Anuj Kumar , Alagarsamy S.K. Kumar , Ganeshraja A. Sundaram , Felipe Martins de Souza , Ram K. Gupta , Phuong V. Pham
{"title":"挖掘硼吩的潜力:合成、特性和应用方面的最新进展","authors":"Anuj Kumar , Alagarsamy S.K. Kumar , Ganeshraja A. Sundaram , Felipe Martins de Souza , Ram K. Gupta , Phuong V. Pham","doi":"10.1016/j.ccr.2024.216246","DOIUrl":null,"url":null,"abstract":"<div><div>Boron (B), located in close proximity to carbon and positioned between metals and non-metals in the periodic table, is an element that exhibits exceptional chemical and physical versatility. It can be effectively managed to create flat structures with small dimensions, known as borophene, which possess fascinating features. In the ever-expanding landscape of two-dimensional materials, borophene has recently emerged as a compelling focus of research, captivating the interest of scientists globally. Endowed with an extraordinary atomic structure and remarkable properties, borophene stands poised to unlock a multitude of breakthroughs across diverse domains, including supercapacitors, batteries, hydrogen storage, fuel cells, water splitting, biomedical, and beyond. This review provides a comprehensive overview of theoretical and practical advances in borophene synthesis, as well as its unique properties and applications in a variety of fields. This overview describes the decade-long effort to understand the structures of B-clusters, which vary in size, as well as the borophene synthesis strategies, which include bottom-up and up-down approaches. Furthermore, it aims to shed light on recent advancements while delineating future avenues for research and innovation in this burgeoning field.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216246"},"PeriodicalIF":20.3000,"publicationDate":"2024-10-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Unlocking the potential of borophene: Recent progress in synthesis, properties, and applications\",\"authors\":\"Anuj Kumar , Alagarsamy S.K. Kumar , Ganeshraja A. Sundaram , Felipe Martins de Souza , Ram K. Gupta , Phuong V. Pham\",\"doi\":\"10.1016/j.ccr.2024.216246\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Boron (B), located in close proximity to carbon and positioned between metals and non-metals in the periodic table, is an element that exhibits exceptional chemical and physical versatility. It can be effectively managed to create flat structures with small dimensions, known as borophene, which possess fascinating features. In the ever-expanding landscape of two-dimensional materials, borophene has recently emerged as a compelling focus of research, captivating the interest of scientists globally. Endowed with an extraordinary atomic structure and remarkable properties, borophene stands poised to unlock a multitude of breakthroughs across diverse domains, including supercapacitors, batteries, hydrogen storage, fuel cells, water splitting, biomedical, and beyond. This review provides a comprehensive overview of theoretical and practical advances in borophene synthesis, as well as its unique properties and applications in a variety of fields. This overview describes the decade-long effort to understand the structures of B-clusters, which vary in size, as well as the borophene synthesis strategies, which include bottom-up and up-down approaches. Furthermore, it aims to shed light on recent advancements while delineating future avenues for research and innovation in this burgeoning field.</div></div>\",\"PeriodicalId\":289,\"journal\":{\"name\":\"Coordination Chemistry Reviews\",\"volume\":\"523 \",\"pages\":\"Article 216246\"},\"PeriodicalIF\":20.3000,\"publicationDate\":\"2024-10-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Coordination Chemistry Reviews\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0010854524005927\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Coordination Chemistry Reviews","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0010854524005927","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Unlocking the potential of borophene: Recent progress in synthesis, properties, and applications
Boron (B), located in close proximity to carbon and positioned between metals and non-metals in the periodic table, is an element that exhibits exceptional chemical and physical versatility. It can be effectively managed to create flat structures with small dimensions, known as borophene, which possess fascinating features. In the ever-expanding landscape of two-dimensional materials, borophene has recently emerged as a compelling focus of research, captivating the interest of scientists globally. Endowed with an extraordinary atomic structure and remarkable properties, borophene stands poised to unlock a multitude of breakthroughs across diverse domains, including supercapacitors, batteries, hydrogen storage, fuel cells, water splitting, biomedical, and beyond. This review provides a comprehensive overview of theoretical and practical advances in borophene synthesis, as well as its unique properties and applications in a variety of fields. This overview describes the decade-long effort to understand the structures of B-clusters, which vary in size, as well as the borophene synthesis strategies, which include bottom-up and up-down approaches. Furthermore, it aims to shed light on recent advancements while delineating future avenues for research and innovation in this burgeoning field.
期刊介绍:
Coordination Chemistry Reviews offers rapid publication of review articles on current and significant topics in coordination chemistry, encompassing organometallic, supramolecular, theoretical, and bioinorganic chemistry. It also covers catalysis, materials chemistry, and metal-organic frameworks from a coordination chemistry perspective. Reviews summarize recent developments or discuss specific techniques, welcoming contributions from both established and emerging researchers.
The journal releases special issues on timely subjects, including those featuring contributions from specific regions or conferences. Occasional full-length book articles are also featured. Additionally, special volumes cover annual reviews of main group chemistry, transition metal group chemistry, and organometallic chemistry. These comprehensive reviews are vital resources for those engaged in coordination chemistry, further establishing Coordination Chemistry Reviews as a hub for insightful surveys in inorganic and physical inorganic chemistry.