氨基官能化 β-二乙酰亚胺配体稳定胚芽烯和亚锡的合成与反应活性

IF 2.2 4区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

European Journal of Inorganic Chemistry Pub Date : 2024-09-18 DOI:10.1002/ejic.202400378

Tianyi Sun, Cheng Kong, Linlin Wu, Hao Wang

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引用次数: 0

摘要

我们制备出了氨基官能化的β-二亚基酸盐稳定化的氯代锗烯 1 和氯代锡烯 2，并对其进行了结构表征。1 或 2 与 KOtBu 反应后，分别得到了 β-二甲酰亚氨基稳定化叔丁氧基锗 3 和叔丁氧基茚 4。另一方面，2 与 LiN(SiMe3)2 反应后，分离出了含有四元 Sn2N2 环的双亚锡 5。所有新化合物都通过多重核磁共振光谱和单晶 X 射线分析进行了表征。

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Synthesis and Reactivity of the Amino-Functionalized β-Diketiminate Ligand Stabilized Germylene and Stannylene

Amino-functionalized β-diketiminate stabilized chlorogermylene 1 and chlorostannylene 2 have been prepared and structurally characterized. The reactions of 1 or 2 with KOtBu afforded the β-diketiminate stabilized tert-butoxygermylene 3 and tert-butoxystannylene 4, respectively. On the other hand, the reaction of 2 with LiN(SiMe3)2 led to the isolation of the bis-stannylene 5 containing a four-membered Sn2N2 ring. All new compounds have been characterized by multiple NMR spectroscopy and single crystal X-ray analysis.

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来源期刊

European Journal of Inorganic Chemistry 化学-无机化学与核化学

CiteScore

4.30

自引率

4.30%

发文量

419

审稿时长

1.3 months

期刊介绍： The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry: Chemische Berichte Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.