{"title":"窄毛细管中活性液体的诱导压力驱动输送中的流动电场、电粘性效应和电动液体流","authors":"Siddhartha Das, Ghansham Rajendrasingh Chandel","doi":"10.1002/elps.202400133","DOIUrl":null,"url":null,"abstract":"In this paper, we develop a theory for studying the electrokinetic effects in a charged nanocapillary filled with active liquid. The active particles present within the active liquid are self‐driven, demonstrate vortex defects, and enforce a circumferentially arranged polarization field. Under such circumstances, there is the development of an induced pressure‐gradient‐driven transport dictated (similar to diffusioosmotic transport) by the presence of an axial gradient in the activity (or the concentration of the active particles). This pressure‐driven transport has a profile different from the standard Hagen–Poiseuille flow in a nanocapillary. Also, this induced pressure‐driven flow drives electrokinetic effects, which are characterized by the generation of a streaming electric field, associated electroosmotic (EOS) transport opposing pressure‐driven flow, and electroviscous effect. We quantify these effects as functions of dimensionless parameters that vary inversely as the strength of the activity‐induced pressure‐driven flow and salt concentrations. Overall, we anticipate that this paper will draw immense attention toward a new type of activity‐induced pressure‐driven flow and associated electrokinetic phenomena in charged nanoconfinements.","PeriodicalId":11596,"journal":{"name":"ELECTROPHORESIS","volume":null,"pages":null},"PeriodicalIF":3.0000,"publicationDate":"2024-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Streaming electric field, electroviscous effect, and electrokinetic liquid flows in the induced pressure‐driven transport of active liquids in narrow capillaries\",\"authors\":\"Siddhartha Das, Ghansham Rajendrasingh Chandel\",\"doi\":\"10.1002/elps.202400133\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In this paper, we develop a theory for studying the electrokinetic effects in a charged nanocapillary filled with active liquid. The active particles present within the active liquid are self‐driven, demonstrate vortex defects, and enforce a circumferentially arranged polarization field. Under such circumstances, there is the development of an induced pressure‐gradient‐driven transport dictated (similar to diffusioosmotic transport) by the presence of an axial gradient in the activity (or the concentration of the active particles). This pressure‐driven transport has a profile different from the standard Hagen–Poiseuille flow in a nanocapillary. Also, this induced pressure‐driven flow drives electrokinetic effects, which are characterized by the generation of a streaming electric field, associated electroosmotic (EOS) transport opposing pressure‐driven flow, and electroviscous effect. We quantify these effects as functions of dimensionless parameters that vary inversely as the strength of the activity‐induced pressure‐driven flow and salt concentrations. Overall, we anticipate that this paper will draw immense attention toward a new type of activity‐induced pressure‐driven flow and associated electrokinetic phenomena in charged nanoconfinements.\",\"PeriodicalId\":11596,\"journal\":{\"name\":\"ELECTROPHORESIS\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.0000,\"publicationDate\":\"2024-09-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ELECTROPHORESIS\",\"FirstCategoryId\":\"99\",\"ListUrlMain\":\"https://doi.org/10.1002/elps.202400133\",\"RegionNum\":3,\"RegionCategory\":\"生物学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"BIOCHEMICAL RESEARCH METHODS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ELECTROPHORESIS","FirstCategoryId":"99","ListUrlMain":"https://doi.org/10.1002/elps.202400133","RegionNum":3,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"BIOCHEMICAL RESEARCH METHODS","Score":null,"Total":0}
Streaming electric field, electroviscous effect, and electrokinetic liquid flows in the induced pressure‐driven transport of active liquids in narrow capillaries
In this paper, we develop a theory for studying the electrokinetic effects in a charged nanocapillary filled with active liquid. The active particles present within the active liquid are self‐driven, demonstrate vortex defects, and enforce a circumferentially arranged polarization field. Under such circumstances, there is the development of an induced pressure‐gradient‐driven transport dictated (similar to diffusioosmotic transport) by the presence of an axial gradient in the activity (or the concentration of the active particles). This pressure‐driven transport has a profile different from the standard Hagen–Poiseuille flow in a nanocapillary. Also, this induced pressure‐driven flow drives electrokinetic effects, which are characterized by the generation of a streaming electric field, associated electroosmotic (EOS) transport opposing pressure‐driven flow, and electroviscous effect. We quantify these effects as functions of dimensionless parameters that vary inversely as the strength of the activity‐induced pressure‐driven flow and salt concentrations. Overall, we anticipate that this paper will draw immense attention toward a new type of activity‐induced pressure‐driven flow and associated electrokinetic phenomena in charged nanoconfinements.
期刊介绍:
ELECTROPHORESIS is an international journal that publishes original manuscripts on all aspects of electrophoresis, and liquid phase separations (e.g., HPLC, micro- and nano-LC, UHPLC, micro- and nano-fluidics, liquid-phase micro-extractions, etc.).
Topics include new or improved analytical and preparative methods, sample preparation, development of theory, and innovative applications of electrophoretic and liquid phase separations methods in the study of nucleic acids, proteins, carbohydrates natural products, pharmaceuticals, food analysis, environmental species and other compounds of importance to the life sciences.
Papers in the areas of microfluidics and proteomics, which are not limited to electrophoresis-based methods, will also be accepted for publication. Contributions focused on hyphenated and omics techniques are also of interest. Proteomics is within the scope, if related to its fundamentals and new technical approaches. Proteomics applications are only considered in particular cases.
Papers describing the application of standard electrophoretic methods will not be considered.
Papers on nanoanalysis intended for publication in ELECTROPHORESIS should focus on one or more of the following topics:
• Nanoscale electrokinetics and phenomena related to electric double layer and/or confinement in nano-sized geometry
• Single cell and subcellular analysis
• Nanosensors and ultrasensitive detection aspects (e.g., involving quantum dots, "nanoelectrodes" or nanospray MS)
• Nanoscale/nanopore DNA sequencing (next generation sequencing)
• Micro- and nanoscale sample preparation
• Nanoparticles and cells analyses by dielectrophoresis
• Separation-based analysis using nanoparticles, nanotubes and nanowires.