{"title":"通过热力学和动力学将氢化钛的微观结构与其氢化条件联系起来","authors":"","doi":"10.1016/j.matchar.2024.114396","DOIUrl":null,"url":null,"abstract":"<div><div>Titanium hydride is widely considered as an important hydrogen storage material due to its high capacity, stability and low cost. The microstructure of titanium hydride, which is usually induced by the hydrogenation of titanium, strongly influences its storage performance. However, the relationship between the hydrogenation conditions and the derived microstructure of titanium hydride is still unclear, limiting the development of its structure design strategy. In this work, the microstructure of titanium hydride is correlated with its hydrogenation conditions through the thermodynamics and kinetics. By evaluating the effects of the hydrogenation temperature, pressure and cooling rate, three classes of the hydrogenation processes were clarified: kinetic-limited, continuous and stepwise. Besides, according to the SEM and FIB-STEM results, these different processes are confirmed to greatly vary the bulk microstructure. It is concluded that a fast and continuous transition induces a broken bulk morphology, while a stepwise process leads to a larger bulk grain size. In summary, this study presents a framework for designing titanium hydride structures by modifying phase transition processes through careful adjustment of hydrogenation parameters, namely, a condition-process-structure relationship. This relationship offers crucial guidance in managing the grain refinement or coarsening of hydrides within hydrogen storage components and metallurgical applications.</div></div>","PeriodicalId":18727,"journal":{"name":"Materials Characterization","volume":null,"pages":null},"PeriodicalIF":4.8000,"publicationDate":"2024-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Correlating the microstructure of titanium hydride with its hydrogenation conditions via thermodynamics and kinetics\",\"authors\":\"\",\"doi\":\"10.1016/j.matchar.2024.114396\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Titanium hydride is widely considered as an important hydrogen storage material due to its high capacity, stability and low cost. The microstructure of titanium hydride, which is usually induced by the hydrogenation of titanium, strongly influences its storage performance. However, the relationship between the hydrogenation conditions and the derived microstructure of titanium hydride is still unclear, limiting the development of its structure design strategy. In this work, the microstructure of titanium hydride is correlated with its hydrogenation conditions through the thermodynamics and kinetics. By evaluating the effects of the hydrogenation temperature, pressure and cooling rate, three classes of the hydrogenation processes were clarified: kinetic-limited, continuous and stepwise. Besides, according to the SEM and FIB-STEM results, these different processes are confirmed to greatly vary the bulk microstructure. It is concluded that a fast and continuous transition induces a broken bulk morphology, while a stepwise process leads to a larger bulk grain size. In summary, this study presents a framework for designing titanium hydride structures by modifying phase transition processes through careful adjustment of hydrogenation parameters, namely, a condition-process-structure relationship. This relationship offers crucial guidance in managing the grain refinement or coarsening of hydrides within hydrogen storage components and metallurgical applications.</div></div>\",\"PeriodicalId\":18727,\"journal\":{\"name\":\"Materials Characterization\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":4.8000,\"publicationDate\":\"2024-09-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Characterization\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1044580324007770\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CHARACTERIZATION & TESTING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Characterization","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1044580324007770","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CHARACTERIZATION & TESTING","Score":null,"Total":0}
引用次数: 0
摘要
氢化钛因其高容量、稳定性和低成本而被广泛认为是一种重要的储氢材料。氢化钛的微观结构通常是由钛的氢化作用引起的,对其储氢性能有很大影响。然而,氢化条件与氢化钛衍生微观结构之间的关系尚不明确,限制了其结构设计策略的发展。本研究通过热力学和动力学研究氢化钛的微观结构与其氢化条件的相关性。通过评估氢化温度、压力和冷却速率的影响,明确了氢化过程的三种类型:动力学限制型、连续型和阶跃型。此外,根据 SEM 和 FIB-STEM 的结果,这些不同的过程被证实会极大地改变块体的微观结构。结论是快速和连续的转变会导致破碎的块体形态,而逐步的过程则会导致较大的块体晶粒尺寸。总之,本研究提出了一个通过仔细调整氢化参数来改变相变过程从而设计氢化钛结构的框架,即条件-过程-结构关系。这种关系为管理氢化物在储氢元件和冶金应用中的晶粒细化或粗化提供了重要指导。
Correlating the microstructure of titanium hydride with its hydrogenation conditions via thermodynamics and kinetics
Titanium hydride is widely considered as an important hydrogen storage material due to its high capacity, stability and low cost. The microstructure of titanium hydride, which is usually induced by the hydrogenation of titanium, strongly influences its storage performance. However, the relationship between the hydrogenation conditions and the derived microstructure of titanium hydride is still unclear, limiting the development of its structure design strategy. In this work, the microstructure of titanium hydride is correlated with its hydrogenation conditions through the thermodynamics and kinetics. By evaluating the effects of the hydrogenation temperature, pressure and cooling rate, three classes of the hydrogenation processes were clarified: kinetic-limited, continuous and stepwise. Besides, according to the SEM and FIB-STEM results, these different processes are confirmed to greatly vary the bulk microstructure. It is concluded that a fast and continuous transition induces a broken bulk morphology, while a stepwise process leads to a larger bulk grain size. In summary, this study presents a framework for designing titanium hydride structures by modifying phase transition processes through careful adjustment of hydrogenation parameters, namely, a condition-process-structure relationship. This relationship offers crucial guidance in managing the grain refinement or coarsening of hydrides within hydrogen storage components and metallurgical applications.
期刊介绍:
Materials Characterization features original articles and state-of-the-art reviews on theoretical and practical aspects of the structure and behaviour of materials.
The Journal focuses on all characterization techniques, including all forms of microscopy (light, electron, acoustic, etc.,) and analysis (especially microanalysis and surface analytical techniques). Developments in both this wide range of techniques and their application to the quantification of the microstructure of materials are essential facets of the Journal.
The Journal provides the Materials Scientist/Engineer with up-to-date information on many types of materials with an underlying theme of explaining the behavior of materials using novel approaches. Materials covered by the journal include:
Metals & Alloys
Ceramics
Nanomaterials
Biomedical materials
Optical materials
Composites
Natural Materials.