由应变环和高形成热四氮唑组成的组合能量材料。

IF 3 4区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

ChemPlusChem Pub Date : 2024-10-09 DOI:10.1002/cplu.202400164

Jake E Zuckerman, Montgomery C St Myer, Matthias Zeller, Davin G Piercey

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引用次数: 0

摘要

通过叠氮化氰与含应变环的伯胺和仲胺反应，分离出了从应变环和胺四唑中获得能量的高能分子。对这些材料进行偶氮偶联，可获得新型高氮高能材料，其灵敏度非常高。所有化合物都通过红外光谱、核磁共振、单晶 X 射线晶体学和高分辨率质谱法进行了化学鉴定。实验测定了它们的冲击和摩擦灵敏度，并计算了它们的能量性能。

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Combination Energetic Materials Consisting of Strained Rings Combined with High Heat of Formation Tetrazoles.

The reaction of cyanogen azide with strained-ring containing primary and secondary amines led to the isolation of energetic molecules deriving their energy content from both strained rings as well as aminotetrazoles. Azo-coupling of these materials afforded novel high-nitrogen energetic materials of very high sensitivity. All compounds were chemically characterized by IR, NMR, single-crystal X-ray crystallography, and high-resolution mass spectrometry. Their impact and friction sensitivities were experimentally determined, and their energetic performances were calculated.

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来源期刊

ChemPlusChem CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

5.90

自引率

0.00%

发文量

200

审稿时长

1 months

期刊介绍： ChemPlusChem is a peer-reviewed, general chemistry journal that brings readers the very best in multidisciplinary research centering on chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. Fully comprehensive in its scope, ChemPlusChem publishes articles covering new results from at least two different aspects (subfields) of chemistry or one of chemistry and one of another scientific discipline (one chemistry topic plus another one, hence the title ChemPlusChem). All suitable submissions undergo balanced peer review by experts in the field to ensure the highest quality, originality, relevance, significance, and validity.