Sijia Liu , Haiyun Gu , Ken Yang , Junyuan Guo , Kai Wu , Lijie Guo , Zhenghong Yang , Linglin Xu
{"title":"通过 pH 值摆动法制备活性尾矿:实现胶结尾矿回填和就地二氧化碳矿化","authors":"Sijia Liu , Haiyun Gu , Ken Yang , Junyuan Guo , Kai Wu , Lijie Guo , Zhenghong Yang , Linglin Xu","doi":"10.1016/j.cemconcomp.2024.105767","DOIUrl":null,"url":null,"abstract":"<div><div>In-situ CO<sub>2</sub> mineralization of tailings holds great potential for large-scale CO<sub>2</sub> sequestration, but its development is seriously limited by the low CO<sub>2</sub> conversion rate. This study proposed an innovative pH swing process to produce activated tailings through magnesium extraction from raw tailings and subsequent leachate precipitation. By the combination of activated tailings and high-belite calcium sulfoaluminate cement, a new type of cemented activated tailings backfill (CATB) was developed. The results demonstrate that 82.33 % of magnesium is extracted from raw tailings and precipitates in the form of Mg(OH)<sub>2</sub> serving as the dominating carbonation active phase during the pH swing process. Besides the aragonite forms in the carbonated cemented raw tailings backfill (CRTB), carbonated CATB also contains calcite, nesquehonite, and hydromagnesite. Substituting activated tailings for raw tailings results in a higher CO<sub>2</sub> absorption capability (ranging from 8.88 % to 14.17 % with various binder-to-tailings ratios). These indicate that the activated tailings have a promising application scenario in large scale in-situ CO<sub>2</sub> mineralization.</div></div>","PeriodicalId":9865,"journal":{"name":"Cement & concrete composites","volume":"154 ","pages":"Article 105767"},"PeriodicalIF":10.8000,"publicationDate":"2024-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Preparation activated tailings by pH swing process: Towards yielding cemented tailings backfill and in-situ CO2 mineralization\",\"authors\":\"Sijia Liu , Haiyun Gu , Ken Yang , Junyuan Guo , Kai Wu , Lijie Guo , Zhenghong Yang , Linglin Xu\",\"doi\":\"10.1016/j.cemconcomp.2024.105767\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In-situ CO<sub>2</sub> mineralization of tailings holds great potential for large-scale CO<sub>2</sub> sequestration, but its development is seriously limited by the low CO<sub>2</sub> conversion rate. This study proposed an innovative pH swing process to produce activated tailings through magnesium extraction from raw tailings and subsequent leachate precipitation. By the combination of activated tailings and high-belite calcium sulfoaluminate cement, a new type of cemented activated tailings backfill (CATB) was developed. The results demonstrate that 82.33 % of magnesium is extracted from raw tailings and precipitates in the form of Mg(OH)<sub>2</sub> serving as the dominating carbonation active phase during the pH swing process. Besides the aragonite forms in the carbonated cemented raw tailings backfill (CRTB), carbonated CATB also contains calcite, nesquehonite, and hydromagnesite. Substituting activated tailings for raw tailings results in a higher CO<sub>2</sub> absorption capability (ranging from 8.88 % to 14.17 % with various binder-to-tailings ratios). These indicate that the activated tailings have a promising application scenario in large scale in-situ CO<sub>2</sub> mineralization.</div></div>\",\"PeriodicalId\":9865,\"journal\":{\"name\":\"Cement & concrete composites\",\"volume\":\"154 \",\"pages\":\"Article 105767\"},\"PeriodicalIF\":10.8000,\"publicationDate\":\"2024-09-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Cement & concrete composites\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0958946524003408\",\"RegionNum\":1,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CONSTRUCTION & BUILDING TECHNOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Cement & concrete composites","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0958946524003408","RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CONSTRUCTION & BUILDING TECHNOLOGY","Score":null,"Total":0}
Preparation activated tailings by pH swing process: Towards yielding cemented tailings backfill and in-situ CO2 mineralization
In-situ CO2 mineralization of tailings holds great potential for large-scale CO2 sequestration, but its development is seriously limited by the low CO2 conversion rate. This study proposed an innovative pH swing process to produce activated tailings through magnesium extraction from raw tailings and subsequent leachate precipitation. By the combination of activated tailings and high-belite calcium sulfoaluminate cement, a new type of cemented activated tailings backfill (CATB) was developed. The results demonstrate that 82.33 % of magnesium is extracted from raw tailings and precipitates in the form of Mg(OH)2 serving as the dominating carbonation active phase during the pH swing process. Besides the aragonite forms in the carbonated cemented raw tailings backfill (CRTB), carbonated CATB also contains calcite, nesquehonite, and hydromagnesite. Substituting activated tailings for raw tailings results in a higher CO2 absorption capability (ranging from 8.88 % to 14.17 % with various binder-to-tailings ratios). These indicate that the activated tailings have a promising application scenario in large scale in-situ CO2 mineralization.
期刊介绍:
Cement & concrete composites focuses on advancements in cement-concrete composite technology and the production, use, and performance of cement-based construction materials. It covers a wide range of materials, including fiber-reinforced composites, polymer composites, ferrocement, and those incorporating special aggregates or waste materials. Major themes include microstructure, material properties, testing, durability, mechanics, modeling, design, fabrication, and practical applications. The journal welcomes papers on structural behavior, field studies, repair and maintenance, serviceability, and sustainability. It aims to enhance understanding, provide a platform for unconventional materials, promote low-cost energy-saving materials, and bridge the gap between materials science, engineering, and construction. Special issues on emerging topics are also published to encourage collaboration between materials scientists, engineers, designers, and fabricators.