{"title":"具有高热导率和高介电常数的氮化硼纳米片/环氧纳米复合材料在储能应用中的应用","authors":"Brij Mohan Bharti, Kartikeya Dixit, Niraj Sinha","doi":"10.1007/s10965-024-04142-w","DOIUrl":null,"url":null,"abstract":"<div><p>Owing to their ability to provide thermal conduction as well as electrical insulation properties that are required for modern electronic devices and electrical systems, nano-fillers incorporated epoxy composites are being widely investigated. In this study, epoxy composites have been reinforced with boron nitride nanosheets (BNNSs) to achieve enhanced thermal conductivity and dielectric properties. Further, their change as a function of BNNSs concentration (weight %) has been investigated. BNNSs are synthesized using the bottom-up approach, while the nanocomposites of epoxy and BNNSs are fabricated with the help of a process involving stirring and ultrasonication. The results reveal that the incorporation of BNNSs leads to enhancement of thermal conductivity of the nanocomposites and it increases with an increase in the loading of BNNSs. The increase in thermal conductivity is 1.93 W/mK with 15 weight % of BNNSs, that is ~ 865% improvement over the pure epoxy. Also, an approximately 123% increase in dielectric constant has been observed. These results demonstrate the potential of BNNSs as nano-fillers in preparing epoxy nanocomposites with better thermal management and energy storage capacity.</p><h3>Graphical Abstract</h3>\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":658,"journal":{"name":"Journal of Polymer Research","volume":"31 10","pages":""},"PeriodicalIF":2.6000,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Boron nitride nanosheets/epoxy nanocomposites with high thermal conductivity and high dielectric constant for energy storage applications\",\"authors\":\"Brij Mohan Bharti, Kartikeya Dixit, Niraj Sinha\",\"doi\":\"10.1007/s10965-024-04142-w\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Owing to their ability to provide thermal conduction as well as electrical insulation properties that are required for modern electronic devices and electrical systems, nano-fillers incorporated epoxy composites are being widely investigated. In this study, epoxy composites have been reinforced with boron nitride nanosheets (BNNSs) to achieve enhanced thermal conductivity and dielectric properties. Further, their change as a function of BNNSs concentration (weight %) has been investigated. BNNSs are synthesized using the bottom-up approach, while the nanocomposites of epoxy and BNNSs are fabricated with the help of a process involving stirring and ultrasonication. The results reveal that the incorporation of BNNSs leads to enhancement of thermal conductivity of the nanocomposites and it increases with an increase in the loading of BNNSs. The increase in thermal conductivity is 1.93 W/mK with 15 weight % of BNNSs, that is ~ 865% improvement over the pure epoxy. Also, an approximately 123% increase in dielectric constant has been observed. These results demonstrate the potential of BNNSs as nano-fillers in preparing epoxy nanocomposites with better thermal management and energy storage capacity.</p><h3>Graphical Abstract</h3>\\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":658,\"journal\":{\"name\":\"Journal of Polymer Research\",\"volume\":\"31 10\",\"pages\":\"\"},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2024-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Polymer Research\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10965-024-04142-w\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Polymer Research","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10965-024-04142-w","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Boron nitride nanosheets/epoxy nanocomposites with high thermal conductivity and high dielectric constant for energy storage applications
Owing to their ability to provide thermal conduction as well as electrical insulation properties that are required for modern electronic devices and electrical systems, nano-fillers incorporated epoxy composites are being widely investigated. In this study, epoxy composites have been reinforced with boron nitride nanosheets (BNNSs) to achieve enhanced thermal conductivity and dielectric properties. Further, their change as a function of BNNSs concentration (weight %) has been investigated. BNNSs are synthesized using the bottom-up approach, while the nanocomposites of epoxy and BNNSs are fabricated with the help of a process involving stirring and ultrasonication. The results reveal that the incorporation of BNNSs leads to enhancement of thermal conductivity of the nanocomposites and it increases with an increase in the loading of BNNSs. The increase in thermal conductivity is 1.93 W/mK with 15 weight % of BNNSs, that is ~ 865% improvement over the pure epoxy. Also, an approximately 123% increase in dielectric constant has been observed. These results demonstrate the potential of BNNSs as nano-fillers in preparing epoxy nanocomposites with better thermal management and energy storage capacity.
期刊介绍:
Journal of Polymer Research provides a forum for the prompt publication of articles concerning the fundamental and applied research of polymers. Its great feature lies in the diversity of content which it encompasses, drawing together results from all aspects of polymer science and technology.
As polymer research is rapidly growing around the globe, the aim of this journal is to establish itself as a significant information tool not only for the international polymer researchers in academia but also for those working in industry. The scope of the journal covers a wide range of the highly interdisciplinary field of polymer science and technology, including:
polymer synthesis;
polymer reactions;
polymerization kinetics;
polymer physics;
morphology;
structure-property relationships;
polymer analysis and characterization;
physical and mechanical properties;
electrical and optical properties;
polymer processing and rheology;
application of polymers;
supramolecular science of polymers;
polymer composites.