π 键解离能：C-C、C-N 和 C-O

IF 3.3 2区化学 Q1 CHEMISTRY, ORGANIC

Journal of Organic Chemistry Pub Date : 2024-10-10 DOI:10.1021/acs.joc.4c01925

Steven R. Kass

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引用次数: 0

摘要

单键、双键和三键离解能是有用的量，但学生和实际化学家通常不知道它们的代表值或获取方法。本文提供了部分 π 键能，并讨论了测定它们的一般方法。本文还讨论了氢化热、键解离能和 π 键强度之间的关系。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

π-Bond Dissociation Energies: C–C, C–N, and C–O

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π-Bond Dissociation Energies: C–C, C–N, and C–O

Single, double, and triple bond dissociation energies are useful quantities, but students and practicing chemists commonly do not know representative values or how they are obtained. In this paper, select π-bond energies are provided and general methods for their determination are discussed. Relationships between heats of hydrogenation, bond dissociation energies, and π-bond strengths are also addressed.

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来源期刊

Journal of Organic Chemistry 化学-有机化学

CiteScore

6.20

自引率

11.10%

发文量

1467

审稿时长

2 months

期刊介绍： Journal of Organic Chemistry welcomes original contributions of fundamental research in all branches of the theory and practice of organic chemistry. In selecting manuscripts for publication, the editors place emphasis on the quality and novelty of the work, as well as the breadth of interest to the organic chemistry community.