{"title":"通过同时进行 ATRP 和 ROP 一步法合成聚（甲基丙烯酸甲酯-b-ε-己内酯）嵌段共聚物","authors":"Temel Öztürk, Gözde Şenay Demir","doi":"10.1007/s12039-024-02309-y","DOIUrl":null,"url":null,"abstract":"<div><p>In this study, the simultaneous synthesis of poly(methyl methacrylate-b-<i>ε</i>-caprolactone) block copolymer was fulfilled by atom transfer radical polymerization of methyl methacrylate and ring-opening polymerization of <i>ε</i>-caprolactone. The synthesis of poly(methyl methacrylate-b-<i>ε</i>-caprolactone) block copolymer was carried out by varying the amount of <i>ε</i>-caprolactone monomer, the amount of methyl methacrylate monomer, the amount of 2-(2-chloroethoxy) ethanol initiator, the amount of toluene solvent, and the polymerization time. The effects of these parameters on the reaction conditions were investigated. Fourier transform infrared spectroscopy, proton nuclear magnetic resonance spectroscopy, and static light scattering methods were used for the characterization of the synthesized block copolymer. The surface images of the block copolymer were photographed with a scanning electron microscope instrument. In addition, thermal analysis of the synthesized block copolymer was performed using a thermogravimetric analyzer. These analyses prove the formation of the block copolymer structure.</p><h3>Graphical abstract</h3><p>\nThe simultaneous synthesis of poly(methyl methacrylate-b-<i>ε</i>-caprolactone) block copolymer was fulfilled by the atom transfer radical polymerization of methyl methacrylate and ring-opening polymerization of <i>ε</i>-caprolactone. The effects of the parameters on the polymerization reaction conditions were investigated. Thermal and spectroscopic measurements prove the formation of the block copolymer structure.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":616,"journal":{"name":"Journal of Chemical Sciences","volume":null,"pages":null},"PeriodicalIF":1.7000,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"One-step synthesis of poly(methyl methacrylate-b-ε-caprolactone) block copolymer by simultaneous ATRP and ROP\",\"authors\":\"Temel Öztürk, Gözde Şenay Demir\",\"doi\":\"10.1007/s12039-024-02309-y\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In this study, the simultaneous synthesis of poly(methyl methacrylate-b-<i>ε</i>-caprolactone) block copolymer was fulfilled by atom transfer radical polymerization of methyl methacrylate and ring-opening polymerization of <i>ε</i>-caprolactone. The synthesis of poly(methyl methacrylate-b-<i>ε</i>-caprolactone) block copolymer was carried out by varying the amount of <i>ε</i>-caprolactone monomer, the amount of methyl methacrylate monomer, the amount of 2-(2-chloroethoxy) ethanol initiator, the amount of toluene solvent, and the polymerization time. The effects of these parameters on the reaction conditions were investigated. Fourier transform infrared spectroscopy, proton nuclear magnetic resonance spectroscopy, and static light scattering methods were used for the characterization of the synthesized block copolymer. The surface images of the block copolymer were photographed with a scanning electron microscope instrument. In addition, thermal analysis of the synthesized block copolymer was performed using a thermogravimetric analyzer. These analyses prove the formation of the block copolymer structure.</p><h3>Graphical abstract</h3><p>\\nThe simultaneous synthesis of poly(methyl methacrylate-b-<i>ε</i>-caprolactone) block copolymer was fulfilled by the atom transfer radical polymerization of methyl methacrylate and ring-opening polymerization of <i>ε</i>-caprolactone. The effects of the parameters on the polymerization reaction conditions were investigated. Thermal and spectroscopic measurements prove the formation of the block copolymer structure.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":616,\"journal\":{\"name\":\"Journal of Chemical Sciences\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.7000,\"publicationDate\":\"2024-09-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Chemical Sciences\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s12039-024-02309-y\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Chemical Sciences","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s12039-024-02309-y","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
One-step synthesis of poly(methyl methacrylate-b-ε-caprolactone) block copolymer by simultaneous ATRP and ROP
In this study, the simultaneous synthesis of poly(methyl methacrylate-b-ε-caprolactone) block copolymer was fulfilled by atom transfer radical polymerization of methyl methacrylate and ring-opening polymerization of ε-caprolactone. The synthesis of poly(methyl methacrylate-b-ε-caprolactone) block copolymer was carried out by varying the amount of ε-caprolactone monomer, the amount of methyl methacrylate monomer, the amount of 2-(2-chloroethoxy) ethanol initiator, the amount of toluene solvent, and the polymerization time. The effects of these parameters on the reaction conditions were investigated. Fourier transform infrared spectroscopy, proton nuclear magnetic resonance spectroscopy, and static light scattering methods were used for the characterization of the synthesized block copolymer. The surface images of the block copolymer were photographed with a scanning electron microscope instrument. In addition, thermal analysis of the synthesized block copolymer was performed using a thermogravimetric analyzer. These analyses prove the formation of the block copolymer structure.
Graphical abstract
The simultaneous synthesis of poly(methyl methacrylate-b-ε-caprolactone) block copolymer was fulfilled by the atom transfer radical polymerization of methyl methacrylate and ring-opening polymerization of ε-caprolactone. The effects of the parameters on the polymerization reaction conditions were investigated. Thermal and spectroscopic measurements prove the formation of the block copolymer structure.
期刊介绍：
Journal of Chemical Sciences is a monthly journal published by the Indian Academy of Sciences. It formed part of the original Proceedings of the Indian Academy of Sciences – Part A, started by the Nobel Laureate Prof C V Raman in 1934, that was split in 1978 into three separate journals. It was renamed as Journal of Chemical Sciences in 2004. The journal publishes original research articles and rapid communications, covering all areas of chemical sciences. A significant feature of the journal is its special issues, brought out from time to time, devoted to conference symposia/proceedings in frontier areas of the subject, held not only in India but also in other countries.
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