{"title":"通过多阳离子晶格工程加速磷酸铁锂中的锂离子扩散","authors":"Xinxin Wang, Anyang Yu, Tian Jiang, Shijun Yuan, Qi Fan, Qingyu Xu","doi":"10.1002/adma.202410482","DOIUrl":null,"url":null,"abstract":"<p><p>Despite the widespread commercialization of LiFePO<sub>4</sub> as cathodes in lithium-ion batteries, the rigid 1D Li-ion diffusion channel along the [010] direction strongly limits its fast charge and discharge performance. Herein, lattice engineering is developed by the planar triangle BO<sub>3</sub> <sup>3-</sup> substitution on tetrahedron PO<sub>4</sub> <sup>3-</sup> to induce flexibility in the Li-ion diffusion channels, which are broadened simultaneously. The planar structure of BO<sub>3</sub> <sup>3-</sup> may further provide additional paths between the channels. With these synergetic contributions, LiFe(PO<sub>4</sub>)<sub>0.98</sub>(BO<sub>3</sub>)<sub>0.02</sub> shows the best performance, which delivers the high-rate capacity (66.8 mAh g<sup>-1</sup> at 50 C) and long cycle stability (ultra-low capacity loss of 0.003% every cycle at 10 C) at 25 °C. Furthermore, excellent rate performance (34.0 mAh g<sup>-1</sup> at 40 C) and capacity retention (no capacity loss after 2500 cycles at 10 C) at -20 °C are realized.</p>","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":null,"pages":null},"PeriodicalIF":27.4000,"publicationDate":"2024-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Accelerating Li-Ion Diffusion in LiFePO<sub>4</sub> by Polyanion Lattice Engineering.\",\"authors\":\"Xinxin Wang, Anyang Yu, Tian Jiang, Shijun Yuan, Qi Fan, Qingyu Xu\",\"doi\":\"10.1002/adma.202410482\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Despite the widespread commercialization of LiFePO<sub>4</sub> as cathodes in lithium-ion batteries, the rigid 1D Li-ion diffusion channel along the [010] direction strongly limits its fast charge and discharge performance. Herein, lattice engineering is developed by the planar triangle BO<sub>3</sub> <sup>3-</sup> substitution on tetrahedron PO<sub>4</sub> <sup>3-</sup> to induce flexibility in the Li-ion diffusion channels, which are broadened simultaneously. The planar structure of BO<sub>3</sub> <sup>3-</sup> may further provide additional paths between the channels. With these synergetic contributions, LiFe(PO<sub>4</sub>)<sub>0.98</sub>(BO<sub>3</sub>)<sub>0.02</sub> shows the best performance, which delivers the high-rate capacity (66.8 mAh g<sup>-1</sup> at 50 C) and long cycle stability (ultra-low capacity loss of 0.003% every cycle at 10 C) at 25 °C. Furthermore, excellent rate performance (34.0 mAh g<sup>-1</sup> at 40 C) and capacity retention (no capacity loss after 2500 cycles at 10 C) at -20 °C are realized.</p>\",\"PeriodicalId\":114,\"journal\":{\"name\":\"Advanced Materials\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":27.4000,\"publicationDate\":\"2024-10-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advanced Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1002/adma.202410482\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Materials","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1002/adma.202410482","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
尽管作为锂离子电池正极的 LiFePO4 已广泛商业化,但沿 [010] 方向的刚性一维锂离子扩散通道严重限制了其快速充放电性能。在这里,通过在四面体 PO4 3 上取代平面三角形 BO3 3,发展了晶格工程学,从而使锂离子扩散通道具有灵活性,并同时拓宽了锂离子扩散通道。BO3 3- 的平面结构可进一步提供通道之间的额外路径。在这些协同作用下,LiFe(PO4)0.98(BO3)0.02 表现出了最佳性能,在 25 °C时可提供高倍率容量(50 C 时为 66.8 mAh g-1)和长周期稳定性(10 C 时每周期 0.003% 的超低容量损失)。此外,在零下 20 °C时,它还具有出色的速率性能(40 °C时为 34.0 mAh g-1)和容量保持率(10 °C时循环 2500 次后无容量损失)。
Accelerating Li-Ion Diffusion in LiFePO4 by Polyanion Lattice Engineering.
Despite the widespread commercialization of LiFePO4 as cathodes in lithium-ion batteries, the rigid 1D Li-ion diffusion channel along the [010] direction strongly limits its fast charge and discharge performance. Herein, lattice engineering is developed by the planar triangle BO33- substitution on tetrahedron PO43- to induce flexibility in the Li-ion diffusion channels, which are broadened simultaneously. The planar structure of BO33- may further provide additional paths between the channels. With these synergetic contributions, LiFe(PO4)0.98(BO3)0.02 shows the best performance, which delivers the high-rate capacity (66.8 mAh g-1 at 50 C) and long cycle stability (ultra-low capacity loss of 0.003% every cycle at 10 C) at 25 °C. Furthermore, excellent rate performance (34.0 mAh g-1 at 40 C) and capacity retention (no capacity loss after 2500 cycles at 10 C) at -20 °C are realized.
期刊介绍:
Advanced Materials, one of the world's most prestigious journals and the foundation of the Advanced portfolio, is the home of choice for best-in-class materials science for more than 30 years. Following this fast-growing and interdisciplinary field, we are considering and publishing the most important discoveries on any and all materials from materials scientists, chemists, physicists, engineers as well as health and life scientists and bringing you the latest results and trends in modern materials-related research every week.