{"title":"定量评估氢键对聚（乙烯醇）/茶多酚复合材料结晶动力学的影响","authors":"Xiao He, Li-Hua Zhang, Qing Shen","doi":"10.1007/s10965-024-04156-4","DOIUrl":null,"url":null,"abstract":"<div><p>The crystallization kinetics behaviors of PVA (poly (vinyl alcohol))/TP (tea polyphenol) composites were studied. Results showed that the addition of TP component in PVA formed composites would reduce the crystallinity (%), leading to the formation of a lower Avrami exponent, <i>n</i>. Under the fixed cooling rate condition, the <i>n</i> values of Avrami and <i>α</i> values of Mo are both higher for the above composites with TP ingredient at 10–20%. Subsequently, the influence of the hydrogen bonding (H-bonding) in PVA/TP composites, pure PVA and non-hydrogen bonding (non-H-bonding) in such composites were further quantitatively assessed by analyzing the H-bonding factor, F%, in relation to different crystallization kinetic parameters including Avrami exponent <i>n</i>, <i>Z</i><sub><i>t</i></sub><i>, α</i> and <i>F(T)</i>. Results showed that the relationship of Avrami exponent <i>n</i> and <i>α</i> were presented as <b><i>n</i></b><b> = </b><b><i>-</i></b><i>a</i><sub><i>1</i></sub> + <i>b</i><sub><i>1</i></sub><b><i>F</i></b><sup><i>PVA/TP</i></sup><sub><i>H-bonding</i></sub><i>-c</i><sub><i>1</i></sub><b><i>F</i></b><sup><i>2PVA/TP</i></sup><sub><i>H-bonding</i></sub> and <b><i>α</i></b><b> = </b><b><i>-</i></b><i>a</i><sub><i>5</i></sub> + <i>b</i><sub><i>5</i></sub><b><i>F</i></b><sup><i>PVA/TP</i></sup><sub><i>H-bonding</i></sub><i>-c</i><sub><i>5</i></sub><b><i>F</i></b><sup><i>2PVA/TP</i></sup><sub><i>H-bonding</i></sub><i>.</i> The Z<sub>t</sub> was described as the functions like <b><i>Z</i></b><sub><b><i>t</i></b></sub> = <i>a</i><sub><i>2</i></sub><i>-b</i><sub><i>2</i></sub><i>e</i><sup><i>(</i><b><i>F</i></b><i>PVA/TP</i></sup><sub><i>H-bonding</i></sub><sup><i>−c</i></sup><sub><i>2</i></sub><sup><i>)/d</i></sup><i>, </i><b><i>Z</i></b><sub><b><i>t</i></b></sub><b> = </b><b><i>-</i></b><i>a</i><sub><i>3</i></sub> + <i>b</i><sub><i>3</i></sub><b><i>F</i></b><sup><i>PVA</i></sup><sub><i>H-bonding</i></sub><i>-C</i><sub><i>3</i></sub><b><i>F</i></b><sup><i>2PVA</i></sup><sub><i>H-bonding</i></sub><i>,</i> and <b><i>Zt</i></b> = <i>a</i><sub><i>4</i></sub><i>(</i><b><i>F</i></b><sub><i>non-H-bonding</i></sub><b><i>-</i></b><i>b</i><sub><i>4</i></sub><b><i>)</i></b><sup><i>c</i></sup><sub><i>4</i></sub>, respectively. The <i>F(T)</i> was presented as <b><i>F(T)</i></b><b> = </b><i>a</i><sub><i>6-</i></sub><i>b</i><sub><i>6</i></sub><b><i>F</i></b><sup><i>PVA/TP</i></sup><sub><i>H-bonding</i>+</sub><i>c</i><sub><i>6</i></sub><b><i>F</i></b><sup><i>2PVA/TP</i></sup><sub><i>H-bonding</i></sub>, where <i>a</i>, <i>b</i> and <i>c</i> are positive constants.</p></div>","PeriodicalId":658,"journal":{"name":"Journal of Polymer Research","volume":"31 10","pages":""},"PeriodicalIF":2.6000,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Quantitative evaluation of the hydrogen bonding effects on the crystallization kinetics of poly(vinyl alcohol)/tea polyphenol composites\",\"authors\":\"Xiao He, Li-Hua Zhang, Qing Shen\",\"doi\":\"10.1007/s10965-024-04156-4\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The crystallization kinetics behaviors of PVA (poly (vinyl alcohol))/TP (tea polyphenol) composites were studied. Results showed that the addition of TP component in PVA formed composites would reduce the crystallinity (%), leading to the formation of a lower Avrami exponent, <i>n</i>. Under the fixed cooling rate condition, the <i>n</i> values of Avrami and <i>α</i> values of Mo are both higher for the above composites with TP ingredient at 10–20%. Subsequently, the influence of the hydrogen bonding (H-bonding) in PVA/TP composites, pure PVA and non-hydrogen bonding (non-H-bonding) in such composites were further quantitatively assessed by analyzing the H-bonding factor, F%, in relation to different crystallization kinetic parameters including Avrami exponent <i>n</i>, <i>Z</i><sub><i>t</i></sub><i>, α</i> and <i>F(T)</i>. Results showed that the relationship of Avrami exponent <i>n</i> and <i>α</i> were presented as <b><i>n</i></b><b> = </b><b><i>-</i></b><i>a</i><sub><i>1</i></sub> + <i>b</i><sub><i>1</i></sub><b><i>F</i></b><sup><i>PVA/TP</i></sup><sub><i>H-bonding</i></sub><i>-c</i><sub><i>1</i></sub><b><i>F</i></b><sup><i>2PVA/TP</i></sup><sub><i>H-bonding</i></sub> and <b><i>α</i></b><b> = </b><b><i>-</i></b><i>a</i><sub><i>5</i></sub> + <i>b</i><sub><i>5</i></sub><b><i>F</i></b><sup><i>PVA/TP</i></sup><sub><i>H-bonding</i></sub><i>-c</i><sub><i>5</i></sub><b><i>F</i></b><sup><i>2PVA/TP</i></sup><sub><i>H-bonding</i></sub><i>.</i> The Z<sub>t</sub> was described as the functions like <b><i>Z</i></b><sub><b><i>t</i></b></sub> = <i>a</i><sub><i>2</i></sub><i>-b</i><sub><i>2</i></sub><i>e</i><sup><i>(</i><b><i>F</i></b><i>PVA/TP</i></sup><sub><i>H-bonding</i></sub><sup><i>−c</i></sup><sub><i>2</i></sub><sup><i>)/d</i></sup><i>, </i><b><i>Z</i></b><sub><b><i>t</i></b></sub><b> = </b><b><i>-</i></b><i>a</i><sub><i>3</i></sub> + <i>b</i><sub><i>3</i></sub><b><i>F</i></b><sup><i>PVA</i></sup><sub><i>H-bonding</i></sub><i>-C</i><sub><i>3</i></sub><b><i>F</i></b><sup><i>2PVA</i></sup><sub><i>H-bonding</i></sub><i>,</i> and <b><i>Zt</i></b> = <i>a</i><sub><i>4</i></sub><i>(</i><b><i>F</i></b><sub><i>non-H-bonding</i></sub><b><i>-</i></b><i>b</i><sub><i>4</i></sub><b><i>)</i></b><sup><i>c</i></sup><sub><i>4</i></sub>, respectively. The <i>F(T)</i> was presented as <b><i>F(T)</i></b><b> = </b><i>a</i><sub><i>6-</i></sub><i>b</i><sub><i>6</i></sub><b><i>F</i></b><sup><i>PVA/TP</i></sup><sub><i>H-bonding</i>+</sub><i>c</i><sub><i>6</i></sub><b><i>F</i></b><sup><i>2PVA/TP</i></sup><sub><i>H-bonding</i></sub>, where <i>a</i>, <i>b</i> and <i>c</i> are positive constants.</p></div>\",\"PeriodicalId\":658,\"journal\":{\"name\":\"Journal of Polymer Research\",\"volume\":\"31 10\",\"pages\":\"\"},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2024-10-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Polymer Research\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10965-024-04156-4\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Polymer Research","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10965-024-04156-4","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Quantitative evaluation of the hydrogen bonding effects on the crystallization kinetics of poly(vinyl alcohol)/tea polyphenol composites
The crystallization kinetics behaviors of PVA (poly (vinyl alcohol))/TP (tea polyphenol) composites were studied. Results showed that the addition of TP component in PVA formed composites would reduce the crystallinity (%), leading to the formation of a lower Avrami exponent, n. Under the fixed cooling rate condition, the n values of Avrami and α values of Mo are both higher for the above composites with TP ingredient at 10–20%. Subsequently, the influence of the hydrogen bonding (H-bonding) in PVA/TP composites, pure PVA and non-hydrogen bonding (non-H-bonding) in such composites were further quantitatively assessed by analyzing the H-bonding factor, F%, in relation to different crystallization kinetic parameters including Avrami exponent n, Zt, α and F(T). Results showed that the relationship of Avrami exponent n and α were presented as n = -a1 + b1FPVA/TPH-bonding-c1F2PVA/TPH-bonding and α = -a5 + b5FPVA/TPH-bonding-c5F2PVA/TPH-bonding. The Zt was described as the functions like Zt = a2-b2e(FPVA/TPH-bonding−c2)/d, Zt = -a3 + b3FPVAH-bonding-C3F2PVAH-bonding, and Zt = a4(Fnon-H-bonding-b4)c4, respectively. The F(T) was presented as F(T) = a6-b6FPVA/TPH-bonding+c6F2PVA/TPH-bonding, where a, b and c are positive constants.
期刊介绍：
Journal of Polymer Research provides a forum for the prompt publication of articles concerning the fundamental and applied research of polymers. Its great feature lies in the diversity of content which it encompasses, drawing together results from all aspects of polymer science and technology.
As polymer research is rapidly growing around the globe, the aim of this journal is to establish itself as a significant information tool not only for the international polymer researchers in academia but also for those working in industry. The scope of the journal covers a wide range of the highly interdisciplinary field of polymer science and technology, including:
polymer synthesis;
polymer reactions;
polymerization kinetics;
polymer physics;
morphology;
structure-property relationships;
polymer analysis and characterization;
physical and mechanical properties;
electrical and optical properties;
polymer processing and rheology;
application of polymers;
supramolecular science of polymers;
polymer composites.
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