基于应变类别及其对包晶石太阳能电池影响的稳定包晶石晶格的微应变调节策略

IF 13.1 1区 化学 Q1 Energy
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引用次数: 0

摘要

与晶体硅电池相比,光伏金属卤化物包晶体太阳能电池(PSCs)能更有效地将光转换为电能,而且其材料成本也低于硅电池。转换效率并不是影响包晶体太阳能电池在特殊情况下应用的核心问题。目前,稳定性是阻碍其进一步商业化发展的主要技术问题。目前,PSCs 中的微应变是导致设备不稳定的重要因素。人们普遍认为,即使在排除外部刺激的情况下,应变引起的离子迁移也会加速包晶体的降解。毫无疑问,研究应变以提高 PSCs 的稳定性势在必行。本文回顾了了解应变的起源及其对 PSC 性能影响机制的最新进展,包括离子迁移、失效行为、缺陷形成及其对光电特性、稳定性和可靠性的影响。此外,根据薄膜的应变效应机制和应变工程学,系统地介绍了几种著名的应变管理策略,为进一步制备稳定性更高的薄膜提供了更多线索。此外,还广泛研究了从薄膜到整个器件的外部物理应变操作。此外,还对未来的研究方向和化学方法提出了建议。研究强调,应变工程在提高 PSC 的效率和寿命方面起着至关重要的作用。拉伸应变会导致快速降解,而适度的压缩应变和外部应变控制则可以改善性能和稳定性。应集中精力控制压缩应变,以减轻残余拉伸应变,并以可控的方式引入压缩应变。未来的研究工作可能会侧重于探索这些途径,以提高 PSC 的效率和寿命。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Micro-strain regulation strategy to stabilize perovskite lattice based on the categories and impact of strain on perovskite solar cells

Micro-strain regulation strategy to stabilize perovskite lattice based on the categories and impact of strain on perovskite solar cells
Photovoltaic metal halide perovskite solar cells (PSCs) convert light to electricity more efficiently than crystalline silicon cells, and the cost of materials used to make them is lower than that of silicon cells. Conversion efficiency is not a core issue affecting the application of perovskite solar cells in special scenarios. At present, stability is the major technical encounters that hinders its further commercial development. Micro-strain in PSCs is currently a significant factor responsible for the device’s instability. Strain-induced ion migration is widely believed to accelerate perovskite degradation even when external stimuli are excluded. Undoubtedly, it is imperative to study strain to enhance the stability of PSCs. This paper reviews recent developments to understand strain’s origin and effect mechanisms on performance of PSCs, including ion migration, failure behavior, defect formation, and its effect on photoelectric properties, stability, and reliability. Additionally, several well-known strain management strategies are systematically introduced based on the strain effect mechanism and strain engineering on the film, providing more clues for further preparation with increased stability. The manipulation of external physical strain applied from films to entire devices has been extensively studied. Furthermore, recommendations for future research directions and chemical approaches have been provided. It is emphasized that strain engineering plays a crucial role in improving the efficiency and longevity of PSCs. Tensile strain causes rapid degradation, while moderate compressive strain and external strain control could improve properties and stability. Efforts should focus on controlling compressive strain to mitigate residual tensile strain and introducing it in a controlled manner. Future research endeavors may focus on exploring these pathways to improve the efficiency and lifespan of PSCs.
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来源期刊
Journal of Energy Chemistry
Journal of Energy Chemistry CHEMISTRY, APPLIED-CHEMISTRY, PHYSICAL
CiteScore
19.10
自引率
8.40%
发文量
3631
审稿时长
15 days
期刊介绍: The Journal of Energy Chemistry, the official publication of Science Press and the Dalian Institute of Chemical Physics, Chinese Academy of Sciences, serves as a platform for reporting creative research and innovative applications in energy chemistry. It mainly reports on creative researches and innovative applications of chemical conversions of fossil energy, carbon dioxide, electrochemical energy and hydrogen energy, as well as the conversions of biomass and solar energy related with chemical issues to promote academic exchanges in the field of energy chemistry and to accelerate the exploration, research and development of energy science and technologies. This journal focuses on original research papers covering various topics within energy chemistry worldwide, including: Optimized utilization of fossil energy Hydrogen energy Conversion and storage of electrochemical energy Capture, storage, and chemical conversion of carbon dioxide Materials and nanotechnologies for energy conversion and storage Chemistry in biomass conversion Chemistry in the utilization of solar energy
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