开发和制造用于测量液体介电常数的成本效益型非接触式仪器。

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Akram Hassanpouryouzband, Iraj Ahadzadeh, Abbas Mehrdad, Somayyeh Panahpour
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引用次数: 0

摘要

这项研究介绍了一种经济高效的仪器的开发和制造过程,该仪器采用非接触式方法测量液体的介电常数,这种方法依赖于确定装有液体的电池的电容及其弛豫频率。该仪器采用了一个与电阻电容网络集成的星型多谐振荡器,其中装有相关液体的电池充当振荡器的电容元件。产生振荡的频率由分辨率为 1 Hz 的七位频率计精确记录。在样品池中注入一系列已知介电常数的纯液体,随后在环境温度下记录它们的频率。频率-介电常数曲线拟合出一个方程,用作校准方程,以确定后续液体的介电常数。除纯液体外,还利用之前建立的校准方程计算了不同分子分数的溶剂混合物的介电常数。我们的结果表明,仪器具有极佳的频率稳定性,所获得的介电常数值与实验数据和计算方法的预测值都非常一致。这表明所构建的仪器在测量纯液体和混合液体的介电常数时都表现出很高的准确性,从而确立了其在相关研究和工业应用中的潜在用途。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Development and construction of a cost-effective non-contact instrument for measuring the dielectric constant of liquids.

This research presents the development and construction of a cost-effective instrument, designed to measure the dielectric constant of liquids by employing a non-contact method that relies on determining the capacitance of a cell containing the liquid and its relaxation frequency. This instrument utilizes an astable multi-vibrator integrated with a resistance-capacitor network, in which the cell housing the liquid of interest functions as a capacitor element of the oscillator. The frequency of the generated oscillations is meticulously recorded using a seven-digit frequency meter with a resolution of 1 Hz. The cell was filled with an array of pure liquids with known dielectric constants, and their frequencies were subsequently recorded at ambient temperatures. An equation was fitted to the frequency-dielectric constant curve, which was used as a calibration equation to determine the dielectric constant of subsequent liquids. In addition to pure liquids, dielectric constants for solvent mixtures of varying mole fractions were also calculated using the previously established calibration equation. Our results demonstrated excellent frequency stability of the instrument, and the obtained dielectric constant values displayed significant consistency with both the experimental data and predictions made by computational methodologies. This suggests that the constructed instrument exhibits a high level of accuracy in measuring the dielectric constant of both pure and mixed liquids, establishing its potential utility in relevant research and industrial applications.

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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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