使用矿渣改性脲醛树脂改进胶合板制造技术

IF 0.58 Q4 Materials Science
G. S. Varankina, D. S. Rusakov, E. R. Elagina
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引用次数: 0

摘要

摘要 木材复合材料,特别是胶合板的生产是利用废物以增加副产品回收利用的最有效途径之一。这项工作的目的是研究使用炼钢酸性炉渣作为胶合板生产用脲醛树脂的改性添加剂的可能性,并确定炼钢炉渣对胶合板粘接强度的影响。炉渣的主要来源是铸铁的氧化产物和废钢杂质(硅、锰、磷、铬等)、炉料(石灰、石灰石、铁矿石和锰矿石、水垢、铝土矿、萤石等)以及耐火衬破坏的产物。研究结果发现,在脲醛树脂中加入木质素磺酸盐、高岭土和炉渣会提高成品胶水的反应活性。炉渣中的金属氧化物与羟基结合的能力已得到证实;在这方面,压制过程中加热时,聚合物不会分解成简单的单体,脲醛树脂中的游离甲醛会进入缩聚反应,不会从胶水中挥发出来。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Improvement of Plywood Manufacturing Technology Using Slag-Modified Urea–Formaldehyde Resins

Improvement of Plywood Manufacturing Technology Using Slag-Modified Urea–Formaldehyde Resins

Improvement of Plywood Manufacturing Technology Using Slag-Modified Urea–Formaldehyde Resins

The production of wood composite materials and, in particular, plywood is one of the most effective ways to utilize waste in order to increase the recycling of by-products. The purpose of the work was to study the possibility of using steelmaking acidic slag as a modifying additive in urea–formaldehyde resins for plywood production and to determine the effect of steelmaking slag on the strength of plywood adhesive joints. The main sources of slag are the oxidation products of cast iron and scrap impurities (silicon, manganese, phosphorus, chromium, etc.), charge materials (lime, limestone, iron and manganese ore, scale, bauxite, fluorspar, etc.), and products of the destruction of refractory linings. As a result of the study, it has been found that the introduction of lignosulfonates, kaolin, and slags into urea–formaldehyde resin increases the reactivity of the finished glue. The ability of metal oxides in slag to bind hydroxyl groups has been proven; in this regard, when heated during pressing, the polymer does not break down into simple monomers, and the free formaldehyde of the urea–formaldehyde resin enters into a polycondensation reaction and is not evaporated from the glue.

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来源期刊
Polymer Science, Series D
Polymer Science, Series D Materials Science-Polymers and Plastics
CiteScore
0.80
自引率
0.00%
发文量
87
期刊介绍: Polymer Science, Series D  publishes useful description of engineering developments that are related to the preparation and application of glues, compounds, sealing materials, and binding agents, articles on the adhesion theory, prediction of the strength of adhesive joints, methods for the control of their properties, synthesis, and methods of structural modeling of glued joints and constructions, original articles with new scientific results, analytical reviews of the modern state in the field.
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