使用易于获取的有机铋 (V) 试剂对烯烃进行芳基化反官能度处理

IF 19.1 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Chem Pub Date : 2024-10-10 DOI:10.1016/j.chempr.2024.09.014

Nicholas D. Chiappini

引用次数: 0

摘要

在本期《化学》杂志上，Li 和 Rawal 介绍了 Ar3BiCl2 作为方便的试剂在利用可见光或近视光对烯烃进行芳基二官能化时的一种令人兴奋的新应用。该方法不受空气和湿度的影响，能快速、简便地对多种官能化烯进行叠氮、氰和氯芳基化反应。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Arylative difunctionalization of olefins using easily accessed organobismuth (V) reagents

In this issue of Chem, Li and Rawal present an exciting new application of Ar₃BiCl₂ as convenient reagents for arylative difunctionalization of alkenes using visible or near-visible light. Unburdened by air and moisture sensitivity, the method affords rapid and facile azido-, cyano-, and chloro-arylation of a bevy of functionalized alkenes.

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来源期刊

Chem Environmental Science-Environmental Chemistry

CiteScore

32.40

自引率

1.30%

发文量

281

期刊介绍： Chem, affiliated with Cell as its sister journal, serves as a platform for groundbreaking research and illustrates how fundamental inquiries in chemistry and its related fields can contribute to addressing future global challenges. It was established in 2016, and is currently edited by Robert Eagling.