硅酸钠气凝胶的简史和前景--综述

IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CERAMICS
Askwar Hamanjida Hilonga
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引用次数: 0

摘要

这篇题为《硅酸钠气凝胶的简史和前景》的综述论文旨在吸引有兴趣投入时间和其他资源来利用硅气凝胶巨大潜力的初级研究人员和/或学生。它还将为该领域的专家提供快速参考和发展领域。本综述提供了确凿的证据,证明气凝胶水处理解决方案和其他潜在应用的前景比以往任何时候都要乐观。文中回顾了 20 世纪 30 年代的早期报告,并对当前的工作进行了严格审查。气凝胶是一种高度多孔的纳米材料,其 90% 以上的孔隙都充满了空气,可以组装成适合各种应用的纳米级结构。目前在 2023 年和 2024 年开展的工作包括通过常压处理改善光学透射率,采用两步法单凝胶程序生产气凝胶,并实现大规模工业生产/应用。从历史上看,人们一直在努力改进以下方面:(i) 前驱体制备,(ii) 凝胶化,(iii) 老化和 (iv) 干燥。这篇简短的评论文章旨在展示在以下方面所做的努力:(i) 利用超临界干燥法合成具有有趣特性的独特材料(气凝胶);(ii) 克服超临界干燥法带来的挑战;(iii) 在常压干燥前修饰湿硅薄膜的表面;(iv) 再生离子交换树脂;(v) 开发形成凝胶的单步单凝胶工艺;(vi) 合成光学透明的二氧化硅气凝胶;(vii) 采用多功能、成本效益高且不耗时的方法制备具有最大表面积的二氧化硅气凝胶;(viii) 研究气凝胶的可回收性并操纵其亲水性或疏水性;以及 (ix) 设计基于气凝胶的水处理系统。这篇综述文章重点介绍了硅酸钠基气凝胶的简史、前景及其潜在应用,特别是在水处理方面的应用。文章还指出了影响气凝胶大规模生产的关键问题。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

A brief history and prospects of sodium silicate-based aerogel - a review

A brief history and prospects of sodium silicate-based aerogel - a review

This review paper, A Brief History and Prospects of Sodium Silicate-Based Aerogel, aims to attract junior researchers and/or students interested in investing time and other resources to harness the overriding potential of silica aerogel. It will also invigorate the field experts for quick reference and areas of growth. This review provides solid evidence that the prospects for aerogel-based water treatment solutions and other potential applications are very optimistic than ever before. Early reports from the 1930s are reflected on, and current efforts are critically examined. Aerogel is a highly porous nanomaterial with more than 90% of its pores filled with air and can be assembled into nano-scale structures suitable for various applications. Current efforts in 2023 and 2024 include improving optical transmission through ambient pressure treatment to produce aerogels using a two-step sole-gel procedure and enable large scale industrial production/application. Historically, efforts have been made to improve the following aspects: (i) precursor preparation, (ii) gelation, (iii) aging, and (iv) drying. This brief review article intends to demonstrate the efforts made to: (i) synthesize a unique material (aerogels) with interesting properties using supercritical drying method; (ii) overcome the challenges caused by supercritical drying; (iii) modify the surface of a wet silica film prior to ambient pressure drying; (iv) regenerate the ion-exchange resin; (v) develop a single step sole-gel process to form a gel; (vi) synthesize optically transparent silica aerogels; (vii) prepare silica aerogel with the largest surface area by methods that are versatile, cost-effective, and not time consuming; (viii) investigate the recyclability of aerogels and manipulate their hydrophilicity or hydrophobicity and; and (ix) design aerogel-based water treatment system. This review article highlights the brief history and prospects of sodium silicate-based aerogels and its potential applications, particularly in water treatment. Critical issues affecting the large scale production of aerogels are also pointed out.

Graphical Abstract

A brief history of aerogel development and its prospects

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来源期刊
Journal of Sol-Gel Science and Technology
Journal of Sol-Gel Science and Technology 工程技术-材料科学:硅酸盐
CiteScore
4.70
自引率
4.00%
发文量
280
审稿时长
2.1 months
期刊介绍: The primary objective of the Journal of Sol-Gel Science and Technology (JSST), the official journal of the International Sol-Gel Society, is to provide an international forum for the dissemination of scientific, technological, and general knowledge about materials processed by chemical nanotechnologies known as the "sol-gel" process. The materials of interest include gels, gel-derived glasses, ceramics in form of nano- and micro-powders, bulk, fibres, thin films and coatings as well as more recent materials such as hybrid organic-inorganic materials and composites. Such materials exhibit a wide range of optical, electronic, magnetic, chemical, environmental, and biomedical properties and functionalities. Methods for producing sol-gel-derived materials and the industrial uses of these materials are also of great interest.
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