{"title":"封面：通过扩展体系的能量分解分析揭示五环醚衍生物在硅和锗表面的反应趋势（欧洲有机化学杂志 37/2024）","authors":"Franz Thiemann, Hendrik Weiske, Ralf Tonner-Zech","doi":"10.1002/ejoc.202483701","DOIUrl":null,"url":null,"abstract":"<p><b>The Front Cover</b> illustrates the S<sub>N</sub>2-like ring-opening reactions of THF derivatives with the chalcogen elements O, S, Se and Te on both Si(001) and Ge(001) surfaces. The periodic table at the back embodies the trends presented in the work. On the left, the deformation density of the first NOCV in the THF precursor structure showcases the charge transfer towards the surface. The across-trench product of the tellurium derivative is shown on the right. The center features the across-trench transition state geometry of THSe with a deformation density indicating an S<sub>N</sub>2-like reaction. More information can be found in the Research Article by R. Tonner-Zech and co-workers (DOI: 10.1002/ejoc.202400560).\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure>\n </p>","PeriodicalId":167,"journal":{"name":"European Journal of Organic Chemistry","volume":"27 37","pages":""},"PeriodicalIF":2.5000,"publicationDate":"2024-10-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ejoc.202483701","citationCount":"0","resultStr":"{\"title\":\"Front Cover: Trends in the Reactivity of Pentacyclic Ether Derivatives on Silicon and Germanium Surfaces Revealed by Energy Decomposition Analysis for Extended Systems (Eur. J. Org. Chem. 37/2024)\",\"authors\":\"Franz Thiemann, Hendrik Weiske, Ralf Tonner-Zech\",\"doi\":\"10.1002/ejoc.202483701\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><b>The Front Cover</b> illustrates the S<sub>N</sub>2-like ring-opening reactions of THF derivatives with the chalcogen elements O, S, Se and Te on both Si(001) and Ge(001) surfaces. The periodic table at the back embodies the trends presented in the work. On the left, the deformation density of the first NOCV in the THF precursor structure showcases the charge transfer towards the surface. The across-trench product of the tellurium derivative is shown on the right. The center features the across-trench transition state geometry of THSe with a deformation density indicating an S<sub>N</sub>2-like reaction. More information can be found in the Research Article by R. Tonner-Zech and co-workers (DOI: 10.1002/ejoc.202400560).\\n <figure>\\n <div><picture>\\n <source></source></picture><p></p>\\n </div>\\n </figure>\\n </p>\",\"PeriodicalId\":167,\"journal\":{\"name\":\"European Journal of Organic Chemistry\",\"volume\":\"27 37\",\"pages\":\"\"},\"PeriodicalIF\":2.5000,\"publicationDate\":\"2024-10-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ejoc.202483701\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"European Journal of Organic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/ejoc.202483701\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"European Journal of Organic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ejoc.202483701","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
Front Cover: Trends in the Reactivity of Pentacyclic Ether Derivatives on Silicon and Germanium Surfaces Revealed by Energy Decomposition Analysis for Extended Systems (Eur. J. Org. Chem. 37/2024)
The Front Cover illustrates the SN2-like ring-opening reactions of THF derivatives with the chalcogen elements O, S, Se and Te on both Si(001) and Ge(001) surfaces. The periodic table at the back embodies the trends presented in the work. On the left, the deformation density of the first NOCV in the THF precursor structure showcases the charge transfer towards the surface. The across-trench product of the tellurium derivative is shown on the right. The center features the across-trench transition state geometry of THSe with a deformation density indicating an SN2-like reaction. More information can be found in the Research Article by R. Tonner-Zech and co-workers (DOI: 10.1002/ejoc.202400560).
期刊介绍：
The European Journal of Organic Chemistry (2019 ISI Impact Factor 2.889) publishes Full Papers, Communications, and Minireviews from the entire spectrum of synthetic organic, bioorganic and physical-organic chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies.
The following journals have been merged to form two leading journals, the European Journal of Organic Chemistry and the European Journal of Inorganic Chemistry:
Liebigs Annalen
Bulletin des Sociétés Chimiques Belges
Bulletin de la Société Chimique de France
Gazzetta Chimica Italiana
Recueil des Travaux Chimiques des Pays-Bas
Anales de Química
Chimika Chronika
Revista Portuguesa de Química
ACH—Models in Chemistry
Polish Journal of Chemistry.
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