N-未取代的 2-和 3-噻吩亚胺。

IF 2.7 3区化学 Q1 CHEMISTRY, ORGANIC

Organic & Biomolecular Chemistry Pub Date : 2024-09-30 DOI:10.1039/d4ob01315h

Amavi Kpoezoun , Gnon Baba , Jean-Claude Guillemin

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引用次数: 0

摘要

N- 未取代的 2-噻吩甲亚胺和 3-噻吩甲亚胺是亚胺家族--噻吩亚胺的最简单衍生物。这两种噻吩基醛酸亚胺和 C-甲基衍生物是通过相应的 α-氨基硝酸脱氢氰化反应在气固反应中制备的，或通过 N-烯丙基衍生物的逆烯反应在气相中制备的，然后在低温下通过红外光谱和核磁共振光谱进行表征，并用于反硝化反应。我们从多个角度将这些处于游离或络合状态的化合物与最近合成的相应呋喃亚胺和其他 N-未取代亚胺进行了比较，目的是研究它们各自的特异性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

N-Unsubstituted 2- and 3-thiophenimines†

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N-Unsubstituted 2- and 3-thiophenimines†

N-Unsubstituted 2-thiophenemethanimine and 3-thiophenemethanimine are the simplest derivatives of a family of imines, the thienyl imines. These two thienyl aldimines and the C-methyl derivatives were prepared in a gas solid reaction by dehydrocyanation of the corresponding α-aminonitriles or in the gas phase by a retro-ene reaction from N-allyl derivatives, then characterized by IR and NMR spectroscopy at low temperature and used in transimination reactions. From several angles, these compounds in the free or complexed state have been compared to the corresponding recently synthesized furanimines and to other N-unsubstituted imines, with the aim of studying the specificity of each of them.

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来源期刊

Organic & Biomolecular Chemistry 化学-有机化学

CiteScore

5.50

自引率

9.40%

发文量

1056

审稿时长

1.3 months

期刊介绍： Organic & Biomolecular Chemistry is an international journal using integrated research in chemistry-organic chemistry. Founded in 2003 by the Royal Society of Chemistry, the journal is published in Semimonthly issues and has been indexed by SCIE, a leading international database. The journal focuses on the key research and cutting-edge progress in the field of chemistry-organic chemistry, publishes and reports the research results in this field in a timely manner, and is committed to becoming a window and platform for rapid academic exchanges among peers in this field. The journal's impact factor in 2023 is 2.9, and its CiteScore is 5.5.