在 Co(III) 和 Fe(III) 复合物中，通过键重排和臂旋转，单个 H 键引发了 Et3NH+ 周围裂隙的形成

IF 3.3 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2024-10-09 DOI:10.1039/D4DT02515F

Somnath Paik and Manabendra Ray

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引用次数: 0

摘要

三乙基铵中 N-H 的单 H 键能在惰性 Co(III) 复合物中引发大规模的结构重排，而四乙基铵却不能。这种重排提供了一种从光谱学角度区分两种类似阳离子的新方法。这一过程在易变铁（III）中是相同的，而且是瞬间发生的，没有任何光谱变化。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

A single H-bond triggers the formation of a cleft around Et3NH+ through bond rearrangement and rotations of arms in both Co(iii) and Fe(iii) complexes†

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A single H-bond triggers the formation of a cleft around Et3NH+ through bond rearrangement and rotations of arms in both Co(iii) and Fe(iii) complexes†

The single H-bond capable N–H in triethylammonium triggers massive structural rearrangement in an inert Co(III) complex that tetraethylammonium cannot. The rearrangement provides a new way to distinguish two similar cations spectroscopically. The process is identical and instantaneous with labile iron(III) without any spectroscopic change.

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.