V. Karankova, A. Radkevich, V. Torapava, A. Dashouk
{"title":"铁（III）羟基形式和硼酸对水溶液中钌-106 状态的影响","authors":"V. Karankova, A. Radkevich, V. Torapava, A. Dashouk","doi":"10.1134/S1066362224040039","DOIUrl":null,"url":null,"abstract":"<p>The work examines the state of <sup>106</sup>Ru in solutions simulating technological media and liquid radioactive waste from nuclear power plants with a VVER reactor, as well as the influence of the physicochemical state of the radionuclide on the efficiency of ion exchange and ultrafiltration treatment methods. During the study, the regions of existence of ionic and nonionic states of the radionuclide were explored in solutions of complex composition. In addition, the size distribution of particles containing <sup>106</sup>Ru were established. The formation of complex compounds of <sup>106</sup>Ru with polyborate ions in the neutral and slightly alkaline pH region has been shown, which leads to a decrease in the efficiency of decontamination of liquid radioactive waste from ruthenium radionuclides.</p>","PeriodicalId":747,"journal":{"name":"Radiochemistry","volume":"66 4","pages":"416 - 424"},"PeriodicalIF":0.9000,"publicationDate":"2024-10-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Influence of Iron(III) Hydroxo Forms and Boric Acid on the State of Ruthenium-106 in Aqueous Solutions\",\"authors\":\"V. Karankova, A. Radkevich, V. Torapava, A. Dashouk\",\"doi\":\"10.1134/S1066362224040039\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The work examines the state of <sup>106</sup>Ru in solutions simulating technological media and liquid radioactive waste from nuclear power plants with a VVER reactor, as well as the influence of the physicochemical state of the radionuclide on the efficiency of ion exchange and ultrafiltration treatment methods. During the study, the regions of existence of ionic and nonionic states of the radionuclide were explored in solutions of complex composition. In addition, the size distribution of particles containing <sup>106</sup>Ru were established. The formation of complex compounds of <sup>106</sup>Ru with polyborate ions in the neutral and slightly alkaline pH region has been shown, which leads to a decrease in the efficiency of decontamination of liquid radioactive waste from ruthenium radionuclides.</p>\",\"PeriodicalId\":747,\"journal\":{\"name\":\"Radiochemistry\",\"volume\":\"66 4\",\"pages\":\"416 - 424\"},\"PeriodicalIF\":0.9000,\"publicationDate\":\"2024-10-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Radiochemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1066362224040039\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Radiochemistry","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.1134/S1066362224040039","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Influence of Iron(III) Hydroxo Forms and Boric Acid on the State of Ruthenium-106 in Aqueous Solutions
The work examines the state of 106Ru in solutions simulating technological media and liquid radioactive waste from nuclear power plants with a VVER reactor, as well as the influence of the physicochemical state of the radionuclide on the efficiency of ion exchange and ultrafiltration treatment methods. During the study, the regions of existence of ionic and nonionic states of the radionuclide were explored in solutions of complex composition. In addition, the size distribution of particles containing 106Ru were established. The formation of complex compounds of 106Ru with polyborate ions in the neutral and slightly alkaline pH region has been shown, which leads to a decrease in the efficiency of decontamination of liquid radioactive waste from ruthenium radionuclides.
期刊介绍：
Radiochemistry is a journal that covers the theoretical and applied aspects of radiochemistry, including basic nuclear physical properties of radionuclides; chemistry of radioactive elements and their compounds; the occurrence and behavior of natural and artificial radionuclides in the environment; nuclear fuel cycle; radiochemical analysis methods and devices; production and isolation of radionuclides, synthesis of labeled compounds, new applications of radioactive tracers; radiochemical aspects of nuclear medicine; radiation chemistry and after-effects of nuclear transformations.
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