构建用于氢气进化反应的掺硫镍铜界面

IF 11.3 1区化学 Q1 CHEMISTRY, PHYSICAL

ACS Catalysis Pub Date : 2024-09-18 DOI:10.1021/acsmaterialslett.4c01339

Jiajie Yu, Shiwen Zhang, Yuyang Liu, Yurun Tong, Yijie Zhong, Bin He, Enlai Hu, Jing Zhang, Zhongwei Chen

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引用次数: 0

摘要

开发高效、经济的氢进化反应（HER）电催化剂对于高纯度制氢非常重要。过渡金属基化合物一直被认为是氢进化反应铂基电催化剂的理想替代品。然而，由于纯金属对中间产物的吸附行为不理想，因此其 HER 活性不强。在此，我们采用硫脲参与电沉积的方法，制备了含有大量界面的硫掺杂镍和铜（S-Ni/Cu）纳米线。界面和硫掺杂重新分配了电催化剂结构的电子态，从而加速了氢原子在活性位点的吸附并促进了水的解离过程。因此，在 10 mA cm-2 的条件下，S-Ni/Cu 的 HER 过电位仅为 67 mV，具有极佳的耐久性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Construction of Sulfur Doped Nickel and Copper Interfaces for Hydrogen Evolution Reaction

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Construction of Sulfur Doped Nickel and Copper Interfaces for Hydrogen Evolution Reaction

Developing efficient and economical electrocatalysts for the hydrogen evolution reaction (HER) is important for high-purity hydrogen generation. Transition metals-based compounds have been considered as promising substitutes for the Pt-based electrocatalysts toward HER. Nevertheless, pure metals display inert HER activity because of their unfavorable adsorption behavior for intermediates. Herein, thiourea engaged electrodeposition was conducted to fabricate sulfur-doped nickel and copper (S–Ni/Cu) nanowires that contain numerous interfaces. Interface and sulfur doping redistributed the electronic states of the electrocatalyst structure, which accelerated the adsorption of hydrogen atoms at active sites and promoted the water dissociation process. Consequently, the HER overpotential of S–Ni/Cu is only 67 mV at 10 mA cm^–2, with excellent durability.

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来源期刊

ACS Catalysis CHEMISTRY, PHYSICAL-

CiteScore

20.80

自引率

6.20%

发文量

1253

审稿时长

1.5 months

期刊介绍： ACS Catalysis is an esteemed journal that publishes original research in the fields of heterogeneous catalysis, molecular catalysis, and biocatalysis. It offers broad coverage across diverse areas such as life sciences, organometallics and synthesis, photochemistry and electrochemistry, drug discovery and synthesis, materials science, environmental protection, polymer discovery and synthesis, and energy and fuels. The scope of the journal is to showcase innovative work in various aspects of catalysis. This includes new reactions and novel synthetic approaches utilizing known catalysts, the discovery or modification of new catalysts, elucidation of catalytic mechanisms through cutting-edge investigations, practical enhancements of existing processes, as well as conceptual advances in the field. Contributions to ACS Catalysis can encompass both experimental and theoretical research focused on catalytic molecules, macromolecules, and materials that exhibit catalytic turnover.