On-surface synthesis of porous graphene nanoribbons mediated by phenyl migration

Advancements in the on-surface synthesis of atomically precise graphene nanostructures are propelled by the introduction of innovative precursor designs and reaction types. Until now, the latter has been confined to cross-coupling and cyclization reactions that involve the cleavage of specific atoms or groups. In this article, we elucidate how the migration of phenyl substituents attached to graphene nanoribbons can be harnessed to generate arrays of [18]-annulene pores at the edges of the nanostructures. This sequential pathway is revealed through a comprehensive study employing bond-resolved scanning tunneling microscopy and ab-initio computational techniques. The yield of pore formation is maximized by anchoring the graphene nanoribbons at steps of vicinal surfaces, underscoring the potential of these substrates to guide reaction paths. Our study introduces a new reaction to the on-surface synthesis toolbox along with a sequential route, altogether enabling the extension of this strategy towards the formation of other porous nanostructures. The on-surface synthesis of graphene nanoribbons typically relies on Ullmann polymerization followed by an internal cyclodehydrogenation. Here, following these two steps, the authors expand the synthetic protocol by adding controlled phenyl migration and intraribbon aryl-aryl dehydrogenative coupling to afford graphene nanoribbons with periodic arrays of [18]annulene pores at the edges.