L. Guerra-Camacho , A. Ruiz-Garcia , F.A. Godínez , J. Genesca , H. Terryn , R. Montoya
{"title":"液滴蒸发过程中的对流对 CFRP-AA2024 电偶中腐蚀产物分布的影响:建模和实验方法","authors":"L. Guerra-Camacho , A. Ruiz-Garcia , F.A. Godínez , J. Genesca , H. Terryn , R. Montoya","doi":"10.1016/j.corsci.2024.112462","DOIUrl":null,"url":null,"abstract":"<div><div>This work aims to clarify the impact of convection, generated within an electrolyte droplet during evaporation, on the distribution of <span><math><mrow><mi>Al</mi><msub><mrow><mrow><mo>(</mo><mi>OH</mi><mo>)</mo></mrow></mrow><mrow><mn>3</mn></mrow></msub></mrow></math></span> in the CFRP-AA2024 system. Both Finite Element and experimental approaches were employed to determine whether convection is significant or negligible. By coupling the Navier–Stokes and Nernst–Planck equations with appropriate geometric and boundary conditions, the transient distribution of corrosion products was numerically tracked. The results showed that <span><math><mrow><mi>Al</mi><msub><mrow><mrow><mo>(</mo><mi>OH</mi><mo>)</mo></mrow></mrow><mrow><mn>3</mn></mrow></msub></mrow></math></span> preferentially deposits on the CFRP surface, a pattern absent when convection is excluded. Experiments confirmed that internal convective currents can transport the <span><math><mrow><mi>Al</mi><msub><mrow><mrow><mo>(</mo><mi>OH</mi><mo>)</mo></mrow></mrow><mrow><mn>3</mn></mrow></msub></mrow></math></span> compound, aligning with the numerical predictions.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"240 ","pages":"Article 112462"},"PeriodicalIF":7.4000,"publicationDate":"2024-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0010938X24006577/pdfft?md5=2c7d7c982147bc1855ba28dfd54ea1dc&pid=1-s2.0-S0010938X24006577-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Influence of convection during droplet evaporation on corrosion product distribution in CFRP-AA2024 galvanic couple: Modeling and experimental approaches\",\"authors\":\"L. Guerra-Camacho , A. Ruiz-Garcia , F.A. Godínez , J. Genesca , H. Terryn , R. Montoya\",\"doi\":\"10.1016/j.corsci.2024.112462\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>This work aims to clarify the impact of convection, generated within an electrolyte droplet during evaporation, on the distribution of <span><math><mrow><mi>Al</mi><msub><mrow><mrow><mo>(</mo><mi>OH</mi><mo>)</mo></mrow></mrow><mrow><mn>3</mn></mrow></msub></mrow></math></span> in the CFRP-AA2024 system. Both Finite Element and experimental approaches were employed to determine whether convection is significant or negligible. By coupling the Navier–Stokes and Nernst–Planck equations with appropriate geometric and boundary conditions, the transient distribution of corrosion products was numerically tracked. The results showed that <span><math><mrow><mi>Al</mi><msub><mrow><mrow><mo>(</mo><mi>OH</mi><mo>)</mo></mrow></mrow><mrow><mn>3</mn></mrow></msub></mrow></math></span> preferentially deposits on the CFRP surface, a pattern absent when convection is excluded. Experiments confirmed that internal convective currents can transport the <span><math><mrow><mi>Al</mi><msub><mrow><mrow><mo>(</mo><mi>OH</mi><mo>)</mo></mrow></mrow><mrow><mn>3</mn></mrow></msub></mrow></math></span> compound, aligning with the numerical predictions.</div></div>\",\"PeriodicalId\":290,\"journal\":{\"name\":\"Corrosion Science\",\"volume\":\"240 \",\"pages\":\"Article 112462\"},\"PeriodicalIF\":7.4000,\"publicationDate\":\"2024-09-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S0010938X24006577/pdfft?md5=2c7d7c982147bc1855ba28dfd54ea1dc&pid=1-s2.0-S0010938X24006577-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Corrosion Science\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0010938X24006577\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Corrosion Science","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0010938X24006577","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Influence of convection during droplet evaporation on corrosion product distribution in CFRP-AA2024 galvanic couple: Modeling and experimental approaches
This work aims to clarify the impact of convection, generated within an electrolyte droplet during evaporation, on the distribution of in the CFRP-AA2024 system. Both Finite Element and experimental approaches were employed to determine whether convection is significant or negligible. By coupling the Navier–Stokes and Nernst–Planck equations with appropriate geometric and boundary conditions, the transient distribution of corrosion products was numerically tracked. The results showed that preferentially deposits on the CFRP surface, a pattern absent when convection is excluded. Experiments confirmed that internal convective currents can transport the compound, aligning with the numerical predictions.
期刊介绍:
Corrosion occurrence and its practical control encompass a vast array of scientific knowledge. Corrosion Science endeavors to serve as the conduit for the exchange of ideas, developments, and research across all facets of this field, encompassing both metallic and non-metallic corrosion. The scope of this international journal is broad and inclusive. Published papers span from highly theoretical inquiries to essentially practical applications, covering diverse areas such as high-temperature oxidation, passivity, anodic oxidation, biochemical corrosion, stress corrosion cracking, and corrosion control mechanisms and methodologies.
This journal publishes original papers and critical reviews across the spectrum of pure and applied corrosion, material degradation, and surface science and engineering. It serves as a crucial link connecting metallurgists, materials scientists, and researchers investigating corrosion and degradation phenomena. Join us in advancing knowledge and understanding in the vital field of corrosion science.