Cotton-based fabric waste to microcrystalline cellulose: a sustainable waste management approach

The escalating accumulation of textile waste in landfill sites poses a significant environmental hazard that requires immediate intervention. This study focused on the sustainable and value-enhancing management of used fabrics via chemical recycling. The acid hydrolysis of six distinct types of cotton-based fabric waste (FW) has been conducted for the first time using a milder concentration (10%) of acid. The experiments resulted in the successful extraction of microcrystalline cellulose (MCC). The product underwent various analytical techniques, such as XRD, FTIR, FESEM, TGA, DTG, and PL spectroscopy, to verify the presence of microcrystalline cellulose (I-cellulose). The various sources of cellulose yielded varying results for MCC in terms of the yield (ranging from 28.2% to 80.2%), crystallinity index (ranging from 83.9% to 87%), crystallite size (ranging from 5.287 to 5.952 nm), thermal stability (ranging from 310 °C to 327 °C), and heat of fusion (ranging from 302 to 364 J g⁻¹). The physico-chemical parameters of these six MCC samples were similar, with the carbon content ranging from 38.7% to 47%. The samples exhibited a range of bulk density values between 0.077 and 0.1975 g cc⁻¹, and a water retention value (WRV) between 91.3% and 95.5%. The efficient retrieval of cellulose from various fabric waste sources offers an eco-friendly and sustainable approach to bolster waste management initiatives for fabric-related refuse.