Chenglin Zheng, Wenjie Yang, Yujie Chen, Xiuhong Li, Wentao Sun, Laifeng Li, Bo Guan, Jingxia Wang, Lei Jiang
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引用次数: 0
摘要
聚合物稳定蓝相(Polymer stabilized blue phase,PSBP)液晶因其宽广的温度范围以及在柔性显示器、多模式监视器和无镜面激光器中的潜在应用而受到广泛关注。温度会对 PSBP 的结构/光学性能产生重要影响,但目前还缺乏关于热诱导形变及其对 PSBP 光学性能影响的详细研究。本文通过变温超小角度 X 射线衍射、Kossel 衍射和偏光光学显微镜,对不同聚合物含量的 PSBP 结构/光学性能的热诱导演化进行了原位表征。反射波长的移动和 Kossel 图的演变揭示了 PSBP 立方晶格的受限变形,这主要归因于热诱导的相变/非聚合成分的分离。基于有限的变形能力,增加聚合物含量可提高 PSBP 的热稳定性。这项工作对新型功能材料的设计具有重要意义,为制备具有高稳定性和光学品质的光子晶体软材料铺平了道路。
In Situ Characterization of Thermal-Induced Evolution of Structure/Optical Properties of Heterogeneous 3D Chiral Soft Photonic Crystal Polymer
Polymer stabilized blue phase (PSBP) liquid crystal has aroused wide attention due to its broad temperature range and potential applications in flexible display, multi-mode monitor, and mirrorless laser based on its well-compatible stability and multi-responsiveness, such as electricity, humidity, and temperature. Temperature produces an important effect on the structure/optical properties of PSBP, but there lack of detailed investigation on thermal-induced deformation and its influence on the optical performance of PSBP. Here, the thermal-induced evolution of structure/optical properties of PSBP with different polymer content is in situ characterized by variable-temperature ultra-small-angle X-ray diffraction, Kossel diffraction, and polarized optical microscopy. A restricted deformation of PSBP cubic lattice is revealed by the shift of reflective wavelength and evolution of Kossel diagrams, which is mainly attributed to the thermal-induced phase transition/separation of non-polymerized components. The thermal stability of PSBP is improved by increased polymer content based on the limited deformation ability. This work is significant for the design of novel functional material, which paves the way for the preparation of photonic crystal soft materials with high stability and optical quality.
期刊介绍:
Firmly established as a top-tier materials science journal, Advanced Functional Materials reports breakthrough research in all aspects of materials science, including nanotechnology, chemistry, physics, and biology every week.
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