作为光激发发光剂量计的金属有机框架

IF 1.5 3区 化学 Q3 CHEMISTRY, ANALYTICAL
Shailesh Joshi, Madhusmita Panda, O. Annalakshmi, C. Venkata Srinivas, B. Venkatraman
{"title":"作为光激发发光剂量计的金属有机框架","authors":"Shailesh Joshi, Madhusmita Panda, O. Annalakshmi, C. Venkata Srinivas, B. Venkatraman","doi":"10.1007/s10967-024-09761-7","DOIUrl":null,"url":null,"abstract":"<p>Metal–organic frameworks (MOF) have been vigorously investigated as hybrid materials in recent decades due to their exceptional structural versatility and applications in diverse fields. The development of novel MOFs for radiation detection and luminescence-based dosimetry is the latest topic of interest. In this contribution, we have synthesized and characterized a Uranyl MOF, which shows an optically stimulated luminescence (OSL) phenomenon induced by ionizing radiation. OSL dosimetric studies were carried out on Uranyl MOF, which revealed that MOF has a linear dose–response up to 100 Gy with a 1.1 Gy minimum detection dose. It also shows good reusability, around 30% fading in one day, very low fading beyond one day to 30 days, and decent radiation stability (stable up to 10 kGy). Preliminary dosimetry results are promising and show that Uranyl MOF can be utilized in the field of low-dose radiation processing applications in the future.</p>","PeriodicalId":661,"journal":{"name":"Journal of Radioanalytical and Nuclear Chemistry","volume":null,"pages":null},"PeriodicalIF":1.5000,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Metal–organic frameworks as optically stimulated luminescence dosimeter\",\"authors\":\"Shailesh Joshi, Madhusmita Panda, O. Annalakshmi, C. Venkata Srinivas, B. Venkatraman\",\"doi\":\"10.1007/s10967-024-09761-7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Metal–organic frameworks (MOF) have been vigorously investigated as hybrid materials in recent decades due to their exceptional structural versatility and applications in diverse fields. The development of novel MOFs for radiation detection and luminescence-based dosimetry is the latest topic of interest. In this contribution, we have synthesized and characterized a Uranyl MOF, which shows an optically stimulated luminescence (OSL) phenomenon induced by ionizing radiation. OSL dosimetric studies were carried out on Uranyl MOF, which revealed that MOF has a linear dose–response up to 100 Gy with a 1.1 Gy minimum detection dose. It also shows good reusability, around 30% fading in one day, very low fading beyond one day to 30 days, and decent radiation stability (stable up to 10 kGy). Preliminary dosimetry results are promising and show that Uranyl MOF can be utilized in the field of low-dose radiation processing applications in the future.</p>\",\"PeriodicalId\":661,\"journal\":{\"name\":\"Journal of Radioanalytical and Nuclear Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.5000,\"publicationDate\":\"2024-09-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Radioanalytical and Nuclear Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1007/s10967-024-09761-7\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Radioanalytical and Nuclear Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1007/s10967-024-09761-7","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
引用次数: 0

摘要

近几十年来,金属有机框架(MOF)作为杂化材料受到了广泛的研究,因为它们具有特殊的结构多样性,并可应用于多个领域。开发用于辐射检测和基于发光的剂量测定的新型 MOF 是最新的研究课题。在本文中,我们合成并表征了一种铀MOF,它在电离辐射的诱导下显示出光激发发光(OSL)现象。我们对铀基 MOF 进行了剂量测定研究,结果表明 MOF 具有高达 100 Gy 的线性剂量响应,最小检测剂量为 1.1 Gy。它还显示出良好的重复使用性,一天内衰减约 30%,一天后至 30 天内衰减极低,辐射稳定性良好(稳定达 10 kGy)。初步剂量测定结果很有希望,表明铀 MOF 未来可用于低剂量辐射处理应用领域。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Metal–organic frameworks as optically stimulated luminescence dosimeter

Metal–organic frameworks as optically stimulated luminescence dosimeter

Metal–organic frameworks (MOF) have been vigorously investigated as hybrid materials in recent decades due to their exceptional structural versatility and applications in diverse fields. The development of novel MOFs for radiation detection and luminescence-based dosimetry is the latest topic of interest. In this contribution, we have synthesized and characterized a Uranyl MOF, which shows an optically stimulated luminescence (OSL) phenomenon induced by ionizing radiation. OSL dosimetric studies were carried out on Uranyl MOF, which revealed that MOF has a linear dose–response up to 100 Gy with a 1.1 Gy minimum detection dose. It also shows good reusability, around 30% fading in one day, very low fading beyond one day to 30 days, and decent radiation stability (stable up to 10 kGy). Preliminary dosimetry results are promising and show that Uranyl MOF can be utilized in the field of low-dose radiation processing applications in the future.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
CiteScore
2.80
自引率
18.80%
发文量
504
审稿时长
2.2 months
期刊介绍: An international periodical publishing original papers, letters, review papers and short communications on nuclear chemistry. The subjects covered include: Nuclear chemistry, Radiochemistry, Radiation chemistry, Radiobiological chemistry, Environmental radiochemistry, Production and control of radioisotopes and labelled compounds, Nuclear power plant chemistry, Nuclear fuel chemistry, Radioanalytical chemistry, Radiation detection and measurement, Nuclear instrumentation and automation, etc.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信