铁-钴双原子对的电子自旋断裂对称性促进锌-空气电池的双功能氧电催化动力学（科学进展 35/2024）

IF 14.3 1区材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Advanced Science Pub Date : 2024-09-26 DOI:10.1002/advs.202470209

Xiaokang Li, Jian Qin, Qingxin Lin, Xiaoyu Yi, Cheng Yan, Jianhua Zhang, Jinjuan Dong, Kang Yu, Shenglong Zhang, Chong Xie, Huijuan Yang, Wei Xiao, Wenbin Li, Jingjing Wang, Xifei Li

{"title":"铁-钴双原子对的电子自旋断裂对称性促进锌-空气电池的双功能氧电催化动力学（科学进展 35/2024）","authors":"Xiaokang Li, Jian Qin, Qingxin Lin, Xiaoyu Yi, Cheng Yan, Jianhua Zhang, Jinjuan Dong, Kang Yu, Shenglong Zhang, Chong Xie, Huijuan Yang, Wei Xiao, Wenbin Li, Jingjing Wang, Xifei Li","doi":"10.1002/advs.202470209","DOIUrl":null,"url":null,"abstract":"<p><b>Single-Atom Catalysts</b></p><p>In article number 2401187, Xifei Li and co-workers reveal the electron spin broken-symmetry of Fe-Co bimetallic single-atom catalysts, in which the strong charge polarization between Fe and Co sites, and the stray field produced by spin polarization at the Co site optimize the d-band center of the active atom, and effectively balance the adsorption-dissociation relationship of oxygen intermediates.\n\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure></p>","PeriodicalId":117,"journal":{"name":"Advanced Science","volume":null,"pages":null},"PeriodicalIF":14.3000,"publicationDate":"2024-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/advs.202470209","citationCount":"0","resultStr":"{\"title\":\"Electron Spin Broken-Symmetry of Fe–Co Diatomic Pairs to Promote Kinetics of Bifunctional Oxygen Electrocatalysis for Zinc–Air Batteries (Adv. Sci. 35/2024)\",\"authors\":\"Xiaokang Li, Jian Qin, Qingxin Lin, Xiaoyu Yi, Cheng Yan, Jianhua Zhang, Jinjuan Dong, Kang Yu, Shenglong Zhang, Chong Xie, Huijuan Yang, Wei Xiao, Wenbin Li, Jingjing Wang, Xifei Li\",\"doi\":\"10.1002/advs.202470209\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><b>Single-Atom Catalysts</b></p><p>In article number 2401187, Xifei Li and co-workers reveal the electron spin broken-symmetry of Fe-Co bimetallic single-atom catalysts, in which the strong charge polarization between Fe and Co sites, and the stray field produced by spin polarization at the Co site optimize the d-band center of the active atom, and effectively balance the adsorption-dissociation relationship of oxygen intermediates.\\n\\n <figure>\\n <div><picture>\\n <source></source></picture><p></p>\\n </div>\\n </figure></p>\",\"PeriodicalId\":117,\"journal\":{\"name\":\"Advanced Science\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":14.3000,\"publicationDate\":\"2024-09-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/advs.202470209\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advanced Science\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/advs.202470209\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Science","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/advs.202470209","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

单原子催化剂在文章编号 2401187 中，Xifei Li 及其合作者揭示了铁钴双金属单原子催化剂的电子自旋破对称性，其中铁和钴位点之间的强电荷极化以及钴位点自旋极化产生的杂散场优化了活性原子的 d 带中心，并有效平衡了氧中间产物的吸附-解离关系。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Electron Spin Broken-Symmetry of Fe–Co Diatomic Pairs to Promote Kinetics of Bifunctional Oxygen Electrocatalysis for Zinc–Air Batteries (Adv. Sci. 35/2024)

Single-Atom Catalysts

In article number 2401187, Xifei Li and co-workers reveal the electron spin broken-symmetry of Fe-Co bimetallic single-atom catalysts, in which the strong charge polarization between Fe and Co sites, and the stray field produced by spin polarization at the Co site optimize the d-band center of the active atom, and effectively balance the adsorption-dissociation relationship of oxygen intermediates.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Advanced Science CHEMISTRY, MULTIDISCIPLINARYNANOSCIENCE &-NANOSCIENCE & NANOTECHNOLOGY

CiteScore

18.90

自引率

2.60%

发文量

1602

审稿时长

1.9 months

期刊介绍： Advanced Science is a prestigious open access journal that focuses on interdisciplinary research in materials science, physics, chemistry, medical and life sciences, and engineering. The journal aims to promote cutting-edge research by employing a rigorous and impartial review process. It is committed to presenting research articles with the highest quality production standards, ensuring maximum accessibility of top scientific findings. With its vibrant and innovative publication platform, Advanced Science seeks to revolutionize the dissemination and organization of scientific knowledge.