{"title":"600-1200°C 下 Al2O3-ZrO2-SiB6 陶瓷的裂缝愈合行为和抗氧化性","authors":"Haopeng Cai, Kun Jiang, Lihua Gao, Yinglong Wei","doi":"10.1111/ijac.14889","DOIUrl":null,"url":null,"abstract":"In this paper, we prepared Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub>–ZrO<jats:sub>2</jats:sub>–SiB<jats:sub>6</jats:sub> composite ceramics with excellent performance by introducing the second‐phase high‐strength healing agent SiB<jats:sub>6</jats:sub> in zirconia‐toughened alumina system, artificially created cracks using Vickers hardness tester, investigated the effects of heat treatment temperature (600–1200°C) and time (0–300 min) on the microscopic morphology and bending strength of the ceramics, revealed the healing mechanism, and studied the oxidation resistance properties. It was found that the healing effect was better at heat treatment of 90 min at 700°C and 60 min at 800°C, and the flexural strength was restored to more than 95% of that of the smooth specimens in both cases. Crack repair was mainly achieved by the reaction of SiB<jats:sub>6</jats:sub>, ZrB<jats:sub>2</jats:sub>, and B<jats:sub>4</jats:sub>C with O<jats:sub>2</jats:sub>. Below 800°C, healing was mainly achieved by the reaction of SiB<jats:sub>6</jats:sub> and B<jats:sub>4</jats:sub>C with O<jats:sub>2</jats:sub>, and the generated B<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> and SiO<jats:sub>2</jats:sub> migrated toward the crack to repair it. When the healing temperature is higher than 800°C, ZrB<jats:sub>2</jats:sub> also reacts with oxygen to produce B<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> and t‐ZrO<jats:sub>2</jats:sub>. It was found that the oxidation weight gain per unit area of the Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub>–ZrO<jats:sub>2</jats:sub>–SiB<jats:sub>6</jats:sub> ceramic composite at different temperatures was small, and it has excellent oxidation resistance.","PeriodicalId":13903,"journal":{"name":"International Journal of Applied Ceramic Technology","volume":null,"pages":null},"PeriodicalIF":1.8000,"publicationDate":"2024-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The crack‐healing behavior and oxidation resistance of Al2O3–ZrO2–SiB6 ceramic at 600–1200°C\",\"authors\":\"Haopeng Cai, Kun Jiang, Lihua Gao, Yinglong Wei\",\"doi\":\"10.1111/ijac.14889\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In this paper, we prepared Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub>–ZrO<jats:sub>2</jats:sub>–SiB<jats:sub>6</jats:sub> composite ceramics with excellent performance by introducing the second‐phase high‐strength healing agent SiB<jats:sub>6</jats:sub> in zirconia‐toughened alumina system, artificially created cracks using Vickers hardness tester, investigated the effects of heat treatment temperature (600–1200°C) and time (0–300 min) on the microscopic morphology and bending strength of the ceramics, revealed the healing mechanism, and studied the oxidation resistance properties. It was found that the healing effect was better at heat treatment of 90 min at 700°C and 60 min at 800°C, and the flexural strength was restored to more than 95% of that of the smooth specimens in both cases. Crack repair was mainly achieved by the reaction of SiB<jats:sub>6</jats:sub>, ZrB<jats:sub>2</jats:sub>, and B<jats:sub>4</jats:sub>C with O<jats:sub>2</jats:sub>. Below 800°C, healing was mainly achieved by the reaction of SiB<jats:sub>6</jats:sub> and B<jats:sub>4</jats:sub>C with O<jats:sub>2</jats:sub>, and the generated B<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> and SiO<jats:sub>2</jats:sub> migrated toward the crack to repair it. When the healing temperature is higher than 800°C, ZrB<jats:sub>2</jats:sub> also reacts with oxygen to produce B<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> and t‐ZrO<jats:sub>2</jats:sub>. It was found that the oxidation weight gain per unit area of the Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub>–ZrO<jats:sub>2</jats:sub>–SiB<jats:sub>6</jats:sub> ceramic composite at different temperatures was small, and it has excellent oxidation resistance.\",\"PeriodicalId\":13903,\"journal\":{\"name\":\"International Journal of Applied Ceramic Technology\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2024-09-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Applied Ceramic Technology\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1111/ijac.14889\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Applied Ceramic Technology","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1111/ijac.14889","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
The crack‐healing behavior and oxidation resistance of Al2O3–ZrO2–SiB6 ceramic at 600–1200°C
In this paper, we prepared Al2O3–ZrO2–SiB6 composite ceramics with excellent performance by introducing the second‐phase high‐strength healing agent SiB6 in zirconia‐toughened alumina system, artificially created cracks using Vickers hardness tester, investigated the effects of heat treatment temperature (600–1200°C) and time (0–300 min) on the microscopic morphology and bending strength of the ceramics, revealed the healing mechanism, and studied the oxidation resistance properties. It was found that the healing effect was better at heat treatment of 90 min at 700°C and 60 min at 800°C, and the flexural strength was restored to more than 95% of that of the smooth specimens in both cases. Crack repair was mainly achieved by the reaction of SiB6, ZrB2, and B4C with O2. Below 800°C, healing was mainly achieved by the reaction of SiB6 and B4C with O2, and the generated B2O3 and SiO2 migrated toward the crack to repair it. When the healing temperature is higher than 800°C, ZrB2 also reacts with oxygen to produce B2O3 and t‐ZrO2. It was found that the oxidation weight gain per unit area of the Al2O3–ZrO2–SiB6 ceramic composite at different temperatures was small, and it has excellent oxidation resistance.
期刊介绍:
The International Journal of Applied Ceramic Technology publishes cutting edge applied research and development work focused on commercialization of engineered ceramics, products and processes. The publication also explores the barriers to commercialization, design and testing, environmental health issues, international standardization activities, databases, and cost models. Designed to get high quality information to end-users quickly, the peer process is led by an editorial board of experts from industry, government, and universities. Each issue focuses on a high-interest, high-impact topic plus includes a range of papers detailing applications of ceramics. Papers on all aspects of applied ceramics are welcome including those in the following areas:
Nanotechnology applications;
Ceramic Armor;
Ceramic and Technology for Energy Applications (e.g., Fuel Cells, Batteries, Solar, Thermoelectric, and HT Superconductors);
Ceramic Matrix Composites;
Functional Materials;
Thermal and Environmental Barrier Coatings;
Bioceramic Applications;
Green Manufacturing;
Ceramic Processing;
Glass Technology;
Fiber optics;
Ceramics in Environmental Applications;
Ceramics in Electronic, Photonic and Magnetic Applications;