Wearable Inorganic Oxide Chemiresistor Based on Flexible Al2O3-Stabilized ZrO2 Ceramic Sponge Substrate for NO2 Sensing

Wearable gas sensors, possessing the advantages of high sensitivity, excellent flexibility, high permeability, low weight, and workability at ambient conditions, hold great promise for real-time health monitoring and early warnings of poisonous gases. However, obtaining high-performance wearable gas sensors utilizing the current well-developed inorganic semiconductor oxide sensing materials is still very limited due to their fragile and rigid nature. Herein, a newly designed wearable gas sensor based on an all-inorganic ASZ (Al₂O₃-stabilized ZrO₂)/ZnO/SnO₂ nanofibers is introduced for the first time. The flexible ASZ ceramic sponge substrate (with a Young’s modulus of 4.15 MPa) and ultrathin ZnO/SnO₂ sensing layer endow the wearable gas sensor with promising properties such as super flexibility (with a bending radius of 5 mm), high gas permeability, and low weight. Furthermore, driven by UV light irradiation, this all-inorganic wearable sensor also demonstrates a stable NO₂ sensing response under different bending states at room temperature, which enables the gas sensor to be more compatible with wearable sensing applications. This work offers a general method to achieve a high-performance wearable gas sensor based on inorganic materials and provides new insights into their potential in wearable gas-sensing applications.