揭示巧妙的铜基金属有机框架在气体储存和分离方面的潜力

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews Pub Date : 2024-09-26 DOI:10.1016/j.ccr.2024.216230

Sandeep Kumar , Raeesh Muhammad , Abdulkarem Amhamed , Hyunchul Oh

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引用次数: 0

摘要

本研究回顾了为增强气体吸附和分离而设计的铜基金属有机框架（Cu-MOFs）。这些 MOFs 具有经过战略性设计的结构特征，从而优化了气体储存和分离应用的性能。量身定制的巧妙 Cu-MOFs 在选择性捕获氢气 (H2)、二氧化碳 (CO2) 以及其他各种气体（包括碳氢化合物和惰性气体）方面表现出卓越的效率，在工业气体储存和分离以及环境修复方面具有潜力。Cu-MOFs 的系统设计方法可精确控制孔隙结构、孔径、表面积、开放金属位点和孔隙功能，从而提高气体吸附和选择性分离能力。这项研究强调了各种气体的储存和分离，揭示了 Cu-MOFs 的潜力，为应对清洁能源和环境可持续性方面的挑战提供了创新解决方案。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Unveiling the potential of ingenious copper-based metal-organic frameworks in gas storage and separation

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Unveiling the potential of ingenious copper-based metal-organic frameworks in gas storage and separation

This study reviews copper-based metal–organic frameworks (Cu-MOFs) designed for enhanced gas adsorption and separation. These MOFs exhibit strategically designed structural features, resulting in optimized performance in gas storage and separation applications. The tailored ingenious Cu-MOFs demonstrate remarkable efficiency in the selective capture of hydrogen (H₂), carbon dioxide (CO₂), and various other gases including hydrocarbons and noble gases, with potential in industrial gas storage and separation, and environmental remediation. The systematic design approach of Cu-MOFs enables precise control over pore structures, pore size, surface area, open metal site and pore functionality, enhancing gas adsorption and selective separation capacities. This study highlights the storage and separation of various gases, unveiling potential of Cu-MOFs providing innovative solutions for addressing challenges in clean energy, and environmental sustainability.

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来源期刊

Coordination Chemistry Reviews 化学-无机化学与核化学

CiteScore

34.30

自引率

5.30%

发文量

457

审稿时长

54 days

期刊介绍： Coordination Chemistry Reviews offers rapid publication of review articles on current and significant topics in coordination chemistry, encompassing organometallic, supramolecular, theoretical, and bioinorganic chemistry. It also covers catalysis, materials chemistry, and metal-organic frameworks from a coordination chemistry perspective. Reviews summarize recent developments or discuss specific techniques, welcoming contributions from both established and emerging researchers. The journal releases special issues on timely subjects, including those featuring contributions from specific regions or conferences. Occasional full-length book articles are also featured. Additionally, special volumes cover annual reviews of main group chemistry, transition metal group chemistry, and organometallic chemistry. These comprehensive reviews are vital resources for those engaged in coordination chemistry, further establishing Coordination Chemistry Reviews as a hub for insightful surveys in inorganic and physical inorganic chemistry.