{"title":"变质二氧化碳通量抵消喜马拉雅-西藏造山带的净地质碳汇","authors":"Samyak Pradhan, Indra Sekhar Sen","doi":"10.1016/j.epsl.2024.119018","DOIUrl":null,"url":null,"abstract":"<div><div>The carbon budget of the Himalayan-Tibetan orogen often neglects the poorly constrained CO<sub>2</sub> fluxes from the mantle and metamorphism that emerge directly from hot springs or diffusely through the soil, which can potentially warm the climate. What exists are either metamorphic phase relations, thermodynamic model-based CO<sub>2</sub> flux estimates, or field-based estimates in a single catchment extrapolated to the entire orogen having diverse geological and tectonics characteristics, heat flow, and hydrological regimes. Here, we apply a steady-state isotope mass balance model to observations of carbon isotope ratios to quantify the fluxes of CO<sub>2</sub> degassed using a global compilation of hot springs located on the fault systems of the Himalayan Tibetan orogen. We estimate that the hot springs could degas up to ∼84 % of the dissolved CO<sub>2</sub>, releasing up to 1.5 ± 1.0 × 10<sup>11</sup> mol CO<sub>2</sub> yr<sup>-1</sup>. When combined with diffused soil CO<sub>2</sub> emissions, the Himalayan Tibetan orogen has the potential to emit 3.0 ± 1.3 × 10<sup>11</sup> mol CO<sub>2</sub> yr<sup>-1</sup>, which is similar in magnitude to CO<sub>2</sub> emission from continental rifts as well as the CO<sub>2</sub> drawdown due to silicate weathering in the orogen. We find that CO<sub>2</sub> released from the catchments of Himalayan-Tibetan orogen is primarily controlled by metamorphic processes <span><math><mrow><mo>(</mo><msubsup><mn>79</mn><mrow><mo>−</mo><mn>25</mn></mrow><mrow><mo>+</mo><mn>21</mn></mrow></msubsup><mrow><mspace></mspace><mo>%</mo></mrow><mo>)</mo></mrow></math></span>, with secondary controls from mantle degassing <span><math><mrow><mo>(</mo><msubsup><mn>7</mn><mrow><mo>−</mo><mn>7</mn></mrow><mrow><mo>+</mo><mn>17</mn></mrow></msubsup><mrow><mspace></mspace><mo>%</mo></mrow><mo>)</mo></mrow></math></span>, and carbonate dissolution (<span><math><mrow><msubsup><mn>14</mn><mrow><mo>−</mo><mn>14</mn></mrow><mrow><mo>+</mo><mn>26</mn></mrow></msubsup><mspace></mspace></mrow></math></span>%) and is insensitive to contributions from younger biospheric sources. Reevaluation of the geological carbon budget in Narayani Basin, Nepal, shows that metamorphic CO<sub>2</sub> in the collisional orogen is comparable to other carbon sources and sinks. We conclude that metamorphic CO<sub>2</sub> could offset the CO<sub>2</sub> drawdown by silicate weathering and OC<sub>biosphere</sub> burial in the Himalayan-Tibet orogen, resulting in global warming over million-year time scales.</div></div>","PeriodicalId":11481,"journal":{"name":"Earth and Planetary Science Letters","volume":"647 ","pages":"Article 119018"},"PeriodicalIF":4.8000,"publicationDate":"2024-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Metamorphic CO2 fluxes offset the net geological carbon sink in the Himalayan-Tibetan orogen\",\"authors\":\"Samyak Pradhan, Indra Sekhar Sen\",\"doi\":\"10.1016/j.epsl.2024.119018\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The carbon budget of the Himalayan-Tibetan orogen often neglects the poorly constrained CO<sub>2</sub> fluxes from the mantle and metamorphism that emerge directly from hot springs or diffusely through the soil, which can potentially warm the climate. What exists are either metamorphic phase relations, thermodynamic model-based CO<sub>2</sub> flux estimates, or field-based estimates in a single catchment extrapolated to the entire orogen having diverse geological and tectonics characteristics, heat flow, and hydrological regimes. Here, we apply a steady-state isotope mass balance model to observations of carbon isotope ratios to quantify the fluxes of CO<sub>2</sub> degassed using a global compilation of hot springs located on the fault systems of the Himalayan Tibetan orogen. We estimate that the hot springs could degas up to ∼84 % of the dissolved CO<sub>2</sub>, releasing up to 1.5 ± 1.0 × 10<sup>11</sup> mol CO<sub>2</sub> yr<sup>-1</sup>. When combined with diffused soil CO<sub>2</sub> emissions, the Himalayan Tibetan orogen has the potential to emit 3.0 ± 1.3 × 10<sup>11</sup> mol CO<sub>2</sub> yr<sup>-1</sup>, which is similar in magnitude to CO<sub>2</sub> emission from continental rifts as well as the CO<sub>2</sub> drawdown due to silicate weathering in the orogen. We find that CO<sub>2</sub> released from the catchments of Himalayan-Tibetan orogen is primarily controlled by metamorphic processes <span><math><mrow><mo>(</mo><msubsup><mn>79</mn><mrow><mo>−</mo><mn>25</mn></mrow><mrow><mo>+</mo><mn>21</mn></mrow></msubsup><mrow><mspace></mspace><mo>%</mo></mrow><mo>)</mo></mrow></math></span>, with secondary controls from mantle degassing <span><math><mrow><mo>(</mo><msubsup><mn>7</mn><mrow><mo>−</mo><mn>7</mn></mrow><mrow><mo>+</mo><mn>17</mn></mrow></msubsup><mrow><mspace></mspace><mo>%</mo></mrow><mo>)</mo></mrow></math></span>, and carbonate dissolution (<span><math><mrow><msubsup><mn>14</mn><mrow><mo>−</mo><mn>14</mn></mrow><mrow><mo>+</mo><mn>26</mn></mrow></msubsup><mspace></mspace></mrow></math></span>%) and is insensitive to contributions from younger biospheric sources. Reevaluation of the geological carbon budget in Narayani Basin, Nepal, shows that metamorphic CO<sub>2</sub> in the collisional orogen is comparable to other carbon sources and sinks. We conclude that metamorphic CO<sub>2</sub> could offset the CO<sub>2</sub> drawdown by silicate weathering and OC<sub>biosphere</sub> burial in the Himalayan-Tibet orogen, resulting in global warming over million-year time scales.</div></div>\",\"PeriodicalId\":11481,\"journal\":{\"name\":\"Earth and Planetary Science Letters\",\"volume\":\"647 \",\"pages\":\"Article 119018\"},\"PeriodicalIF\":4.8000,\"publicationDate\":\"2024-09-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Earth and Planetary Science Letters\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0012821X24004503\",\"RegionNum\":1,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"GEOCHEMISTRY & GEOPHYSICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Earth and Planetary Science Letters","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0012821X24004503","RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"GEOCHEMISTRY & GEOPHYSICS","Score":null,"Total":0}
Metamorphic CO2 fluxes offset the net geological carbon sink in the Himalayan-Tibetan orogen
The carbon budget of the Himalayan-Tibetan orogen often neglects the poorly constrained CO2 fluxes from the mantle and metamorphism that emerge directly from hot springs or diffusely through the soil, which can potentially warm the climate. What exists are either metamorphic phase relations, thermodynamic model-based CO2 flux estimates, or field-based estimates in a single catchment extrapolated to the entire orogen having diverse geological and tectonics characteristics, heat flow, and hydrological regimes. Here, we apply a steady-state isotope mass balance model to observations of carbon isotope ratios to quantify the fluxes of CO2 degassed using a global compilation of hot springs located on the fault systems of the Himalayan Tibetan orogen. We estimate that the hot springs could degas up to ∼84 % of the dissolved CO2, releasing up to 1.5 ± 1.0 × 1011 mol CO2 yr-1. When combined with diffused soil CO2 emissions, the Himalayan Tibetan orogen has the potential to emit 3.0 ± 1.3 × 1011 mol CO2 yr-1, which is similar in magnitude to CO2 emission from continental rifts as well as the CO2 drawdown due to silicate weathering in the orogen. We find that CO2 released from the catchments of Himalayan-Tibetan orogen is primarily controlled by metamorphic processes , with secondary controls from mantle degassing , and carbonate dissolution (%) and is insensitive to contributions from younger biospheric sources. Reevaluation of the geological carbon budget in Narayani Basin, Nepal, shows that metamorphic CO2 in the collisional orogen is comparable to other carbon sources and sinks. We conclude that metamorphic CO2 could offset the CO2 drawdown by silicate weathering and OCbiosphere burial in the Himalayan-Tibet orogen, resulting in global warming over million-year time scales.
期刊介绍:
Earth and Planetary Science Letters (EPSL) is a leading journal for researchers across the entire Earth and planetary sciences community. It publishes concise, exciting, high-impact articles ("Letters") of broad interest. Its focus is on physical and chemical processes, the evolution and general properties of the Earth and planets - from their deep interiors to their atmospheres. EPSL also includes a Frontiers section, featuring invited high-profile synthesis articles by leading experts on timely topics to bring cutting-edge research to the wider community.