Xin Sun, Jindi Yang, Dr. Xiangkang Zeng, Lijun Guo, Dr. Chuanbiao Bie, Zhuyuan Wang, Kaige Sun, Dr. Aloka Kumar Sahu, Dr. Mike Tebyetekerwa, Prof. Thomas E. Rufford, Prof. Xiwang Zhang
{"title":"氧还原与水氧化配对，实现双途径 H2O2 生产。","authors":"Xin Sun, Jindi Yang, Dr. Xiangkang Zeng, Lijun Guo, Dr. Chuanbiao Bie, Zhuyuan Wang, Kaige Sun, Dr. Aloka Kumar Sahu, Dr. Mike Tebyetekerwa, Prof. Thomas E. Rufford, Prof. Xiwang Zhang","doi":"10.1002/anie.202414417","DOIUrl":null,"url":null,"abstract":"<p>Hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>) is a crucial chemical applied in various industry sectors. However, the current industrial anthraquinone process for H<sub>2</sub>O<sub>2</sub> synthesis is carbon-intensive. With sunlight and renewable electricity as energy inputs, photocatalysis and electrocatalysis have great potential for green H<sub>2</sub>O<sub>2</sub> production from oxygen (O<sub>2</sub>) and water (H<sub>2</sub>O). Herein, we review the advances in pairing two-electron O<sub>2</sub> reduction and two-electron H<sub>2</sub>O oxidation reactions for dual-pathway H<sub>2</sub>O<sub>2</sub> synthesis. The basic principles, paired redox reactions, and catalytic device configurations are introduced initially. Aligning with the energy input, the latest photocatalysts, electrocatalysts, and photo-electrocatalysts for dual-pathway H<sub>2</sub>O<sub>2</sub> production are discussed afterward. Finally, we outlook the research opportunities in the future. This minireview aims to provide insights and guidelines for the broad community who are interested in catalyst design and innovative technology for on-site H<sub>2</sub>O<sub>2</sub> synthesis.</p>","PeriodicalId":125,"journal":{"name":"Angewandte Chemie International Edition","volume":"63 52","pages":""},"PeriodicalIF":16.1000,"publicationDate":"2024-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/anie.202414417","citationCount":"0","resultStr":"{\"title\":\"Pairing Oxygen Reduction and Water Oxidation for Dual-Pathway H2O2 Production\",\"authors\":\"Xin Sun, Jindi Yang, Dr. Xiangkang Zeng, Lijun Guo, Dr. Chuanbiao Bie, Zhuyuan Wang, Kaige Sun, Dr. Aloka Kumar Sahu, Dr. Mike Tebyetekerwa, Prof. Thomas E. Rufford, Prof. Xiwang Zhang\",\"doi\":\"10.1002/anie.202414417\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>) is a crucial chemical applied in various industry sectors. However, the current industrial anthraquinone process for H<sub>2</sub>O<sub>2</sub> synthesis is carbon-intensive. With sunlight and renewable electricity as energy inputs, photocatalysis and electrocatalysis have great potential for green H<sub>2</sub>O<sub>2</sub> production from oxygen (O<sub>2</sub>) and water (H<sub>2</sub>O). Herein, we review the advances in pairing two-electron O<sub>2</sub> reduction and two-electron H<sub>2</sub>O oxidation reactions for dual-pathway H<sub>2</sub>O<sub>2</sub> synthesis. The basic principles, paired redox reactions, and catalytic device configurations are introduced initially. Aligning with the energy input, the latest photocatalysts, electrocatalysts, and photo-electrocatalysts for dual-pathway H<sub>2</sub>O<sub>2</sub> production are discussed afterward. Finally, we outlook the research opportunities in the future. This minireview aims to provide insights and guidelines for the broad community who are interested in catalyst design and innovative technology for on-site H<sub>2</sub>O<sub>2</sub> synthesis.</p>\",\"PeriodicalId\":125,\"journal\":{\"name\":\"Angewandte Chemie International Edition\",\"volume\":\"63 52\",\"pages\":\"\"},\"PeriodicalIF\":16.1000,\"publicationDate\":\"2024-09-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/anie.202414417\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Angewandte Chemie International Edition\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/anie.202414417\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Angewandte Chemie International Edition","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/anie.202414417","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Pairing Oxygen Reduction and Water Oxidation for Dual-Pathway H2O2 Production
Hydrogen peroxide (H2O2) is a crucial chemical applied in various industry sectors. However, the current industrial anthraquinone process for H2O2 synthesis is carbon-intensive. With sunlight and renewable electricity as energy inputs, photocatalysis and electrocatalysis have great potential for green H2O2 production from oxygen (O2) and water (H2O). Herein, we review the advances in pairing two-electron O2 reduction and two-electron H2O oxidation reactions for dual-pathway H2O2 synthesis. The basic principles, paired redox reactions, and catalytic device configurations are introduced initially. Aligning with the energy input, the latest photocatalysts, electrocatalysts, and photo-electrocatalysts for dual-pathway H2O2 production are discussed afterward. Finally, we outlook the research opportunities in the future. This minireview aims to provide insights and guidelines for the broad community who are interested in catalyst design and innovative technology for on-site H2O2 synthesis.
期刊介绍：
Angewandte Chemie, a journal of the German Chemical Society (GDCh), maintains a leading position among scholarly journals in general chemistry with an impressive Impact Factor of 16.6 (2022 Journal Citation Reports, Clarivate, 2023). Published weekly in a reader-friendly format, it features new articles almost every day. Established in 1887, Angewandte Chemie is a prominent chemistry journal, offering a dynamic blend of Review-type articles, Highlights, Communications, and Research Articles on a weekly basis, making it unique in the field.
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