Xiaowei Deng , Xu Chen , Meng Wang , Weilong Qin , Gaoqiang Li , Jiaqiong Qin , Yanbing Han , Mochen Jia , Xinjian Li , Zhifeng Shi
{"title":"掺杂镧系元素的 Cs2NaInCl6:Sb3+ 从可见光到近红外的多色多模发光,可用于多种应用领域","authors":"Xiaowei Deng , Xu Chen , Meng Wang , Weilong Qin , Gaoqiang Li , Jiaqiong Qin , Yanbing Han , Mochen Jia , Xinjian Li , Zhifeng Shi","doi":"10.1016/j.jlumin.2024.120908","DOIUrl":null,"url":null,"abstract":"<div><div>Double halide perovskites have shown admirable potential in promising optoelectronic applications due to simple synthesis, good stability and high structural tolerance. However, the poor optical properties caused by the parity-forbidden transitions posts a stringent limitation on their potential applications. Herein, we dope the lanthanide (Ln<sup>3+</sup>) ions with abundant energy levels into the Cs<sub>2</sub>NaInCl<sub>6</sub>:Sb<sup>3+</sup> single crystals, which not only achieve multicolor visible emissions spectra from blue to red light, but also expand to the near infrared region from 800 to 1900 nm. In addition, the phosphors enable the multimode emissions with the up-conversion and down-conversion photoluminescence. Intriguingly, the excitation source, and the excitation light intensity also endow the multicolor emissions. Thus, combining with the multicolor and multimode luminescent properties, Cs<sub>2</sub>NaInCl<sub>6</sub>:Sb<sup>3+</sup>/Ln<sup>3+</sup> could be applied to night vision imaging, substance detection, optical thermometry, white-light-emitting diodes (WLEDs) and anti-counterfeiting. The maximum value of relative temperature sensitivity reaches as high as 1.207 % K<sup>−1</sup>, which is relatively higher than those of most metal halide perovskites. Moreover, the single-source WLED displays Commission Internationale de L'Eclairage color coordinates (0.32, 0.31), a correlated color temperature of 6673 K, and color rendering index of 81.7. These results demonstrate the potential applications in the multifunctional photoelectric applications.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"277 ","pages":"Article 120908"},"PeriodicalIF":3.3000,"publicationDate":"2024-09-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Multicolor and multimode luminescent lanthanide-doped Cs2NaInCl6:Sb3+ from visible to near infrared for versatile applications\",\"authors\":\"Xiaowei Deng , Xu Chen , Meng Wang , Weilong Qin , Gaoqiang Li , Jiaqiong Qin , Yanbing Han , Mochen Jia , Xinjian Li , Zhifeng Shi\",\"doi\":\"10.1016/j.jlumin.2024.120908\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Double halide perovskites have shown admirable potential in promising optoelectronic applications due to simple synthesis, good stability and high structural tolerance. However, the poor optical properties caused by the parity-forbidden transitions posts a stringent limitation on their potential applications. Herein, we dope the lanthanide (Ln<sup>3+</sup>) ions with abundant energy levels into the Cs<sub>2</sub>NaInCl<sub>6</sub>:Sb<sup>3+</sup> single crystals, which not only achieve multicolor visible emissions spectra from blue to red light, but also expand to the near infrared region from 800 to 1900 nm. In addition, the phosphors enable the multimode emissions with the up-conversion and down-conversion photoluminescence. Intriguingly, the excitation source, and the excitation light intensity also endow the multicolor emissions. Thus, combining with the multicolor and multimode luminescent properties, Cs<sub>2</sub>NaInCl<sub>6</sub>:Sb<sup>3+</sup>/Ln<sup>3+</sup> could be applied to night vision imaging, substance detection, optical thermometry, white-light-emitting diodes (WLEDs) and anti-counterfeiting. The maximum value of relative temperature sensitivity reaches as high as 1.207 % K<sup>−1</sup>, which is relatively higher than those of most metal halide perovskites. Moreover, the single-source WLED displays Commission Internationale de L'Eclairage color coordinates (0.32, 0.31), a correlated color temperature of 6673 K, and color rendering index of 81.7. These results demonstrate the potential applications in the multifunctional photoelectric applications.</div></div>\",\"PeriodicalId\":16159,\"journal\":{\"name\":\"Journal of Luminescence\",\"volume\":\"277 \",\"pages\":\"Article 120908\"},\"PeriodicalIF\":3.3000,\"publicationDate\":\"2024-09-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Luminescence\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0022231324004721\",\"RegionNum\":3,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"OPTICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Luminescence","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0022231324004721","RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"OPTICS","Score":null,"Total":0}
Multicolor and multimode luminescent lanthanide-doped Cs2NaInCl6:Sb3+ from visible to near infrared for versatile applications
Double halide perovskites have shown admirable potential in promising optoelectronic applications due to simple synthesis, good stability and high structural tolerance. However, the poor optical properties caused by the parity-forbidden transitions posts a stringent limitation on their potential applications. Herein, we dope the lanthanide (Ln3+) ions with abundant energy levels into the Cs2NaInCl6:Sb3+ single crystals, which not only achieve multicolor visible emissions spectra from blue to red light, but also expand to the near infrared region from 800 to 1900 nm. In addition, the phosphors enable the multimode emissions with the up-conversion and down-conversion photoluminescence. Intriguingly, the excitation source, and the excitation light intensity also endow the multicolor emissions. Thus, combining with the multicolor and multimode luminescent properties, Cs2NaInCl6:Sb3+/Ln3+ could be applied to night vision imaging, substance detection, optical thermometry, white-light-emitting diodes (WLEDs) and anti-counterfeiting. The maximum value of relative temperature sensitivity reaches as high as 1.207 % K−1, which is relatively higher than those of most metal halide perovskites. Moreover, the single-source WLED displays Commission Internationale de L'Eclairage color coordinates (0.32, 0.31), a correlated color temperature of 6673 K, and color rendering index of 81.7. These results demonstrate the potential applications in the multifunctional photoelectric applications.
期刊介绍:
The purpose of the Journal of Luminescence is to provide a means of communication between scientists in different disciplines who share a common interest in the electronic excited states of molecular, ionic and covalent systems, whether crystalline, amorphous, or liquid.
We invite original papers and reviews on such subjects as: exciton and polariton dynamics, dynamics of localized excited states, energy and charge transport in ordered and disordered systems, radiative and non-radiative recombination, relaxation processes, vibronic interactions in electronic excited states, photochemistry in condensed systems, excited state resonance, double resonance, spin dynamics, selective excitation spectroscopy, hole burning, coherent processes in excited states, (e.g. coherent optical transients, photon echoes, transient gratings), multiphoton processes, optical bistability, photochromism, and new techniques for the study of excited states. This list is not intended to be exhaustive. Papers in the traditional areas of optical spectroscopy (absorption, MCD, luminescence, Raman scattering) are welcome. Papers on applications (phosphors, scintillators, electro- and cathodo-luminescence, radiography, bioimaging, solar energy, energy conversion, etc.) are also welcome if they present results of scientific, rather than only technological interest. However, papers containing purely theoretical results, not related to phenomena in the excited states, as well as papers using luminescence spectroscopy to perform routine analytical chemistry or biochemistry procedures, are outside the scope of the journal. Some exceptions will be possible at the discretion of the editors.