锂金属阳极异位生长的原子和宏观视角之桥

IF 19.3 1区 材料科学 Q1 CHEMISTRY, PHYSICAL
Borong Li, Weicheng Zhang, Kang Yang, Long Li, Jing Luo, Qingqing Lin, Yichen Li, Zheyuan Liu*, Lingyun Li*, Yan Yu* and Chengkai Yang*, 
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引用次数: 0

摘要

研究锂在具有独特晶体结构的不同基底上的生长情况,对于将原子和宏观视角联系起来至关重要,可确保锂金属电池的长循环寿命和安全性。这项研究解释了:(1)受吸附-松弛机制影响的成核阶段;(2)从胚胎中获得树枝状形态的进化特征;(3)通过不同尺度的各种技术整合原子和宏观视角,以验证树枝状的进化。胚的异外延生长过程分为成核和生长两个主要阶段。在成核阶段,吸附型基底表现出平均相互作用能和比应力能相对较低的特点。在生长阶段,吸附型基底倾向于促进多层生长。这项研究为锂金属电池的设计和材料选择提供了可能,有助于开发更安全、更高效、更持久的储能系统。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Bridging Atomic and Macroscopic Perspectives on Heteroepitaxial Growth in Lithium Metal Anodes

Bridging Atomic and Macroscopic Perspectives on Heteroepitaxial Growth in Lithium Metal Anodes

Studying lithium growth on diverse substrates with unique crystal structures is crucial for linking atomic and macroscopic views, which ensures a long cycle life and safety in lithium metal batteries. This work provides explanations on (1) the stages of nucleation, which are influenced by the adsorption-relaxation mechanism, (2) acquiring evolved traits of dendritic morphology from the embryo, and (3) the integration of the atomic and macroscopic perspectives through a variety of techniques at different scales to validate dendrite evolution. The heteroepitaxial growth process of the embryos is divided into two principal stages: nucleation and growth. The adsorption-type substrates exhibit characteristics of relatively lower average interaction energy and specific stress energy during the nucleation stage. At the growth stage, the adsorption-type substrate tends to facilitate multilayer growth. This work provides potential to design and material selection for lithium metal batteries, contributing to the development of safer, more efficient, and longer-lasting energy storage systems.

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来源期刊
ACS Energy Letters
ACS Energy Letters Energy-Renewable Energy, Sustainability and the Environment
CiteScore
31.20
自引率
5.00%
发文量
469
审稿时长
1 months
期刊介绍: ACS Energy Letters is a monthly journal that publishes papers reporting new scientific advances in energy research. The journal focuses on topics that are of interest to scientists working in the fundamental and applied sciences. Rapid publication is a central criterion for acceptance, and the journal is known for its quick publication times, with an average of 4-6 weeks from submission to web publication in As Soon As Publishable format. ACS Energy Letters is ranked as the number one journal in the Web of Science Electrochemistry category. It also ranks within the top 10 journals for Physical Chemistry, Energy & Fuels, and Nanoscience & Nanotechnology. The journal offers several types of articles, including Letters, Energy Express, Perspectives, Reviews, Editorials, Viewpoints and Energy Focus. Additionally, authors have the option to submit videos that summarize or support the information presented in a Perspective or Review article, which can be highlighted on the journal's website. ACS Energy Letters is abstracted and indexed in Chemical Abstracts Service/SciFinder, EBSCO-summon, PubMed, Web of Science, Scopus and Portico.
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