锂离子电池多维健康状况评估新方法

iEnergy Pub Date : 2024-09-01 DOI:10.23919/IEN.2024.0020
Peng Peng;Yue Sun;Man Chen;Yuxuan Li;Zhenkai Hu;Rui Xiong
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引用次数: 0

摘要

电动汽车和电池储能是实现碳中和的有效技术途径,而锂离子电池(LiBs)是非常关键的储能设备,对实现这一目标具有重要意义。然而,电池瞬间降解的特性严重影响了其长寿命和高安全性的应用。锂电池的老化机理复杂多样,受众多相互作用因素的强烈影响。目前,人们通常用容量衰减程度来描述电池的老化,并将电池最大可用容量与额定容量之比定义为电池的健康状况(SOH)。为实现对电池健康状况的多维度综合评价,本文通过改进的单颗粒模型,提出了一种由多维老化特征驱动的新型 SOH 估算方法。在宽温环境下的整个寿命周期内,对模型进行了参数识别和灵敏度分析。得到了九个描述 SOH 的老化特征参数。结合老化机理,从容量水平、锂离子扩散、电化学反应和功率容量四个方面评估了当前的健康状况。所提出的方法能更全面地评估电池的老化特性,其 SOH 估计误差在 2% 以内。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
A New Multi-Dimensional State of Health Evaluation Method for Lithium-Ion Batteries
Electric vehicles and battery energy storage are effective technical paths to achieve carbon neutrality, and lithium-ion batteries (LiBs) are very critical energy storage devices, which is of great significance to the goal. However, the battery's characteristics of instant degradation seriously affect its long life and high safety applications. The aging mechanisms of LiBs are complex and multi-faceted, strongly influenced by numerous interacting factors. Currently, the degree of capacity fading is commonly used to describe the aging of the battery, and the ratio of the maximum available capacity to the rated capacity of the battery is defined as the state of health (SOH). However, the aging or health of the battery should be multifaceted. to realize the multi-dimensional comprehensive evaluation of battery health status, a novel SOH estimation method driven by multidimensional aging characteristics is proposed through the improved single-particle model. The parameter identification and sensitivity analysis of the model were carried out during the whole cycle of life in a wide temperature environment. Nine aging characteristic parameters were obtained to describe the SOH. Combined with aging mechanisms, the current health status was evaluated from four aspects: capacity level, lithium-ion diffusion, electrochemical reaction, and power capacity. The proposed method can more comprehensively evaluate the aging characteristics of batteries, and the SOH estimation error is within 2%.
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