Depeng Zhang , Hui Li , Zhenyu Pi , Mingfeng Xu , Jian Zhou , Mingzhong Zhang
{"title":"晶体和凝胶水化产物之间的相互作用对胶凝材料体积变化的影响","authors":"Depeng Zhang , Hui Li , Zhenyu Pi , Mingfeng Xu , Jian Zhou , Mingzhong Zhang","doi":"10.1016/j.cemconcomp.2024.105764","DOIUrl":null,"url":null,"abstract":"<div><div>The volume change of cementitious materials is often studied based on the properties of the individual hydration product, either from the gel products causing shrinkage or the crystal products causing expansion. Previous studies of the team have theoretically revealed that the interactions between crystal and gel products produce the “micro self-stressing”, which affects the volume change of cementitious materials. This work presents theoretical and experimental studies into the impact of the interactions between crystal and gel products on the volume change of cementitious materials. Firstly, a theoretical model for the volume change of cementitious materials was proposed. Secondly, in the followed experiment, the crystallization pressure, which affects the interactions between crystal and gel products, was tailored by immersing specimens in different exchange solvents or solutions to change the solubility product. Water, isopropyl alcohol, ethanol, calcium hydroxide and calcium acetate were selected as the exchange solvents or solutions. Subsequently, cement pastes were vacuum dried. Volume changes of cement pastes were tested during the whole process. Inductively-coupled plasma mass spectrometry and ion chromatography were utilized to test the ion concentrations and calculate the crystallization pressure. Finally, the experimental results were compared with the calculated results to validate the model. Results indicated that cement pastes immersed in different solvents or solutions exhibited different volume changes. An increase in crystallization pressure by 45.3 % resulted in a 46.1 % increase in the expansion of cement paste. Moreover, the reduction in the interactions should be one of the factors contributing to the drying shrinkage of cement paste.</div></div>","PeriodicalId":9865,"journal":{"name":"Cement & concrete composites","volume":"154 ","pages":"Article 105764"},"PeriodicalIF":10.8000,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effect of the interactions between crystal and gel hydration products on the volume change of cementitious materials\",\"authors\":\"Depeng Zhang , Hui Li , Zhenyu Pi , Mingfeng Xu , Jian Zhou , Mingzhong Zhang\",\"doi\":\"10.1016/j.cemconcomp.2024.105764\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The volume change of cementitious materials is often studied based on the properties of the individual hydration product, either from the gel products causing shrinkage or the crystal products causing expansion. Previous studies of the team have theoretically revealed that the interactions between crystal and gel products produce the “micro self-stressing”, which affects the volume change of cementitious materials. This work presents theoretical and experimental studies into the impact of the interactions between crystal and gel products on the volume change of cementitious materials. Firstly, a theoretical model for the volume change of cementitious materials was proposed. Secondly, in the followed experiment, the crystallization pressure, which affects the interactions between crystal and gel products, was tailored by immersing specimens in different exchange solvents or solutions to change the solubility product. Water, isopropyl alcohol, ethanol, calcium hydroxide and calcium acetate were selected as the exchange solvents or solutions. Subsequently, cement pastes were vacuum dried. Volume changes of cement pastes were tested during the whole process. Inductively-coupled plasma mass spectrometry and ion chromatography were utilized to test the ion concentrations and calculate the crystallization pressure. Finally, the experimental results were compared with the calculated results to validate the model. Results indicated that cement pastes immersed in different solvents or solutions exhibited different volume changes. An increase in crystallization pressure by 45.3 % resulted in a 46.1 % increase in the expansion of cement paste. Moreover, the reduction in the interactions should be one of the factors contributing to the drying shrinkage of cement paste.</div></div>\",\"PeriodicalId\":9865,\"journal\":{\"name\":\"Cement & concrete composites\",\"volume\":\"154 \",\"pages\":\"Article 105764\"},\"PeriodicalIF\":10.8000,\"publicationDate\":\"2024-09-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Cement & concrete composites\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0958946524003378\",\"RegionNum\":1,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CONSTRUCTION & BUILDING TECHNOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Cement & concrete composites","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0958946524003378","RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CONSTRUCTION & BUILDING TECHNOLOGY","Score":null,"Total":0}
Effect of the interactions between crystal and gel hydration products on the volume change of cementitious materials
The volume change of cementitious materials is often studied based on the properties of the individual hydration product, either from the gel products causing shrinkage or the crystal products causing expansion. Previous studies of the team have theoretically revealed that the interactions between crystal and gel products produce the “micro self-stressing”, which affects the volume change of cementitious materials. This work presents theoretical and experimental studies into the impact of the interactions between crystal and gel products on the volume change of cementitious materials. Firstly, a theoretical model for the volume change of cementitious materials was proposed. Secondly, in the followed experiment, the crystallization pressure, which affects the interactions between crystal and gel products, was tailored by immersing specimens in different exchange solvents or solutions to change the solubility product. Water, isopropyl alcohol, ethanol, calcium hydroxide and calcium acetate were selected as the exchange solvents or solutions. Subsequently, cement pastes were vacuum dried. Volume changes of cement pastes were tested during the whole process. Inductively-coupled plasma mass spectrometry and ion chromatography were utilized to test the ion concentrations and calculate the crystallization pressure. Finally, the experimental results were compared with the calculated results to validate the model. Results indicated that cement pastes immersed in different solvents or solutions exhibited different volume changes. An increase in crystallization pressure by 45.3 % resulted in a 46.1 % increase in the expansion of cement paste. Moreover, the reduction in the interactions should be one of the factors contributing to the drying shrinkage of cement paste.
期刊介绍:
Cement & concrete composites focuses on advancements in cement-concrete composite technology and the production, use, and performance of cement-based construction materials. It covers a wide range of materials, including fiber-reinforced composites, polymer composites, ferrocement, and those incorporating special aggregates or waste materials. Major themes include microstructure, material properties, testing, durability, mechanics, modeling, design, fabrication, and practical applications. The journal welcomes papers on structural behavior, field studies, repair and maintenance, serviceability, and sustainability. It aims to enhance understanding, provide a platform for unconventional materials, promote low-cost energy-saving materials, and bridge the gap between materials science, engineering, and construction. Special issues on emerging topics are also published to encourage collaboration between materials scientists, engineers, designers, and fabricators.