创新型 La-Fe-CNT 膜对磷酸盐的吸收:结构-活性相关性与机理研究

IF 7.4 Q1 ENGINEERING, ENVIRONMENTAL
Yi Yang, Xintong You, Shuo Tang, Ying Li, Minyi Liu, Ying Mei, Wei Shu
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引用次数: 0

摘要

过量磷污染造成的富营养化不仅带来一系列环境问题,还威胁着生物安全。吸附法具有选择性高、环境友好、操作简便、成本低廉等优点,已被广泛应用于防治富营养化。本研究采用简单的浸渍和真空过滤相结合的方法,合成了一种易于分离的磁性镧铁制碳纳米管(La-Fe-CNT)膜,用于高效吸附磷酸盐。表征结果表明,在碳纳米管膜上成功制备了金属(氢)氧化物,并吸收了磷酸盐。利用 Box-Behnken 设计模型定量研究了 La-Fe-CNT 的结构-活性相关性,得到了以下优化条件:反应温度为 44 ℃,合成时间为 14.3 h,La 摩尔比为 0.53,吸附容量为 127 mg/g。La-Fe-CNT 在较宽的 pH 值范围内表现良好(pH 值为 2 时为 142 毫克/克),稳定性高(金属沥滤小于 2 毫克/升)。在吸附过程中存在三种相互作用,包括静电作用、配体交换和路易斯酸碱作用。动力学研究表明,磷酸盐吸附过程是一个物理化学过程,包括颗粒内扩散和表面膜扩散。在等温线研究中,La-Fe-CNT 的平衡磷酸盐吸附容量为 120.2 mg/g,磷酸盐的吸收过程是一个复杂的过程,包括 Langmuir 吸附和 Freundlich 吸附。该吸附剂在运行 5 个周期后仍能保持近 70% 的原始容量,这表明它具有稳定性和可持续性,可用于潜在的工业应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Phosphate Uptake over the Innovative La–Fe–CNT Membrane: Structure-Activity Correlation and Mechanism Investigation

Phosphate Uptake over the Innovative La–Fe–CNT Membrane: Structure-Activity Correlation and Mechanism Investigation
Eutrophication caused by excessive phosphorus pollution not only brings a series of environmental problems but also threatens biological safety. The adsorption method has been widely used for preventing eutrophication due to its high selectivity, environmental friendliness, easy operation, and cost-effectiveness. In this study, an easily separated magnetic lanthanum and iron-fabricated carbon nanotube (La–Fe–CNT) membrane was synthesized by a simple combined impregnation and vacuum filtration method for highly effective phosphate uptake. Characterization results show that metallic (hydr)oxide species were successfully fabricated on the CNT membrane, and phosphate was absorbed on it. The structure-activity correlation of La–Fe–CNT was quantitatively investigated by the Box–Behnken design model, and the following optimized conditions were obtained: a reaction temperature of 44 °C, synthesis time of 14.3 h, and La molar ratio of 0.53, with an adsorption capacity of 127 mg/g. La–Fe–CNT performs well over a wide pH range (142 mg/g at pH 2) with high stability (less than 2 mg/L metal leaching). Three interactions exist during the adsorption process, including electrostatic interactions, ligand exchange, and Lewis acid–base interactions. A kinetic study shows that the phosphate adsorption process is a physical-chemical process with combined intraparticle and surface film diffusion. The equilibrium phosphate adsorption capacity of La–Fe–CNT in the isotherm study is 120.2 mg/g, and the phosphate uptake process involves a complex process including both Langmuir and Freundlich adsorption. The adsorbent still retains nearly 70% of its original capacity after 5 cycles of operation, depicting its stability and sustainability for potential industrial applications.
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来源期刊
ACS ES&T engineering
ACS ES&T engineering ENGINEERING, ENVIRONMENTAL-
CiteScore
8.50
自引率
0.00%
发文量
0
期刊介绍: ACS ES&T Engineering publishes impactful research and review articles across all realms of environmental technology and engineering, employing a rigorous peer-review process. As a specialized journal, it aims to provide an international platform for research and innovation, inviting contributions on materials technologies, processes, data analytics, and engineering systems that can effectively manage, protect, and remediate air, water, and soil quality, as well as treat wastes and recover resources. The journal encourages research that supports informed decision-making within complex engineered systems and is grounded in mechanistic science and analytics, describing intricate environmental engineering systems. It considers papers presenting novel advancements, spanning from laboratory discovery to field-based application. However, case or demonstration studies lacking significant scientific advancements and technological innovations are not within its scope. Contributions containing experimental and/or theoretical methods, rooted in engineering principles and integrated with knowledge from other disciplines, are welcomed.
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