和微米级二氧化铈(CeO2)表层。通过扫描电子显微镜、欧杰电子能谱、能量色散光谱和 X 射线衍射分析研究了样品的结构。我们发现表面层厚度与沉积时间呈线性关系,厚度随电源功率的增加呈非线性增加,表面粗糙度增加,分层和表面层松动,这可能与退火有关。在表层厚度小于 750 nm 的样品中,发现形成了 TiO2、Al2O3 和 CeVO4 子层;在表层厚度小于 300 nm 时,整个二氧化铈被消耗,由二氧化钒形成钒酸盐。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Effect of Annealing on the Structure of Magnetron-Sputtered Cerium Dioxide Surface Layers

Effect of Annealing on the Structure of Magnetron-Sputtered Cerium Dioxide Surface Layers

Magnetron sputtering and subsequent annealing are used to form nano- and micron-sized cerium dioxide (CeO2) surface layers on a VT6 titanium alloy base. The structure of samples is studied by scanning electron microscopy, Auger-electron spectroscopy, energy dispersive spectroscopy, and X-ray diffraction analysis. We detected a linear dependence of the surface layer thickness on the deposition time, a nonlinear increase in the thickness with the supply power, an increase in the surface roughness, and delamination and surface layer loosening, which are likely to be related to annealing. For samples with a surface layer less than 750 nm in thickness, the formation of a TiO2, Al2O3, and CeVO4 sublayer is found; at a layer thickness of less than 300 nm, the entire cerium dioxide is consumed to form vanadate from vanadium dioxide.

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来源期刊
Russian Metallurgy (Metally)
Russian Metallurgy (Metally) METALLURGY & METALLURGICAL ENGINEERING-
CiteScore
0.70
自引率
25.00%
发文量
140
期刊介绍: Russian Metallurgy (Metally)  publishes results of original experimental and theoretical research in the form of reviews and regular articles devoted to topical problems of metallurgy, physical metallurgy, and treatment of ferrous, nonferrous, rare, and other metals and alloys, intermetallic compounds, and metallic composite materials. The journal focuses on physicochemical properties of metallurgical materials (ores, slags, matters, and melts of metals and alloys); physicochemical processes (thermodynamics and kinetics of pyrometallurgical, hydrometallurgical, electrochemical, and other processes); theoretical metallurgy; metal forming; thermoplastic and thermochemical treatment; computation and experimental determination of phase diagrams and thermokinetic diagrams; mechanisms and kinetics of phase transitions in metallic materials; relations between the chemical composition, phase and structural states of materials and their physicochemical and service properties; interaction between metallic materials and external media; and effects of radiation on these materials.
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