二茂铁基双（吡唑）钯配合物的合成、结构表征和催化应用。

IF 3 4区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

ChemPlusChem Pub Date : 2024-09-30 DOI:10.1002/cplu.202400547

Sushanta Kumar Meher, Basava Punna Rao Aradhyula, Venkateswara Rao Velpuri, Krishnan Venkatasubbaiah

{"title":"二茂铁基双（吡唑）钯配合物的合成、结构表征和催化应用。","authors":"Sushanta Kumar Meher, Basava Punna Rao Aradhyula, Venkateswara Rao Velpuri, Krishnan Venkatasubbaiah","doi":"10.1002/cplu.202400547","DOIUrl":null,"url":null,"abstract":"Here we report, synthesis of ferrocenyl based bis(pyrazolyl) palladium complexes. The catalytic utility of the complexes in the cross-coupling of triarylbismuthanes and aryl bromides was evaluated. Our ferrocenyl based palladium complex showed wide substrate scope for both triarylbismuthanes and aryl bromides. Further, the current catalytic system also showed superior activity over the well-established palladium-phosphine catalytic system using triarylbismuthanes as reagents.","PeriodicalId":148,"journal":{"name":"ChemPlusChem","volume":" ","pages":"e202400547"},"PeriodicalIF":3.0000,"publicationDate":"2024-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis, Structural Characterization and Catalytic Application of Ferrocenyl Based Bis(pyrazolyl) Palladium Complexes.\",\"authors\":\"Sushanta Kumar Meher, Basava Punna Rao Aradhyula, Venkateswara Rao Velpuri, Krishnan Venkatasubbaiah\",\"doi\":\"10.1002/cplu.202400547\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Here we report, synthesis of ferrocenyl based bis(pyrazolyl) palladium complexes. The catalytic utility of the complexes in the cross-coupling of triarylbismuthanes and aryl bromides was evaluated. Our ferrocenyl based palladium complex showed wide substrate scope for both triarylbismuthanes and aryl bromides. Further, the current catalytic system also showed superior activity over the well-established palladium-phosphine catalytic system using triarylbismuthanes as reagents.\",\"PeriodicalId\":148,\"journal\":{\"name\":\"ChemPlusChem\",\"volume\":\" \",\"pages\":\"e202400547\"},\"PeriodicalIF\":3.0000,\"publicationDate\":\"2024-09-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemPlusChem\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1002/cplu.202400547\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemPlusChem","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1002/cplu.202400547","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

在此，我们报告了二茂铁基双（吡唑）钯络合物的合成。我们评估了这些配合物在三芳基铋烷和芳基溴化物交叉偶联反应中的催化作用。我们以二茂铁为基础的钯配合物对三芳基铋烷和芳基溴化物都显示出了广泛的底物范围。此外，与使用三芳基铋烷作为试剂的成熟的钯膦催化体系相比，当前的催化体系还显示出更高的活性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Synthesis, Structural Characterization and Catalytic Application of Ferrocenyl Based Bis(pyrazolyl) Palladium Complexes.

Here we report, synthesis of ferrocenyl based bis(pyrazolyl) palladium complexes. The catalytic utility of the complexes in the cross-coupling of triarylbismuthanes and aryl bromides was evaluated. Our ferrocenyl based palladium complex showed wide substrate scope for both triarylbismuthanes and aryl bromides. Further, the current catalytic system also showed superior activity over the well-established palladium-phosphine catalytic system using triarylbismuthanes as reagents.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

ChemPlusChem CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

5.90

自引率

0.00%

发文量

200

审稿时长

1 months

期刊介绍： ChemPlusChem is a peer-reviewed, general chemistry journal that brings readers the very best in multidisciplinary research centering on chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. Fully comprehensive in its scope, ChemPlusChem publishes articles covering new results from at least two different aspects (subfields) of chemistry or one of chemistry and one of another scientific discipline (one chemistry topic plus another one, hence the title ChemPlusChem). All suitable submissions undergo balanced peer review by experts in the field to ensure the highest quality, originality, relevance, significance, and validity.