Angélica Martín-Lorenzo, Enrique Blázquez-Blázquez, José Manuel Gómez-Elvira, Mario Hoyos-Núñez
{"title":"用于高性能电介质的光活性芴官能化聚丙烯","authors":"Angélica Martín-Lorenzo, Enrique Blázquez-Blázquez, José Manuel Gómez-Elvira, Mario Hoyos-Núñez","doi":"10.1016/j.reactfunctpolym.2024.106059","DOIUrl":null,"url":null,"abstract":"<div><p>Reducing the impact of polyolefins on the environment is a difficult task not only because of its ubiquity in everyday items, but also because these polymers are used on a massive scale as high-performance materials, for example in electronics and automotive applications. This is the case for polypropylene that behaves as a robust and efficient dielectric in capacitors as a result of its high melting temperature and very low dielectric dissipation factor. The current challenge is to increase its low permittivity, in order to improve energy density and, at the same time, to contribute to the reduction of production, thus progressively increasing the miniaturization of devices.</p><p>Low content functionalisation has been found to be an efficient route to rise the polypropylene (PP) permittivity, without compromising the mechanical and thermal stability of the material. Recent work has shown that decreasing chain mobility in the amorphous phase is key to maintaining dielectric loss into the low level of PP. This has been achieved by inserting carbazole or N-alkyl pyrrole groups. The former increases the T<sub>g</sub> due to their characteristic π-π stacking interactions and both enable tailored crosslinking, UV and thermally activated respectively.</p><p>The present study analyses the synthesis and thermal and dielectric stabilities of poly-(propylene-<em>co</em>-9-(undec-10-en-1-yl)-9<em>H</em>-fluorene), with fluorene contents up to 3 mol%, as another example of PP grade that has both enhanced T<sub>g</sub> and crosslinking potential under UV radiation. Initial results reveal that these materials have a relative permittivity (ɛ<sub>r</sub>) up to 3 and dielectric losses under 0.005. As in the case of carbazole, the strong π-π stacking between fluorene units improves the thermal, mechanical and dielectric responses and also, that further improvement in stability would be possible under appropriate post-processing irradiation conditions.</p></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"205 ","pages":"Article 106059"},"PeriodicalIF":4.5000,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1381514824002347/pdfft?md5=4ebd53de6e578a43d49ddeb9a8186238&pid=1-s2.0-S1381514824002347-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Photoactive fluorenyl-functionalized polypropylene for high-performance dielectrics\",\"authors\":\"Angélica Martín-Lorenzo, Enrique Blázquez-Blázquez, José Manuel Gómez-Elvira, Mario Hoyos-Núñez\",\"doi\":\"10.1016/j.reactfunctpolym.2024.106059\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Reducing the impact of polyolefins on the environment is a difficult task not only because of its ubiquity in everyday items, but also because these polymers are used on a massive scale as high-performance materials, for example in electronics and automotive applications. This is the case for polypropylene that behaves as a robust and efficient dielectric in capacitors as a result of its high melting temperature and very low dielectric dissipation factor. The current challenge is to increase its low permittivity, in order to improve energy density and, at the same time, to contribute to the reduction of production, thus progressively increasing the miniaturization of devices.</p><p>Low content functionalisation has been found to be an efficient route to rise the polypropylene (PP) permittivity, without compromising the mechanical and thermal stability of the material. Recent work has shown that decreasing chain mobility in the amorphous phase is key to maintaining dielectric loss into the low level of PP. This has been achieved by inserting carbazole or N-alkyl pyrrole groups. The former increases the T<sub>g</sub> due to their characteristic π-π stacking interactions and both enable tailored crosslinking, UV and thermally activated respectively.</p><p>The present study analyses the synthesis and thermal and dielectric stabilities of poly-(propylene-<em>co</em>-9-(undec-10-en-1-yl)-9<em>H</em>-fluorene), with fluorene contents up to 3 mol%, as another example of PP grade that has both enhanced T<sub>g</sub> and crosslinking potential under UV radiation. Initial results reveal that these materials have a relative permittivity (ɛ<sub>r</sub>) up to 3 and dielectric losses under 0.005. As in the case of carbazole, the strong π-π stacking between fluorene units improves the thermal, mechanical and dielectric responses and also, that further improvement in stability would be possible under appropriate post-processing irradiation conditions.</p></div>\",\"PeriodicalId\":20916,\"journal\":{\"name\":\"Reactive & Functional Polymers\",\"volume\":\"205 \",\"pages\":\"Article 106059\"},\"PeriodicalIF\":4.5000,\"publicationDate\":\"2024-09-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S1381514824002347/pdfft?md5=4ebd53de6e578a43d49ddeb9a8186238&pid=1-s2.0-S1381514824002347-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Reactive & Functional Polymers\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1381514824002347\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Reactive & Functional Polymers","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1381514824002347","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Photoactive fluorenyl-functionalized polypropylene for high-performance dielectrics
Reducing the impact of polyolefins on the environment is a difficult task not only because of its ubiquity in everyday items, but also because these polymers are used on a massive scale as high-performance materials, for example in electronics and automotive applications. This is the case for polypropylene that behaves as a robust and efficient dielectric in capacitors as a result of its high melting temperature and very low dielectric dissipation factor. The current challenge is to increase its low permittivity, in order to improve energy density and, at the same time, to contribute to the reduction of production, thus progressively increasing the miniaturization of devices.
Low content functionalisation has been found to be an efficient route to rise the polypropylene (PP) permittivity, without compromising the mechanical and thermal stability of the material. Recent work has shown that decreasing chain mobility in the amorphous phase is key to maintaining dielectric loss into the low level of PP. This has been achieved by inserting carbazole or N-alkyl pyrrole groups. The former increases the Tg due to their characteristic π-π stacking interactions and both enable tailored crosslinking, UV and thermally activated respectively.
The present study analyses the synthesis and thermal and dielectric stabilities of poly-(propylene-co-9-(undec-10-en-1-yl)-9H-fluorene), with fluorene contents up to 3 mol%, as another example of PP grade that has both enhanced Tg and crosslinking potential under UV radiation. Initial results reveal that these materials have a relative permittivity (ɛr) up to 3 and dielectric losses under 0.005. As in the case of carbazole, the strong π-π stacking between fluorene units improves the thermal, mechanical and dielectric responses and also, that further improvement in stability would be possible under appropriate post-processing irradiation conditions.
期刊介绍:
Reactive & Functional Polymers provides a forum to disseminate original ideas, concepts and developments in the science and technology of polymers with functional groups, which impart specific chemical reactivity or physical, chemical, structural, biological, and pharmacological functionality. The scope covers organic polymers, acting for instance as reagents, catalysts, templates, ion-exchangers, selective sorbents, chelating or antimicrobial agents, drug carriers, sensors, membranes, and hydrogels. This also includes reactive cross-linkable prepolymers and high-performance thermosetting polymers, natural or degradable polymers, conducting polymers, and porous polymers.
Original research articles must contain thorough molecular and material characterization data on synthesis of the above polymers in combination with their applications. Applications include but are not limited to catalysis, water or effluent treatment, separations and recovery, electronics and information storage, energy conversion, encapsulation, or adhesion.