{"title":"用作钠离子电池负极材料的甘蔗渣衍生碳气凝胶","authors":"Xinyu Yang, Shijiao Sun, Xiangyu Zhao","doi":"10.1016/j.matlet.2024.137414","DOIUrl":null,"url":null,"abstract":"<div><p>Biomass-derived carbons have been regarded as promising anode materials for sodium-ion batteries due to their tunable physicochemical properties, economic value, and environmental considerations. Nowadays, most of biomass-derived carbon materials are directly prepared through a one-step carbonization process, which may damage the inherent structure of biomass materials. In this work, hydrothermal and freeze-drying pretreatment before carbonization was employed to prepare sugarcane bagasse derived carbon aerogels, which can preserve the unique structure of the biomass material. When utilized as anode materials for sodium-ion batteries, the optimized carbon aerogel delivered an initial discharge capacity as high as 380 mAh g<sup>−1</sup> at a current density of 50 mA g<sup>−1</sup>. After 50 cycles, the reversible specific capacity was still maintained at 248 mAh g<sup>−1</sup>.</p></div>","PeriodicalId":384,"journal":{"name":"Materials Letters","volume":"377 ","pages":"Article 137414"},"PeriodicalIF":2.7000,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Sugarcane bagasse derived carbon aerogels as anode materials for sodium-ion batteries\",\"authors\":\"Xinyu Yang, Shijiao Sun, Xiangyu Zhao\",\"doi\":\"10.1016/j.matlet.2024.137414\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Biomass-derived carbons have been regarded as promising anode materials for sodium-ion batteries due to their tunable physicochemical properties, economic value, and environmental considerations. Nowadays, most of biomass-derived carbon materials are directly prepared through a one-step carbonization process, which may damage the inherent structure of biomass materials. In this work, hydrothermal and freeze-drying pretreatment before carbonization was employed to prepare sugarcane bagasse derived carbon aerogels, which can preserve the unique structure of the biomass material. When utilized as anode materials for sodium-ion batteries, the optimized carbon aerogel delivered an initial discharge capacity as high as 380 mAh g<sup>−1</sup> at a current density of 50 mA g<sup>−1</sup>. After 50 cycles, the reversible specific capacity was still maintained at 248 mAh g<sup>−1</sup>.</p></div>\",\"PeriodicalId\":384,\"journal\":{\"name\":\"Materials Letters\",\"volume\":\"377 \",\"pages\":\"Article 137414\"},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2024-09-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Letters\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0167577X24015544\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Letters","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0167577X24015544","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
生物质衍生碳因其可调整的物理化学特性、经济价值和环境因素,一直被视为钠离子电池的理想负极材料。目前,大多数生物质衍生碳材料都是通过一步碳化工艺直接制备的,这可能会破坏生物质材料的固有结构。本研究在碳化前采用水热法和冷冻干燥法预处理甘蔗渣衍生碳气凝胶,从而保留了生物质材料的独特结构。将优化后的碳气凝胶用作钠离子电池的阳极材料时,在电流密度为 50 mA g-1 的条件下,初始放电容量高达 380 mAh g-1。经过 50 次循环后,可逆比容量仍保持在 248 mAh g-1。
Sugarcane bagasse derived carbon aerogels as anode materials for sodium-ion batteries
Biomass-derived carbons have been regarded as promising anode materials for sodium-ion batteries due to their tunable physicochemical properties, economic value, and environmental considerations. Nowadays, most of biomass-derived carbon materials are directly prepared through a one-step carbonization process, which may damage the inherent structure of biomass materials. In this work, hydrothermal and freeze-drying pretreatment before carbonization was employed to prepare sugarcane bagasse derived carbon aerogels, which can preserve the unique structure of the biomass material. When utilized as anode materials for sodium-ion batteries, the optimized carbon aerogel delivered an initial discharge capacity as high as 380 mAh g−1 at a current density of 50 mA g−1. After 50 cycles, the reversible specific capacity was still maintained at 248 mAh g−1.
期刊介绍:
Materials Letters has an open access mirror journal Materials Letters: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review.
Materials Letters is dedicated to publishing novel, cutting edge reports of broad interest to the materials community. The journal provides a forum for materials scientists and engineers, physicists, and chemists to rapidly communicate on the most important topics in the field of materials.
Contributions include, but are not limited to, a variety of topics such as:
• Materials - Metals and alloys, amorphous solids, ceramics, composites, polymers, semiconductors
• Applications - Structural, opto-electronic, magnetic, medical, MEMS, sensors, smart
• Characterization - Analytical, microscopy, scanning probes, nanoscopic, optical, electrical, magnetic, acoustic, spectroscopic, diffraction
• Novel Materials - Micro and nanostructures (nanowires, nanotubes, nanoparticles), nanocomposites, thin films, superlattices, quantum dots.
• Processing - Crystal growth, thin film processing, sol-gel processing, mechanical processing, assembly, nanocrystalline processing.
• Properties - Mechanical, magnetic, optical, electrical, ferroelectric, thermal, interfacial, transport, thermodynamic
• Synthesis - Quenching, solid state, solidification, solution synthesis, vapor deposition, high pressure, explosive