基于掺氮碳材料开发高性能钾离子电池阳极的最新进展

IF 13 2区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Small Pub Date : 2024-10-07 DOI:10.1002/smll.202406630
Yonghuan Fu, Yulian Dong, Yonglong Shen, Huaping Zhao, Guosheng Shao, Yong Lei
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引用次数: 0

摘要

由于碳基材料具有低电位(对 K/K+)、良好的循环稳定性和可持续性,因此是钾离子电池(PIB)的最佳阳极材料之一。然而,由于碳基阳极反应动力学迟缓且容量较低,使用现有碳基材料实现高倍率性能和出色的容量具有挑战性。事实证明,掺氮是提高碳基材料作为 PIB 阳极的速率性能和容量的有效方法。然而,目前还缺乏一篇系统总结氮掺杂类型的特点和功能的综述文章。从这个意义上讲,有必要对掺氮(N-掺杂)碳材料中的掺氮类型进行基本了解。本综述概述了掺氮碳基材料的类型、功能和应用。然后,总结了掺氮碳作为 PIBs 阳极活性和改性材料在合成、性能和应用方面的最新进展。最后,总结了掺氮的主要特点和功能,并概述了该领域未来研究的重要前景。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Recent Advances in Developing High-Performance Anode for Potassium-Ion Batteries based on Nitrogen-Doped Carbon Materials

Recent Advances in Developing High-Performance Anode for Potassium-Ion Batteries based on Nitrogen-Doped Carbon Materials

Recent Advances in Developing High-Performance Anode for Potassium-Ion Batteries based on Nitrogen-Doped Carbon Materials

Owing to the low potential (vs K/K+), good cycling stability, and sustainability, carbon-based materials stand out as one of the optimal anode materials for potassium-ion batteries (PIBs). However, achieving high-rate performance and excellent capacity with the current carbon-based materials is challenging because of the sluggish reaction kinetics and the low capacity of carbon-based anodes. The doping of nitrogen proves to be an effective way to improve the rate performance and capacity of carbon-based materials as PIB anode. However, a review article is lacking in systematically summarizing the features and functions of nitrogen doping types. In this sense, it is necessary to provide a fundamental understanding of doped nitrogen types in nitrogen-doped(N-doped) carbon materials. The types, functions, and applications of nitrogen-doped carbon-based materials are overviewed in this review. Then, the recent advances in the synthesis, properties, and applications of N-doped carbon as both active and modification materials for PIBs anode are summarized. Finally, doped nitrogen's main features and functions are concluded, and critical perspectives for future research in this field are outlined.

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来源期刊
Small
Small 工程技术-材料科学:综合
CiteScore
17.70
自引率
3.80%
发文量
1830
审稿时长
2.1 months
期刊介绍: Small serves as an exceptional platform for both experimental and theoretical studies in fundamental and applied interdisciplinary research at the nano- and microscale. The journal offers a compelling mix of peer-reviewed Research Articles, Reviews, Perspectives, and Comments. With a remarkable 2022 Journal Impact Factor of 13.3 (Journal Citation Reports from Clarivate Analytics, 2023), Small remains among the top multidisciplinary journals, covering a wide range of topics at the interface of materials science, chemistry, physics, engineering, medicine, and biology. Small's readership includes biochemists, biologists, biomedical scientists, chemists, engineers, information technologists, materials scientists, physicists, and theoreticians alike.
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