{"title":"分子特性的灵敏度编年史：揭开双光束 Z-Scan 和时间分辨热透镜光谱学的神秘面纱。","authors":"Aman Sharma, Sumit Kumar Gupta, Debabrata Goswami","doi":"10.1021/acs.jpca.4c04030","DOIUrl":null,"url":null,"abstract":"<p><p>Ultrasensitive thermal lens (TL) spectroscopy, where the interplay between conduction and convection is crucial, provides profound insights into molecular behavior. This work focuses on the critical role of molecular convection by using the dual-beam z-scan method and time-resolved TL spectroscopy. We specifically investigated the correlation between the detection iris and the spot size of the pump beam. Additionally, we address detection limitations and their influence on the perception of convection timing. We introduce an experimentally derived ratio optimized for higher sensitivity, enhancing the reliability of TL spectroscopy. This refined approach to TL spectroscopy allows for a deeper exploration of molecular characteristics in liquids.</p>","PeriodicalId":2,"journal":{"name":"ACS Applied Bio Materials","volume":null,"pages":null},"PeriodicalIF":4.6000,"publicationDate":"2024-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Sensitivity Chronicles in Molecular Properties: Unraveling the Nexus of Dual-Beam Z-Scan and Time-Resolved Thermal Lens Spectroscopy.\",\"authors\":\"Aman Sharma, Sumit Kumar Gupta, Debabrata Goswami\",\"doi\":\"10.1021/acs.jpca.4c04030\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Ultrasensitive thermal lens (TL) spectroscopy, where the interplay between conduction and convection is crucial, provides profound insights into molecular behavior. This work focuses on the critical role of molecular convection by using the dual-beam z-scan method and time-resolved TL spectroscopy. We specifically investigated the correlation between the detection iris and the spot size of the pump beam. Additionally, we address detection limitations and their influence on the perception of convection timing. We introduce an experimentally derived ratio optimized for higher sensitivity, enhancing the reliability of TL spectroscopy. This refined approach to TL spectroscopy allows for a deeper exploration of molecular characteristics in liquids.</p>\",\"PeriodicalId\":2,\"journal\":{\"name\":\"ACS Applied Bio Materials\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":4.6000,\"publicationDate\":\"2024-10-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Applied Bio Materials\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://doi.org/10.1021/acs.jpca.4c04030\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2024/9/23 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, BIOMATERIALS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Bio Materials","FirstCategoryId":"1","ListUrlMain":"https://doi.org/10.1021/acs.jpca.4c04030","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/9/23 0:00:00","PubModel":"Epub","JCR":"Q2","JCRName":"MATERIALS SCIENCE, BIOMATERIALS","Score":null,"Total":0}
Sensitivity Chronicles in Molecular Properties: Unraveling the Nexus of Dual-Beam Z-Scan and Time-Resolved Thermal Lens Spectroscopy.
Ultrasensitive thermal lens (TL) spectroscopy, where the interplay between conduction and convection is crucial, provides profound insights into molecular behavior. This work focuses on the critical role of molecular convection by using the dual-beam z-scan method and time-resolved TL spectroscopy. We specifically investigated the correlation between the detection iris and the spot size of the pump beam. Additionally, we address detection limitations and their influence on the perception of convection timing. We introduce an experimentally derived ratio optimized for higher sensitivity, enhancing the reliability of TL spectroscopy. This refined approach to TL spectroscopy allows for a deeper exploration of molecular characteristics in liquids.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
