Chengjun Liu, Xiaoxiang Xie, Jiyu Qiu, Wenjie Li, Guojie Huo
{"title":"还原气氛下 CaO-Al2O3-VOx 熔渣体系的相图","authors":"Chengjun Liu, Xiaoxiang Xie, Jiyu Qiu, Wenjie Li, Guojie Huo","doi":"10.1007/s11837-024-06866-y","DOIUrl":null,"url":null,"abstract":"<div><p>The phase diagram information of the CaO-Al<sub>2</sub>O<sub>3</sub>-VO<sub><i>x</i></sub> system is of significant importance for the direct alloying study of vanadium (V) during the smelting process of V-containing alloy steel, as well as for subsequent process optimization. This study has utilized the high-temperature phase equilibrium experimental method, combined with scanning electron microscope–energy dispersive spectrometer (SEM–EDS), electron probe micro-analysis (EPMA) and X-ray photoelectron spectroscopy (XPS) detection techniques, to research the phase equilibrium of the CaO-Al<sub>2</sub>O<sub>3</sub>-VO<sub><i>x</i></sub> system under argon (Ar) atmosphere at 1400°C. This study reveals that the phase diagram of CaO-Al<sub>2</sub>O<sub>3</sub>-VO<sub><i>x</i></sub> system, under the specified conditions, comprises 4 three-phase regions, 7 two-phase regions, and a liquid phase region. This study has plotted the CaO-Al<sub>2</sub>O<sub>3</sub>-V<sub>2</sub>O<sub>5</sub>-VO<sub>2</sub> three-dimensional phase diagram and represented the phase equilibrium in CaO-Al<sub>2</sub>O<sub>3</sub>-V<sub>2</sub>O<sub>5</sub>, CaO-Al<sub>2</sub>O<sub>3</sub>-VO<sub>2</sub>, CaO-Al<sub>2</sub>O<sub>3</sub>-VO<sub>2.335</sub>, and Ca-Al-V systems. At the same time, the reliability of each projected phase diagram was quantitatively assessed.</p></div>","PeriodicalId":605,"journal":{"name":"JOM","volume":"76 11","pages":"6555 - 6567"},"PeriodicalIF":2.1000,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11837-024-06866-y.pdf","citationCount":"0","resultStr":"{\"title\":\"Phase Diagram of CaO-Al2O3-VOx Slag System Under Reducing Atmosphere\",\"authors\":\"Chengjun Liu, Xiaoxiang Xie, Jiyu Qiu, Wenjie Li, Guojie Huo\",\"doi\":\"10.1007/s11837-024-06866-y\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The phase diagram information of the CaO-Al<sub>2</sub>O<sub>3</sub>-VO<sub><i>x</i></sub> system is of significant importance for the direct alloying study of vanadium (V) during the smelting process of V-containing alloy steel, as well as for subsequent process optimization. This study has utilized the high-temperature phase equilibrium experimental method, combined with scanning electron microscope–energy dispersive spectrometer (SEM–EDS), electron probe micro-analysis (EPMA) and X-ray photoelectron spectroscopy (XPS) detection techniques, to research the phase equilibrium of the CaO-Al<sub>2</sub>O<sub>3</sub>-VO<sub><i>x</i></sub> system under argon (Ar) atmosphere at 1400°C. This study reveals that the phase diagram of CaO-Al<sub>2</sub>O<sub>3</sub>-VO<sub><i>x</i></sub> system, under the specified conditions, comprises 4 three-phase regions, 7 two-phase regions, and a liquid phase region. This study has plotted the CaO-Al<sub>2</sub>O<sub>3</sub>-V<sub>2</sub>O<sub>5</sub>-VO<sub>2</sub> three-dimensional phase diagram and represented the phase equilibrium in CaO-Al<sub>2</sub>O<sub>3</sub>-V<sub>2</sub>O<sub>5</sub>, CaO-Al<sub>2</sub>O<sub>3</sub>-VO<sub>2</sub>, CaO-Al<sub>2</sub>O<sub>3</sub>-VO<sub>2.335</sub>, and Ca-Al-V systems. At the same time, the reliability of each projected phase diagram was quantitatively assessed.</p></div>\",\"PeriodicalId\":605,\"journal\":{\"name\":\"JOM\",\"volume\":\"76 11\",\"pages\":\"6555 - 6567\"},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2024-09-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://link.springer.com/content/pdf/10.1007/s11837-024-06866-y.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"JOM\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11837-024-06866-y\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"JOM","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s11837-024-06866-y","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Phase Diagram of CaO-Al2O3-VOx Slag System Under Reducing Atmosphere
The phase diagram information of the CaO-Al2O3-VOx system is of significant importance for the direct alloying study of vanadium (V) during the smelting process of V-containing alloy steel, as well as for subsequent process optimization. This study has utilized the high-temperature phase equilibrium experimental method, combined with scanning electron microscope–energy dispersive spectrometer (SEM–EDS), electron probe micro-analysis (EPMA) and X-ray photoelectron spectroscopy (XPS) detection techniques, to research the phase equilibrium of the CaO-Al2O3-VOx system under argon (Ar) atmosphere at 1400°C. This study reveals that the phase diagram of CaO-Al2O3-VOx system, under the specified conditions, comprises 4 three-phase regions, 7 two-phase regions, and a liquid phase region. This study has plotted the CaO-Al2O3-V2O5-VO2 three-dimensional phase diagram and represented the phase equilibrium in CaO-Al2O3-V2O5, CaO-Al2O3-VO2, CaO-Al2O3-VO2.335, and Ca-Al-V systems. At the same time, the reliability of each projected phase diagram was quantitatively assessed.
期刊介绍：
JOM is a technical journal devoted to exploring the many aspects of materials science and engineering. JOM reports scholarly work that explores the state-of-the-art processing, fabrication, design, and application of metals, ceramics, plastics, composites, and other materials. In pursuing this goal, JOM strives to balance the interests of the laboratory and the marketplace by reporting academic, industrial, and government-sponsored work from around the world.
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