调查含磷阻燃化学品对使用脲醛树脂生产的刨花板的影响

IF 4.3 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Nazan Uygur, Erdinc Doganci* and Ayse Aytac, 
{"title":"调查含磷阻燃化学品对使用脲醛树脂生产的刨花板的影响","authors":"Nazan Uygur,&nbsp;Erdinc Doganci* and Ayse Aytac,&nbsp;","doi":"10.1021/acsomega.4c0341910.1021/acsomega.4c03419","DOIUrl":null,"url":null,"abstract":"<p >In this study, urea–formaldehyde resins containing different phosphate-based flame retardants (FRs) were prepared to produce wood-based panels (medium-density fiberboard, particleboard, and veneer board), and their flammability properties were investigated. The changes in the gelation times were investigated when the phosphate-containing FRs used in different amounts were mixed with the resin. Chemicals that have both hardener and flame-retardant properties at the same time have been studied. In addition, the pH and thermal analyses of the resin and flame-retardant mixtures prepared in this study were performed by a pH meter and thermogravimetric analysis, respectively. The limiting oxygen index, UL-94 vertical burning, and cone calorimetry tests on the samples with the best combustion characteristics were carried out by sizing the particleboards in accordance with the standards and applying the prepared flame-retardant resins on them. The distribution of flame-retardant resin on the particleboard surface was investigated for the samples prepared by scanning electron microscopy. As a result of the analyses, it was determined that the samples containing 20% ammonium polyphosphate had good nonflammability properties.</p>","PeriodicalId":22,"journal":{"name":"ACS Omega","volume":"9 38","pages":"39513–39522 39513–39522"},"PeriodicalIF":4.3000,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acsomega.4c03419","citationCount":"0","resultStr":"{\"title\":\"Investigation of the Effects of Phosphate-Containing Flame-Retardant Chemicals on Particleboards Produced Using Urea–Formaldehyde Resin\",\"authors\":\"Nazan Uygur,&nbsp;Erdinc Doganci* and Ayse Aytac,&nbsp;\",\"doi\":\"10.1021/acsomega.4c0341910.1021/acsomega.4c03419\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >In this study, urea–formaldehyde resins containing different phosphate-based flame retardants (FRs) were prepared to produce wood-based panels (medium-density fiberboard, particleboard, and veneer board), and their flammability properties were investigated. The changes in the gelation times were investigated when the phosphate-containing FRs used in different amounts were mixed with the resin. Chemicals that have both hardener and flame-retardant properties at the same time have been studied. In addition, the pH and thermal analyses of the resin and flame-retardant mixtures prepared in this study were performed by a pH meter and thermogravimetric analysis, respectively. The limiting oxygen index, UL-94 vertical burning, and cone calorimetry tests on the samples with the best combustion characteristics were carried out by sizing the particleboards in accordance with the standards and applying the prepared flame-retardant resins on them. The distribution of flame-retardant resin on the particleboard surface was investigated for the samples prepared by scanning electron microscopy. As a result of the analyses, it was determined that the samples containing 20% ammonium polyphosphate had good nonflammability properties.</p>\",\"PeriodicalId\":22,\"journal\":{\"name\":\"ACS Omega\",\"volume\":\"9 38\",\"pages\":\"39513–39522 39513–39522\"},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2024-09-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://pubs.acs.org/doi/epdf/10.1021/acsomega.4c03419\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Omega\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acsomega.4c03419\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Omega","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acsomega.4c03419","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

本研究制备了含有不同磷酸盐阻燃剂(FRs)的脲醛树脂,用于生产人造板(中密度纤维板、刨花板和单板),并对其可燃性能进行了研究。研究了不同用量的含磷阻燃剂与树脂混合后凝胶化时间的变化。还研究了同时具有固化剂和阻燃特性的化学品。此外,本研究中制备的树脂和阻燃剂混合物的 pH 值和热分析分别通过 pH 计和热重分析进行。通过按照标准确定刨花板的尺寸并在其上涂抹制备的阻燃树脂,对具有最佳燃烧特性的样品进行了极限氧指数、UL-94 垂直燃烧和锥形量热试验。通过扫描电子显微镜研究了阻燃树脂在刨花板表面的分布情况。分析结果表明,含有 20% 聚磷酸铵的样品具有良好的阻燃性能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Investigation of the Effects of Phosphate-Containing Flame-Retardant Chemicals on Particleboards Produced Using Urea–Formaldehyde Resin

In this study, urea–formaldehyde resins containing different phosphate-based flame retardants (FRs) were prepared to produce wood-based panels (medium-density fiberboard, particleboard, and veneer board), and their flammability properties were investigated. The changes in the gelation times were investigated when the phosphate-containing FRs used in different amounts were mixed with the resin. Chemicals that have both hardener and flame-retardant properties at the same time have been studied. In addition, the pH and thermal analyses of the resin and flame-retardant mixtures prepared in this study were performed by a pH meter and thermogravimetric analysis, respectively. The limiting oxygen index, UL-94 vertical burning, and cone calorimetry tests on the samples with the best combustion characteristics were carried out by sizing the particleboards in accordance with the standards and applying the prepared flame-retardant resins on them. The distribution of flame-retardant resin on the particleboard surface was investigated for the samples prepared by scanning electron microscopy. As a result of the analyses, it was determined that the samples containing 20% ammonium polyphosphate had good nonflammability properties.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
ACS Omega
ACS Omega Chemical Engineering-General Chemical Engineering
CiteScore
6.60
自引率
4.90%
发文量
3945
审稿时长
2.4 months
期刊介绍: ACS Omega is an open-access global publication for scientific articles that describe new findings in chemistry and interfacing areas of science, without any perceived evaluation of immediate impact.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信