Kiem Do Van, Nguyen Van Hieu, Thomas C-K Yang and Tu Le Manh
{"title":"通过从非水性溶剂中直接电沉积在芯片上制造 SnO2 气体传感器,实现超低 H2S 浓度的快速检测","authors":"Kiem Do Van, Nguyen Van Hieu, Thomas C-K Yang and Tu Le Manh","doi":"10.1149/1945-7111/ad790f","DOIUrl":null,"url":null,"abstract":"Hydrogen sulfide (H2S) causes significant impacts on human health and the environment due to its highly toxic properties. Thus, the design and development of gas sensors to detect and monitor H2S (especially at extremely low concentrations) are challenging tasks for scientists. In this work, SnO2 gas sensors were successfully synthesized directly on a chip by Sn electrodeposition from ethylene glycol solutions + a post-treatment (calcination) stage (to form and stabilize SnO2). Mechanisms and kinetics of Sn electrodeposition on Pt microelectrodes were thoroughly studied using electrochemical techniques. These fabricated gas sensors exhibit a high selectivity toward H2S gas and an effective response to low-level concentrations of H2S in the range of 0.1 ppm–1 ppm at different working temperatures. The influence of electrodeposition conditions and calcination temperatures on the gas response of sensors were also examined. The results have verified that the electrodeposition method from ethylene glycol solutions is promising for the fabrication of ultrasensitive on-chip gas sensors.","PeriodicalId":17364,"journal":{"name":"Journal of The Electrochemical Society","volume":null,"pages":null},"PeriodicalIF":3.1000,"publicationDate":"2024-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Rapid Detection of Ultralow H2S Concentration with on-chip Fabrication of SnO2-based Gas Sensors by Direct Electrodeposition from Non-Aqueous Solvents\",\"authors\":\"Kiem Do Van, Nguyen Van Hieu, Thomas C-K Yang and Tu Le Manh\",\"doi\":\"10.1149/1945-7111/ad790f\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Hydrogen sulfide (H2S) causes significant impacts on human health and the environment due to its highly toxic properties. Thus, the design and development of gas sensors to detect and monitor H2S (especially at extremely low concentrations) are challenging tasks for scientists. In this work, SnO2 gas sensors were successfully synthesized directly on a chip by Sn electrodeposition from ethylene glycol solutions + a post-treatment (calcination) stage (to form and stabilize SnO2). Mechanisms and kinetics of Sn electrodeposition on Pt microelectrodes were thoroughly studied using electrochemical techniques. These fabricated gas sensors exhibit a high selectivity toward H2S gas and an effective response to low-level concentrations of H2S in the range of 0.1 ppm–1 ppm at different working temperatures. The influence of electrodeposition conditions and calcination temperatures on the gas response of sensors were also examined. The results have verified that the electrodeposition method from ethylene glycol solutions is promising for the fabrication of ultrasensitive on-chip gas sensors.\",\"PeriodicalId\":17364,\"journal\":{\"name\":\"Journal of The Electrochemical Society\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.1000,\"publicationDate\":\"2024-09-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Electrochemical Society\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1149/1945-7111/ad790f\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ELECTROCHEMISTRY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Electrochemical Society","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1149/1945-7111/ad790f","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
Rapid Detection of Ultralow H2S Concentration with on-chip Fabrication of SnO2-based Gas Sensors by Direct Electrodeposition from Non-Aqueous Solvents
Hydrogen sulfide (H2S) causes significant impacts on human health and the environment due to its highly toxic properties. Thus, the design and development of gas sensors to detect and monitor H2S (especially at extremely low concentrations) are challenging tasks for scientists. In this work, SnO2 gas sensors were successfully synthesized directly on a chip by Sn electrodeposition from ethylene glycol solutions + a post-treatment (calcination) stage (to form and stabilize SnO2). Mechanisms and kinetics of Sn electrodeposition on Pt microelectrodes were thoroughly studied using electrochemical techniques. These fabricated gas sensors exhibit a high selectivity toward H2S gas and an effective response to low-level concentrations of H2S in the range of 0.1 ppm–1 ppm at different working temperatures. The influence of electrodeposition conditions and calcination temperatures on the gas response of sensors were also examined. The results have verified that the electrodeposition method from ethylene glycol solutions is promising for the fabrication of ultrasensitive on-chip gas sensors.
期刊介绍:
The Journal of The Electrochemical Society (JES) is the leader in the field of solid-state and electrochemical science and technology. This peer-reviewed journal publishes an average of 450 pages of 70 articles each month. Articles are posted online, with a monthly paper edition following electronic publication. The ECS membership benefits package includes access to the electronic edition of this journal.