评估电池中的阴极-电解质间相

IF 49.7 1区 材料科学 Q1 ENERGY & FUELS
Jie Xiao, Nicole Adelstein, Yujing Bi, Wenjuan Bian, Jordi Cabana, Corie L. Cobb, Yi Cui, Shen J. Dillon, Marca M. Doeff, Saiful M. Islam, Kevin Leung, Mengya Li, Feng Lin, Jun Liu, Hongmei Luo, Amy C. Marschilok, Ying Shirley Meng, Yue Qi, Ritu Sahore, Kayla G. Sprenger, Robert C. Tenent, Michael F. Toney, Wei Tong, Liwen F. Wan, Chongmin Wang, Stephen E. Weitzner, Bingbin Wu, Yaobin Xu
{"title":"评估电池中的阴极-电解质间相","authors":"Jie Xiao, Nicole Adelstein, Yujing Bi, Wenjuan Bian, Jordi Cabana, Corie L. Cobb, Yi Cui, Shen J. Dillon, Marca M. Doeff, Saiful M. Islam, Kevin Leung, Mengya Li, Feng Lin, Jun Liu, Hongmei Luo, Amy C. Marschilok, Ying Shirley Meng, Yue Qi, Ritu Sahore, Kayla G. Sprenger, Robert C. Tenent, Michael F. Toney, Wei Tong, Liwen F. Wan, Chongmin Wang, Stephen E. Weitzner, Bingbin Wu, Yaobin Xu","doi":"10.1038/s41560-024-01639-y","DOIUrl":null,"url":null,"abstract":"The cathode–electrolyte interphase plays a pivotal role in determining the usable capacity and cycling stability of electrochemical cells, yet it is overshadowed by its counterpart, the solid–electrolyte interphase. This is primarily due to the prevalence of side reactions, particularly at low potentials on the negative electrode, especially in state-of-the-art Li-ion batteries where the charge cutoff voltage is limited. However, as the quest for high-energy battery technologies intensifies, there is a pressing need to advance the study of cathode–electrolyte interphase properties. Here, we present a comprehensive approach to analyse the cathode–electrolyte interphase in battery systems. We underscore the importance of employing model cathode materials and coin cell protocols to establish baseline performance. Additionally, we delve into the factors behind the inconsistent and occasionally controversial findings related to the cathode–electrolyte interphase. We also address the challenges and opportunities in characterizing and simulating the cathode–electrolyte interphase, offering potential solutions to enhance its relevance to real-world applications. The cathode–electrolyte interphase (CEI) is vital for battery cell capacity and stability but receives less attention than the solid–electrolyte interphase. The authors review CEI properties, emphasize using model cathode materials and coin cell protocols, and address challenges and opportunities in characterizing and simulating CEI for real-world applications.","PeriodicalId":19073,"journal":{"name":"Nature Energy","volume":"9 12","pages":"1463-1473"},"PeriodicalIF":49.7000,"publicationDate":"2024-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Assessing cathode–electrolyte interphases in batteries\",\"authors\":\"Jie Xiao, Nicole Adelstein, Yujing Bi, Wenjuan Bian, Jordi Cabana, Corie L. Cobb, Yi Cui, Shen J. Dillon, Marca M. Doeff, Saiful M. Islam, Kevin Leung, Mengya Li, Feng Lin, Jun Liu, Hongmei Luo, Amy C. Marschilok, Ying Shirley Meng, Yue Qi, Ritu Sahore, Kayla G. Sprenger, Robert C. Tenent, Michael F. Toney, Wei Tong, Liwen F. Wan, Chongmin Wang, Stephen E. Weitzner, Bingbin Wu, Yaobin Xu\",\"doi\":\"10.1038/s41560-024-01639-y\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The cathode–electrolyte interphase plays a pivotal role in determining the usable capacity and cycling stability of electrochemical cells, yet it is overshadowed by its counterpart, the solid–electrolyte interphase. This is primarily due to the prevalence of side reactions, particularly at low potentials on the negative electrode, especially in state-of-the-art Li-ion batteries where the charge cutoff voltage is limited. However, as the quest for high-energy battery technologies intensifies, there is a pressing need to advance the study of cathode–electrolyte interphase properties. Here, we present a comprehensive approach to analyse the cathode–electrolyte interphase in battery systems. We underscore the importance of employing model cathode materials and coin cell protocols to establish baseline performance. Additionally, we delve into the factors behind the inconsistent and occasionally controversial findings related to the cathode–electrolyte interphase. We also address the challenges and opportunities in characterizing and simulating the cathode–electrolyte interphase, offering potential solutions to enhance its relevance to real-world applications. The cathode–electrolyte interphase (CEI) is vital for battery cell capacity and stability but receives less attention than the solid–electrolyte interphase. The authors review CEI properties, emphasize using model cathode materials and coin cell protocols, and address challenges and opportunities in characterizing and simulating CEI for real-world applications.\",\"PeriodicalId\":19073,\"journal\":{\"name\":\"Nature Energy\",\"volume\":\"9 12\",\"pages\":\"1463-1473\"},\"PeriodicalIF\":49.7000,\"publicationDate\":\"2024-10-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nature Energy\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.nature.com/articles/s41560-024-01639-y\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nature Energy","FirstCategoryId":"88","ListUrlMain":"https://www.nature.com/articles/s41560-024-01639-y","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
引用次数: 0

摘要

阴极-电解质相间层在决定电化学电池的可用容量和循环稳定性方面发挥着关键作用,但与之相对应的固态-电解质相间层相比,阴极-电解质相间层的作用却黯然失色。这主要是由于副反应的普遍存在,特别是在负极电位较低时,尤其是在充电截止电压有限的最先进锂离子电池中。然而,随着人们对高能电池技术的不断追求,迫切需要推进对正极-电解质相间特性的研究。在此,我们提出了一种分析电池系统中阴极-电解质相间的综合方法。我们强调了采用模型阴极材料和纽扣电池协议建立基线性能的重要性。此外,我们还深入探讨了与阴极-电解质相生相克相关的研究结果不一致且偶尔存在争议的背后因素。我们还探讨了表征和模拟阴极-电解质相间过程所面临的挑战和机遇,并提供了潜在的解决方案,以提高其与实际应用的相关性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Assessing cathode–electrolyte interphases in batteries

Assessing cathode–electrolyte interphases in batteries

Assessing cathode–electrolyte interphases in batteries
The cathode–electrolyte interphase plays a pivotal role in determining the usable capacity and cycling stability of electrochemical cells, yet it is overshadowed by its counterpart, the solid–electrolyte interphase. This is primarily due to the prevalence of side reactions, particularly at low potentials on the negative electrode, especially in state-of-the-art Li-ion batteries where the charge cutoff voltage is limited. However, as the quest for high-energy battery technologies intensifies, there is a pressing need to advance the study of cathode–electrolyte interphase properties. Here, we present a comprehensive approach to analyse the cathode–electrolyte interphase in battery systems. We underscore the importance of employing model cathode materials and coin cell protocols to establish baseline performance. Additionally, we delve into the factors behind the inconsistent and occasionally controversial findings related to the cathode–electrolyte interphase. We also address the challenges and opportunities in characterizing and simulating the cathode–electrolyte interphase, offering potential solutions to enhance its relevance to real-world applications. The cathode–electrolyte interphase (CEI) is vital for battery cell capacity and stability but receives less attention than the solid–electrolyte interphase. The authors review CEI properties, emphasize using model cathode materials and coin cell protocols, and address challenges and opportunities in characterizing and simulating CEI for real-world applications.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Nature Energy
Nature Energy Energy-Energy Engineering and Power Technology
CiteScore
75.10
自引率
1.10%
发文量
193
期刊介绍: Nature Energy is a monthly, online-only journal committed to showcasing the most impactful research on energy, covering everything from its generation and distribution to the societal implications of energy technologies and policies. With a focus on exploring all facets of the ongoing energy discourse, Nature Energy delves into topics such as energy generation, storage, distribution, management, and the societal impacts of energy technologies and policies. Emphasizing studies that push the boundaries of knowledge and contribute to the development of next-generation solutions, the journal serves as a platform for the exchange of ideas among stakeholders at the forefront of the energy sector. Maintaining the hallmark standards of the Nature brand, Nature Energy boasts a dedicated team of professional editors, a rigorous peer-review process, meticulous copy-editing and production, rapid publication times, and editorial independence. In addition to original research articles, Nature Energy also publishes a range of content types, including Comments, Perspectives, Reviews, News & Views, Features, and Correspondence, covering a diverse array of disciplines relevant to the field of energy.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信