Organic/inorganic heterostructures templated by interfacial instability-driven BCP colloids in deformable emulsion droplets†

Hybrid heterostructure materials have received considerable attention due to the integration of each component and abundant functional applications in micromotors, catalysis, photothermal therapy, drug delivery, and bioimaging. However, the preparation of organic/inorganic heterostructure nanoparticles (HSNPs) with high quality still remains a remarkable challenge since thermodynamically metastable structures usually coexist, resulting in a lack of organic scaffolds with extreme uniformity both in shape and size distribution. Here, we prepared polystyrene-block-poly(4-vinylpyridine) (PS-b-P4VP) block copolymer (BCP) core–shell spherical colloids driven by interfacial instability of soft and deformable emulsion droplets. Ultra-low interfacial tension was achieved through the co-adsorption of BCP segments and sodium dodecyl sulfate (SDS) surfactant, which had a strong affinity with the P4VP segment at the interface of the emulsified droplets. The excellent and homogeneous BCP colloids were further utilized as organic scaffolds to selectively grow a functional SiO₂ layer on the surface of the BCP spherical colloids, producing BCP/SiO₂ HSNPs with highly uniform shape and size distribution originating from the PS-b-P4VP scaffolds, thus providing an efficient and general strategy to construct and design organic/inorganic HSNPs with diverse applications.